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Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
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* Storage: {[proInfo.prStorage]}
CAS No. : | 533-60-8 | MDL No. : | MFCD00045549 |
Formula : | C6H10O2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 114.14 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Danger | Class: | 4.1 |
Precautionary Statements: | P240-P210-P241-P264-P280-P302+P352-P370+P378-P337+P313-P305+P351+P338-P362+P364-P332+P313 | UN#: | 1325 |
Hazard Statements: | H228-H315-H319 | Packing Group: | Ⅱ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | With sodium chloride; zinc In methanol; water Heating; | |
92% | With ammonium chloride; zinc In tetrahydrofuran at 20℃; for 0.75h; | |
80% | With trimethylphosphane In tetrahydrofuran at 20℃; for 2h; |
62% | With bis(η5-cyclopentadienyl)hafnium dihydride In isopropyl alcohol at 80℃; for 8h; | |
With lithium aluminium tetrahydride; diethyl ether | ||
With NADH In aq. buffer at 50℃; Enzymatic reaction; | ||
With sodium chloride; zinc In methanol; water at 90℃; for 1h; | 1 Step 1. 2-Hydroxycyclohexan-1-one A mixture of zinc (4.67 g, 71.4 mmol), NaCl (4.17 g, 71.4 mmol) and cyclohexane-1,2- dione (4.0 g, 35.7 mmol) in MeOH (40 ml) and H2O (40 ml) was heated at 90° C for 1 h. The reaction was filtered and the filtrate extracted with EtOAc (3 x 60 ml). The combined organic phase was concentrated under reduced pressure to give the title compound as a white solid, which was used directly in the next step. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
at 130℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
87.5% | Stage #1: cyclohexanone-2-ol With phosphorous pentoxide In dichloromethane; dimethyl sulfoxide at -5℃; for 2h; Stage #2: With triethylamine In dichloromethane; dimethyl sulfoxide for 2h; | 1.4; 1.4; 2.4; 2.4; 3.4; 3.4; 4.4; 4.4; 5.4 (4) 20 mL of DMSO and 0.5 g of phosphorus pentoxide were successively added to 150 mL of dichloromethane solution containing 20 g of the compound having the structure shown in formula III, reacted at -5°C for 2 h, and 10 mL of 10 mL was added dropwise to the reaction flask Triethylamine, continue to react for 2h. After the reaction was completed, the reaction was quenched with 10% hydrochloric acid, filtered, washed, dried, and the solvent was rotary evaporated to obtain ortho-cyclohexanedione with a yield of 87.5% and a purity of 92.5%. |
With iron(III) chloride | ||
45 % Spectr. | With oxygen In dimethyl sulfoxide at 100℃; for 2h; |
Inert atmosphere; Schlenk technique; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
99% | With erbium(III) triflate In nitromethane at 20℃; for 0.5h; | |
99% | With cerium triflate In nitromethane; water at 20℃; for 1h; | |
99% | With water at 80℃; for 0.25h; microwave irradiation; |
80% | With sulfuric acid In chloroform | |
With hydrogenchloride In dichloromethane Yield given; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | With iodosylbenzene; boron trifluoride diethyl ether complex In water monomer | |
65% | With chromyl chloride In dichloromethane at -78℃; for 0.5h; | |
63% | With C6H6BF4IO*C12H24O6 In water monomer; acetonitrile at 0℃; Inert atmosphere; |
With hydrogenchloride; 3-(4-nitrophenyl)-2-(phenylsulfonyl)-1,2-oxaziridine 1.) CHCl3, 60 deg C, 0.5 h, 2.) THF; Yield given. Multistep reaction; | ||
With pyridine; potassium fluoride; dihydrogen peroxide; methyltrioxorhenium(VII) 1.) MeCN, AcOH, 15 min, 2.) MeOH, 2 h; Yield given. Multistep reaction; | ||
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / cyclohexane / 5 h / -15 - 20 °C 2: sodium flouride / dichloromethane / 3 h / 30 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
55% | With allyl methyl carbonate In toluene for 10h; Heating; | |
55% | With allyl methyl carbonate In toluene for 12h; Heating; | |
70 % Chromat. | With cyclohexanone at 150℃; for 8h; |
