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Chemical Structure| 5461-30-3 Chemical Structure| 5461-30-3

Structure of 5461-30-3

Chemical Structure| 5461-30-3

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Product Details of [ 5461-30-3 ]

CAS No. :5461-30-3
Formula : C6H13NO2
M.W : 131.17
SMILES Code : O=C(OCCCC)NC

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Application In Synthesis of [ 5461-30-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 5461-30-3 ]

[ 5461-30-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 105-40-8 ]
  • [ 3180-09-4 ]
  • 2-butylphenyl-N-methylcarbamate [ No CAS ]
  • [ 5461-30-3 ]
YieldReaction ConditionsOperation in experiment
96% With trichlorophosphate; In 1,2-dichloro-ethane; EXAMPLE 3 2-SEC BUTYLPHENYL N-METHYLCARBAMATE To a solution of 2-sec butylphenol (1.5 g, 0.01 mole) and ethyl N-methylcarbamate (1.03 g, 0.01 mole) in ethylene dichloride (6 ml) was added phosphoryl chloride (0.77g, 0.05 mole) and the reaction mixture was refluxed under stirring for twenty hours. It was poured onto ice-cold water. The organic layer was separated and aqueous layer was extracted with dichloroethane. The combined organic layers were washed with water, dried (Na2SO4) and distilled to give liquid residue, which was further purified by distillation to give 2-sec butyl N-methylcarbamate [96% by GLC, DV-101 (3%), 150oC, nitrogen, 30 ml/min.] as a liquid, b.p. 110oC (vap.)/4 mm; IR: 3320 (N-H), 1730 (-COO-), 1535,1490 and 750 (aromatic); PMR (CDCl3, 90 MHz): 0.81 (3H, t , primary methyl of side chain, 1.58 (2H, m , methylene protons of side chain), 2.88 (4H, doublet overlapping a multiplet, and benzylic proton), 4.97 (1H, br s , N- H) and 6.95 to 7.25 (4H, m , aromatic).
 

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