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[ CAS No. 5335-84-2 ]

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Cat. No.: {[proInfo.prAm]}
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type HazMat fee
Excepted Quantity Free
Inaccessible (Haz class 6.1), Domestic USD 41.00
Inaccessible (Haz class 6.1), International USD 64.00
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 83.00
Accessible (Haz class 3, 4, 5 or 8), International USD 133.00
2D
Chemical Structure| 5335-84-2
Chemical Structure| 5335-84-2
Structure of 5335-84-2 *Storage: {[proInfo.prStorage]}

Quality Control of [ 5335-84-2 ]

Related Doc. of [ 5335-84-2 ]

SDS
Alternatived Products of [ 5335-84-2 ]
Alternatived Products of [ 5335-84-2 ]

Product Details of [ 5335-84-2 ]

CAS No. :5335-84-2MDL No. :MFCD00017832
Formula : C12H8Br2S2 Boiling Point : -
Linear Structure Formula :-InChI Key :N/A
M.W :376.13Pubchem ID :-
Synonyms :

Computed Properties of [ 5335-84-2 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 5335-84-2 ]

Signal Word:DangerClass:8
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P332+P313-P362-P403+P233-P405-P501-P273-P391UN#:1759
Hazard Statements:H315-H318-H335-H410Packing Group:
GHS Pictogram:

Application In Synthesis of [ 5335-84-2 ]

  • Upstream synthesis route of [ 5335-84-2 ]
  • Downstream synthetic route of [ 5335-84-2 ]

[ 5335-84-2 ] Synthesis Path-Upstream   1~3

  • 1
  • [ 5335-84-2 ]
  • [ 98-58-8 ]
Reference: [1] Synlett, 2009, # 17, p. 2773 - 2776
  • 2
  • [ 201230-82-2 ]
  • [ 622-29-7 ]
  • [ 106-53-6 ]
  • [ 5335-84-2 ]
  • [ 27466-83-7 ]
  • [ 53136-21-3 ]
Reference: [1] Canadian Journal of Chemistry, 1986, vol. 64, p. 2010 - 2012
  • 3
  • [ 5335-84-2 ]
  • [ 100-01-6 ]
  • [ 21969-12-0 ]
YieldReaction ConditionsOperation in experiment
80% With tert.-butylnitrite; ascorbic acid In acetonitrile at 20℃; for 4 h; Schlenk technique; Inert atmosphere General procedure: For solid disulfide: A 10-mL Schlenk tube with a magnetic stirring bar was charged with aniline(0.2 mmol) and disulfide (0.2 mmol). The tube was evacuated and backfilled with dry nitrogen (this operation was repeated three times). Acetonitrile (1 mL) was added by syringe, followed by L-ascorbicacid (0.5 equiv., 20 mg) dissolved in 0.1 mL DMSO. For liquid disulfide: A 10-mL Schlenk tube with a magnetic stirring bar was charged with aniline(0.2 mmol). The tube was evacuated and backfilled with dry nitrogen (this operation was repeated three times). Acetonitrile (1 mL) was added by syringe, followed by disulfide (0.2 mmol or 0.4mmol) and L-ascorbic acid (0.5 equiv., 20 mg) dissolved in 0.1 mL DMSO.The mixture was stirred vigorously for 1 minute before t-BuONO (0.3 mmol, 36 μL) was added via syringe. After the resulting mixture was stirred at 20 °C for 4 hours, the solvent was removed under reduced pressure. Purification of the crude product was achieved by column chromatography
Reference: [1] Synlett, 2015, vol. 26, # 13, p. 1841 - 1846
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