With 3,3-dimethyldioxirane In acetone Ambient temperature; Yield given; | ||
With sodium bromate; sodium hydrogensulfite | 2-Hydroxycyclohexanone was not commercially avail-able and was synthesized by oxidation of 1,2-cyclohexanediol withNaBrO3/NaHSO3as previously reported [88]. | |
With silver(0) nanoparticles supported on silica-coated ferrite In toluene for 48h; Inert atmosphere; Reflux; | ||
With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; butanedial; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃; for 1h; | ||
With hydrogenchloride; dichloro(4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane)manganese(II); dihydrogen peroxide In water; acetonitrile at 29.84℃; for 6h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1) toluene, 1.5h, reflux, 2) toluene, 45 min, reflux; Yield given. Multistep reaction; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With dimethylsulfite Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
99% | With oxygen; acetic acid In water at 60℃; for 0.5h; | |
90% | With oxygen In methanol at 60℃; for 24h; | |
87% | With sodium hypochlorite for 0.5h; Irradiation; |
86% | With sodium hypochlorite for 0.05h; Irradiation; | |
78% | With potassium superoxide In benzene for 3h; Irradiation; | |
73% | With 2.5Cs(1+)*0.5H(1+)*PMo12O40(3-)=Cs2.5H0.5PMo12O40; oxygen; vanadia In water at 79.84℃; for 3h; Autoclave; | |
64% | With oxygen; sodium hydroxide In water at 90℃; for 3h; | |
55% | With calcium hypochlorite; acetic acid In dichloromethane; water for 2h; Ambient temperature; | |
48% | With sulfuric acid; K-10 montmorillonite; oxygen In water; acetic acid at 70℃; for 24h; | 2.4 Catalytic tests General procedure: All catalytic tests were carried out using Schlenk techniques (20 mL) which was attached to a vacuum line with a manometer and a gas inlet. Prior to each catalytic test, the clay was dried at 373 K for 2 h. In a typical experiment, the Schlenk was charged with the solvent (5.0 mL; solvent: CH3CN, H2O, CH3OH, CH3COOH or a mixture of CH3COOH and H2O) and K-10MT (0.20 g). In some tests H2SO4 (0-0.37 mmol) was also added. The substrate (5.0 mmol) was then added and the vessel was immersed in an oil bath preheated at 70 °C. O2 was introduced at atmospheric pressure and the mixture was stirred magnetically for 24 h. Three parallel catalytic experiments were carried out for each test. |
45% | With aurin; water; copper(II) bis(trifluoromethanesulfonate) In acetonitrile for 48h; Schlenk technique; Irradiation; | |
With perchloric acid; meta ammonium vanadate(V) In water; acetic acid at 35℃; | ||
80 % Chromat. | With oxygen In water; acetic acid at 65℃; for 3.5h; | |
53 %Chromat. | With graphitic carbon nitride; oxygen; acetic acid In water; acetonitrile at 100℃; for 16h; Autoclave; Irradiation; Green chemistry; | General procedure for synthesis of benzil (2a) General procedure: In a typical procedure, mpg-C3N4 (60 mg) and 2-hydroxy-1,2-diphenylethanone (1a, 1.0 mmol) were added to CH3CN (10 mL) in a 100 mL stainless steel autoclave. The O2 (3 bar) source was introduced and the closed autoclave was heated to 100 °C, followed by visible light irradiation for 16 h. The reaction mixture turned clear and the catalysts were deposited on the button, which was recovered by filtration. And then the solvent was removed, and the residue was separated by column chromatography to give the pure sample 2a. |
68 %Spectr. | With C59H45BFeN6O3; oxygen In benzene at 20℃; for 0.366667h; Inert atmosphere; | |
With oxygen; vanadia In water at 80℃; for 4h; Autoclave; | ||
47 %Chromat. | With phosphotungstic acid decahydrate; oxygen In water at 79.84℃; for 24h; Autoclave; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
91 % Chromat. | With lithium aluminium tetrahydride | |
With tetrabutylammonium borohydride In various solvent(s) at 25℃; | ||
