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Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
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CAS No. : | 57774-14-8 | MDL No. : | MFCD31537213 |
Formula : | C44H26Cl4N4Ni | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 811.21 | Pubchem ID : | - |
Synonyms : |
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Signal Word: | Danger | Class: | 6.1 |
Precautionary Statements: | P501-P272-P260-P270-P202-P201-P264-P280-P284-P302+P352-P308+P313-P362+P364-P304+P340-P333+P313-P301+P312+P330-P405 | UN#: | 2811 |
Hazard Statements: | H302-H372-H317-H334-H350 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In dichloromethane Electrolysis; exhaustive electrolysis at potential of first oxidn. wave with 0.1 M TBA(PF6) at room temp.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In dichloromethane Electrolysis; exhaustive electrolysis at redn. potential at room temp.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In 1,2-dichloro-benzene N2, refluxed for 2 h with 2 equiv. of NCS; solvent removed (vac.), chromy. (silica gel, CHCl3), pptd. (CHCl3/methanol), recrystd. (CHCl3/methanol, room temp., 3 wk); elem. anal.; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In N,N-dimethyl-formamide |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
0.42 g | With N-chloro-succinimide In 1,2-dichloro-benzene for 2h; Inert atmosphere; Reflux; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: N-chloro-succinimide / 1,2-dichloro-benzene / 2 h / Inert atmosphere; Reflux 2: sulfuric acid / dichloromethane / 4 h / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
99.4% | In N,N-dimethyl-formamide; for 12h;Reflux; | The liquid-solid multiphase reaction diagram shown in separatesync reactor to four pairs chlorophenyl porphine nickel acetylacetonate and as raw material for thepreparation of air oxidation of four pairs chlorophenyl porphyrin nickelproducts; wherein, stirring the reaction column diameter than 1:25; features aheated sedimentation column I and climate settlement of two equal andconsistent with the structure of the thermostat tower II settlement tower; thereaction liquid outlet from the reaction tower at the top of the tower at aheight of 2/5control the mixing tee reaction column under the reactionwas stirred and heated tower tower I communicated settlement, the settlement ofthe thermostat from the top of the column DMF solvent feed port was added tothe heterogeneous reaction sync separation reactor, filled with stirring untilthe reaction tower the reaction zone and the inner settling thermostatic columnI, elevated temperature to reflux temperature DMF, the four pairs chlorophenylporphine nickel acetylacetonate and 1: molar ratio, from the top of the columnthe reaction was stirred for raw feed of 14. when the port is addedcontinuously to maintain the four pairs chlorophenyl porphine reaction solutionat a concentration of 2wt% reacted, the reaction proceeds when the reactionmixture to a concentration of four pairs of nickel chlorophenyl porphyrinproduct reaches the saturated solubility, four pairs of chlorine porphyrincrystal precipitation of nickel, while four pairs chlorophenyl porphyrin nickelunder gravity from the stirring of the reaction tower reaction zone directlyinto the thermostat settlement settlement column I, at a time when thethermostat settling column I of the reaction mixture settlement were fourchlorophenyl porphyrin nickel-crowding rise into the stirred reaction column;when the ongoing reaction until I thermostatic settlement tower filled withfour pairs chlorophenyl porphyrin nickel, the reaction was stirred by thethree-way control Taqie change to a thermostat and filled with DMF settlementtower II communication, and settlement column I remove the thermostat, whichwill be directly taken four chlorophenyl porphyrin nickel, filtration, washedwith water, washed with ethanol, to give pure four pairs chlorophenyl porphyrinnickel products; thus alternating, continuous production. When thereaction is stable, sampling every 4 hours for four pairs chlorophenylporphyrin Ni purity of the product testing, and entering the fourthchlorophenyl porphine raw reaction system and get four pairs of nickel productchlorophenyl porphyrin the amount and composition of the reaction liquid isdetected, the calculated four pairs chlorophenyl porphyrin nickel yield andpurity results are shown in table 3. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
50% | With aluminum (III) chloride In N,N-dimethyl-formamide for 2.5h; Reflux; | 7 Example Seven: Add 2500mL DMF into a stirred reactor with a reflux condenser, add 2 moles of anhydrous aluminum trichloride, 0.75 moles of 4-chlorobenzaldehyde, 0.5 moles of pyrrole and 2 moles of nickel acetate under stirring, and heat the reaction mixture to After refluxing and maintaining the reaction for 2.5 hours, the reaction was stopped, the temperature was lowered to below 373K, and 2500mL ethanol was added to continue cooling. After standing overnight at 273K, purple crystals of tetrakis(4-chlorophenyl)nickel porphyrin were obtained by suction filtration with a yield of 50%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In N,N-dimethyl-formamide |