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Chemical Structure| 5331-64-6 Chemical Structure| 5331-64-6

Structure of 5331-64-6

Chemical Structure| 5331-64-6

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Product Details of [ 5331-64-6 ]

CAS No. :5331-64-6
Formula : C11H12O2
M.W : 176.21
SMILES Code : CCC(CC(C1=CC=CC=C1)=O)=O
MDL No. :MFCD11185178

Safety of [ 5331-64-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338

Application In Synthesis of [ 5331-64-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 5331-64-6 ]

[ 5331-64-6 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 100-52-7 ]
  • [ 78-93-3 ]
  • [ 6668-24-2 ]
  • [ 5331-64-6 ]
YieldReaction ConditionsOperation in experiment
With tert.-butylhydroperoxide; di-tert-butylhydroperoxide; tetra-(n-butyl)ammonium iodide; toluene-4-sulfonic acid; at 120℃; for 24h; General procedure: Under air atmosphere, aldehydes (0.3 mmol), TBAI (0.2 equiv),TBHP (2.0 equiv), DTBP (2.0 equiv), p-TsOH (0.1 equiv), and acetoneor other ketones (2 mL) were added to a screw-capped vial.The reaction vial was placed in a temperature-controlled aluminum-heating block set at 120 C. The reaction progress wasmonitored by TLC. After the completion of the reaction, the vialwas removed from the heating block and was left to cool to ambienttemperature. The solution was filtered through a short columnof silica gel and washed with EtOAc. The filtrate was concentratedunder reduced pressure to leave a crude product, which was purifiedby flash column chromatography on silica gel with petroleumether/EtOAc as an eluent to give the desired product
 

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