With sodium tetrahydroborate In methanol at 0℃; for 1h; | 4 Example 4 (General procedure for the synthesis of 1, 2-cyclohexanediol); The solution of oc-hydroxy cyclohexanone 8a (1 equiv, 0.8 mmol) in MeOH (1 mL) was added to a methanol suspension of NaBH4 at 0 °C and stirred at this temperature for 1 h. Then, the reaction mixture was poured into saturated NH4C1 solution. The aqueous layer was extracted with diethyl ether (20 mLx3). The combined organic extracts were dried over Na2S04 with cooling and concentrated under reduced pressure after filtration. The residual crude product was chromatographed on column filled with silica gel using a mixture of ethyl acetate and hexane as the eluant to give the product. |
With 5 % platinum on carbon; hydrogen In water at 219.84℃; for 0.5h; Autoclave; Sealed tube; | ||
Multi-step reaction with 2 steps 1: 5 % platinum on carbon / water / 0.5 h / 219.84 °C / Autoclave; Inert atmosphere; Sealed tube 2: 5 % platinum on carbon / water / 0.5 h / 219.84 °C / Autoclave; Inert atmosphere; Sealed tube |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
90% | With sulfuric acid; quinolinium dichromate(VI) In water at 49.9℃; | |
90% | With sulfuric acid; quinolinium dichromate(VI) In water at 49.9℃; oxidant and substrate concentrations dependence, solvent dependence, various diols; | |
81% | With [(neocuproine)Pd(OAc)]2(OTf)2; oxygen In water; acetonitrile at 25℃; for 3h; |
74% | Stage #1: trans-1,2-cyclohexandiol With dimethyltin dichloride In dichloromethane; 2,2,2-trifluoroethanol Stage #2: With tetraethylammonium bromide In dichloromethane; 2,2,2-trifluoroethanol at 0℃; Electrolysis; | |
62% | With dihydroxy-methyl-borane; potassium carbonate; dibromoisocyanuric acid In water at 0℃; for 8h; Darkness; Electrochemical reaction; Green chemistry; | |
79 % Turnov. | With fluorine In acetonitrile | |
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 21℃; for 2h; | ||
82 mg | With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; butanedial; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃; for 1h; | |
25 %Spectr. | With tetrabutylphosphonium decatungstate; diphenyldisulfane In acetonitrile for 18h; Cooling with ice; UV-irradiation; Inert atmosphere; Sealed tube; | |
Multi-step reaction with 2 steps 1.1: tetrabutylphosphonium decatungstate; diphenyldisulfane; dihydroxy-methyl-borane / acetonitrile / 12 h / Cooling with ice; UV-irradiation; Inert atmosphere; Sealed tube 1.2: 6 h 2.1: tetrabutylphosphonium decatungstate; diphenyldisulfane / acetonitrile / 18 h / Cooling with ice; UV-irradiation; Inert atmosphere; Sealed tube |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
96% | With tetraethylammonium bromide; di(n-butyl)tin oxide In methanol at 0℃; | |
96% | With tetraethylammonium bromide; di(n-butyl)tin oxide In methanol at 0℃; var. (type and amount) of organotin comp., supporting electrolyte; in the presence of trans and racem 1,2-cyclohexanediol also; | |
96% | With potassium bromate; potassium hydrogensulfate In water at 20℃; for 36h; Darkness; | General procedure for selective oxidation of 1,2-diols: General procedure: To a solution of 1,2-diol 1a (1.0 mmol) in water (4 mL), KBrO3 (0.5 mmol) was added followed by addition of KHSO4 (1.0 mmol). The reaction was conducted at room temperature under shielding from light until 1a disappeared, as monitored by TLC. After the reaction completion, aqueous saturated Na2S2O3 solution(10 mL) was added. The organic portion was extracted with AcOEt (3 40 mL)and then dried over MgSO4. The solvent was removed under vacuum and the residue was subjected to silica gel column chromatography (n-hexane/AcOEt5:1) to afford (134 mg, 94% yield) of product 2a. |
92% | With 1,4-butanediol dimethylacrylate crosslinked polyacenaphthylene supported t-butyl chromate In chloroform at 30℃; for 23h; | |
72% | With bromine; oxygen; dimethyltin dichloride; potassium carbonate In water at 0℃; for 2h; Darkness; Green chemistry; | |
68% | With dihydroxy-methyl-borane; potassium carbonate; dibromoisocyanuric acid In water at 0℃; for 8h; Darkness; Electrochemical reaction; Green chemistry; | |
60% | With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; butanedial; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃; for 1h; | |
52% | With (Bu4N)4W10O32; sulfuric acid; oxygen In water at 25℃; for 0.116667h; Irradiation; | |
With potassium hydroxide In tetrahydrofuran | ||
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 21℃; for 6h; | ||
With polystyrene-supported hypervalent iodine(V) reagent In 1,2-dichloro-ethane at 60℃; for 3h; | ||
With sulfuric acid; oxygen In water at 25℃; Irradiation; | ||
96 %Chromat. | Stage #1: cis-1,2-cyclohexane With di(n-butyl)tin oxide In methanol for 1h; Reflux; Stage #2: With tetraethylammonium bromide In methanol at 0℃; Electrolysis; | |
23 %Spectr. | With tetrabutylphosphonium decatungstate; diphenyldisulfane In acetonitrile for 18h; Cooling with ice; UV-irradiation; Inert atmosphere; Sealed tube; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 95% 2: 1% | With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 2.5h; | |
1: 53% 2: 30% | With fluorine In acetonitrile at 20℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 74% 2: 13% 3: 8% | With sodium bromate; sodium hydrogensulfite In dichloromethane; water; acetonitrile at 20℃; for 3h; | |
1: 18% 2: 51% 3: 19% | With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 2h; | |
With 2O34W9Zn(12-)*W(6+)*3Zn(2+)*2H2O; dihydrogen peroxide In water; acetonitrile at 135℃; for 0.25h; Microwave irradiation; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 64% 2: 31% 3: 5% | With oxygen In acetonitrile at 80℃; for 5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 56% 2: 41% 3: 3% | With oxygen In acetonitrile at 80℃; for 5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With dihydrogen peroxide In water at 80℃; for 24h; Further byproducts given; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
1: 45% 2: 34% | With potassium peroxomonosulfate at 20℃; for 18h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: 1.) p-toluenesulfonic acid / 1.) toluene, reflux 2: 41.1 percent / 8 h / Heating 3: 50.3 percent / polyphosphoric acid / 1.5 h / 60 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hydrogen at 100℃; for 72h; | ||
With hydrogen In water at 65℃; for 15h; Schlenk technique; Green chemistry; | ||
7 %Chromat. | With hydrogen In tetrahydrofuran at 60℃; for 3.5h; Autoclave; Glovebox; | 3.3 General procedure for the catalytic hydrogenation reactions General procedure: Autoclave Par 477 equipped with PID control temperature and reservoir for kinetic measurements and HEL 24 Cat reactor for substrate scope were used as reactors for the hydrogenation reactions. In a typical experiment, the autoclave was charged in the glove-box with the desired Rh NPs (1.25 or 0.625mol%; the catalyst concentration was calculated based on the total number of metallic Rh atoms in the surface of the NPs) and the substrate (0.124M) in THF. Molecular hydrogen was then introduced until the desired pressure was reached and the reaction was stirred for the desired reaction time at the selected temperature. At the end of the reaction, the autoclave was depressurised and the solution was filtered through silica for subsequent analysis by GC. The conversion and selectivities for each reaction product were determined by GC-FID on an Agilent Technologies 7890A spectrometer, with a HP-5 column (30m×0.25mm×0.25μm) using undecane as internal standard. TOF was defined as moles of products per mol Rh at the surface of the NPs per hour. |
With palladium on activated carbon; sodium formate; sodium hydroxide In water at 90℃; for 0.25h; Flow reactor; Green chemistry; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With phosphoric acid; 5% Pd(II)/C(eggshell); hydrogen In water at 149.84℃; for 1.66667h; Autoclave; | Kinetic study of anisole, catechol, and guaiacol hydrodeoxygenation conversion General procedure.The kinetic study of anisole, catechol, or guaiacol was carried out as follows. The reactant (0.016 mol) was mixed with 0.5 wt.% H3PO4-H2O solution (80 ml) and 5 wt.% Pd/C (0.020 g), and then such mixture was hydrodeoxygenated at 423 K and 5 MPa H2 with a stirring speed of 1000 rpm. After reaction, ethyl acetate was used to extract the organic phase, and the liquid products including aqueous phase and organic phase were analyzed through GC and GC-MS with internal standards (i.e., 2-isopropylphenol for the organic phase and acetone for the aqueous phase). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With dihydrogen peroxide In N,N-dimethyl-formamide at 75℃; for 10h; | 2.4.1. Oxidation of cyclohexene with different solvents 50 mg of UF-MCN-1.0, 10 mmol of cyclohexene and 5 mlof solvent such as ethanol or acetone or acetonitrile or N,Ndimethylformamide(DMF) were stirred in a glass reactor(Chemistation II, Japan) and heated to 75 C. The 40 mmol of hydrogen peroxide was introduced through the septum to the reactant mixture. After the reaction was completed, the filtrate was collected and the reaction mixture was diluted with acetone and subjected to GC and GC-MS analysis. | |
With dihydrogen peroxide In methanol; water at 70℃; for 6h; Green chemistry; | 2.4. Catalytic activity General procedure: Polymer-bound 1-3 were used as catalysts for oxidation of styrene, cyclohexene, allylbenzene,and cis-cyclooctene. For the best catalytic performance, optimized reaction conditionswere achieved by changing the various reaction parameters such as catalyst amount, oxidantamount, solvent amount, and nature of solvent while taking styrene as the representativealkene. In a typical reaction, 10-mL methanolic solution of styrene (0.52 g, 5 mmol) wasreacted with dilute aqueous solution of 30% H2O2 (1.14 g, 10 mmol) in the presence of preswelledcatalysts 1-3 (0.015 g) at 70 °C for 6 h. Catalysts were swelled in methanol for 12 hbefore using in oxidation reactions. In a fixed time interval, a small portion of reaction mixturewas withdrawn and analyzed in a gas chromatograph fitted with a HP-5 capillary columnand a FID detector. Percent conversion was estimated using a calibration plot. Catalyticoxidation of cyclohexene, allylbenzene, and cis-cyclooctene under optimized reaction conditionswas also examined and analyzed through GC periodically. Identities of the reactionproducts were established by GC-MS analysis using a thermo ISQ QD single quadrupolemass analyzer system equipped with a TG-5MS column (30 m × 0.32 μm × 0.25 μm); percentconversions of the substrates were calculated using the following equation. | |
With dihydrogen peroxide; C17H13Cl2MoN3O2S In methanol at 80℃; for 8h; |
With tetra(n-butyl)ammonium hydroxide; dihydrogen peroxide; (Bu4N)2[W5O18Zr(H2O)3] In water at 50℃; for 1.5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With hydrogen In water at 45℃; for 15h; Schlenk technique; Green chemistry; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
65% | With zinc(II) chloride In methanol at 90℃; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With dihydrogen peroxide In acetonitrile at 70℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: cyclohexane With 2C60H50O21Si10(12-)*9Cu(2+)*6Na(1+); water; dihydrogen peroxide; nitric acid; oxygen-18 In acetonitrile at 60℃; Stage #2: With triphenylphosphine |
Tags: 533-60-8 synthesis path| 533-60-8 SDS| 533-60-8 COA| 533-60-8 purity| 533-60-8 application| 533-60-8 NMR| 533-60-8 COA| 533-60-8 structure
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
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P222 | Do not allow contact with air. |
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P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
Sorry,this product has been discontinued.
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