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[ CAS No. 58086-67-2 ]

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Chemical Structure| 58086-67-2
Chemical Structure| 58086-67-2
Structure of 58086-67-2 * Storage: {[proInfo.prStorage]}

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Product Details of [ 58086-67-2 ]

CAS No. :58086-67-2 MDL No. :MFCD00011983
Formula : C13H14FNO3S Boiling Point : -
Linear Structure Formula :- InChI Key :N/A
M.W :283.32 g/mol Pubchem ID :-
Synonyms :

Safety of [ 58086-67-2 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 58086-67-2 ]

  • Downstream synthetic route of [ 58086-67-2 ]

[ 58086-67-2 ] Synthesis Path-Downstream   1~15

  • 1
  • [ 372-48-5 ]
  • [ 80-48-8 ]
  • [ 58086-67-2 ]
YieldReaction ConditionsOperation in experiment
89% In toluene for 1.5h; Heating;
89% In toluene Reflux; C Preparation of 2-fluoro-N-methylpyridinium tosylate from 2-fluoropyridine In a 25 ml round-bottomed flask topped with a condenser, 2-fluoropyridine (2 g, 20.6 mmol) was diluted in 15 ml of toluene.Using a syringe, methyl tosylate (3.83 g, 20.6 mmol) was added to this solution.The mixture was refluxed with magnetic stirring overnight.During the reaction a second yellow phase appeared which crystallized at room temperature.The precipitate was then filtered over a Büchner funnel.The traces of solvent were removed via evaporation under a reduced pressure of around 20 mmHg.The product was in the form of a yellow solid and was obtained with a yield of 89% (5.16 g).
at 70℃; for 6h;
1 2-Fluoro-1-methylpyridinium 4-methylbenzenesulphonate PREPARATION 1 2-Fluoro-1-methylpyridinium 4-methylbenzenesulphonate 10 mmol of 2-fluoropyridine and 10 mmol of methyl 4-methylbenzenesulphonate are mixed in a 50 ml round-bottomed flask and stirred for 6 hours at 70° C. under a nitrogen atmosphere. The salt obtained in the form of a white solid is used without additional purification in the following step.

  • 2
  • [ 57-88-5 ]
  • [ 58086-67-2 ]
  • Toluene-4-sulfonate2-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yloxy]-1-methyl-pyridinium; [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine In dichloromethane for 1h;
  • 3
  • [ 90700-15-5 ]
  • [ 58086-67-2 ]
  • Toluene-4-sulfonic acid (S)-2-benzyloxy-1-((3aR,4S,6aR)-2,2-dimethyl-6-oxo-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine Ambient temperature;
  • 4
  • (S)-1-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-en-1-ol [ No CAS ]
  • [ 58086-67-2 ]
  • Toluene-4-sulfonic acid (S)-1-((4R,5S)-5-benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-but-3-enyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine
  • 5
  • [ 58086-67-2 ]
  • [ 100-51-6 ]
  • [ 58086-65-0 ]
YieldReaction ConditionsOperation in experiment
50% With triethylamine In acetone for 1h; Ambient temperature;
  • 6
  • [ 631-61-8 ]
  • [ 33069-62-4 ]
  • [ 58086-67-2 ]
  • Taxol-2'-methylpyridiniumacetat [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine 1.) CH2Cl2, r.t., 30 min, 2.) methanol; Yield given. Multistep reaction;
  • 7
  • [ 58086-67-2 ]
  • [ 159500-67-1 ]
  • C51H55N2O14S(1+)*C7H7O3S(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine In dichloromethane at 25℃; for 0.583333h;
  • 8
  • [ 58086-67-2 ]
  • [ 183271-31-0 ]
  • Toluene-4-sulfonate2-{2-[2-(3,6-bis-acetylamino-9H-xanthen-9-yl)-benzyloxymethoxy]-ethoxy}-1-methyl-pyridinium; [ No CAS ]
  • 9
  • [ 58086-67-2 ]
  • [ 106061-15-8 ]
  • Toluene-4-sulfonic acid 3-[(8-methoxy-1,2,3,4-tetrahydro-naphthalen-2-yl)-propyl-amino]-propyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
With TEA In toluene
  • 10
  • [ 14212-87-4 ]
  • [ 58086-67-2 ]
  • 2-(2,2-di-morpholin-4-yl-vinyl)-1-methyl-pyridinium; toluene-4-sulfonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In acetonitrile at 20℃;
  • 11
  • [ 3433-56-5 ]
  • [ 58086-67-2 ]
  • 1-Methyl-2-[2-phenyl-2-(1-pyrrolidinyl)ethenyl]pyridinium hexafluoro-phosphate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With ammonium hexafluorophosphate In acetonitrile at 80℃; for 2h;
  • 12
  • [ 170988-81-5 ]
  • [ 58086-67-2 ]
  • [ 5439-14-5 ]
  • [ 170987-74-3 ]
YieldReaction ConditionsOperation in experiment
In dichloromethane; chloroform; water 1.d c-2 (d) To a solution of 4-(2-aminobenzoyl)-1-(4-methoxybenzyl)-1,2,3-triazole-5-carboxylic acid (c-1) (6.62 g, 18.8 mmole) in methylene chloride (120 ml) were added under an argon atmosphere and ice cooling tributyamine (4.7 ml, 19.7 mmole), 2-fluoro-1-methylpyridinium p-toluenesulfonate (5.85 g, 20.7 mmole) and 3,4-dihydro-2H-pyrido[1,2-a]pyrimidin-2-one (3.34 g, 22.5 mmole), and the mixture was stirred for 1 hour. Chloroform and water were added to the reaction mixture, which was extracted with chloroform. The chloroform layer was washed with dilute hydrochloric acid, a saturated aqueous sodium hydrogen carbonate solution, and saturated aqueous saline in this sequence. The organic layer was dried with anhydrous magnesium sulfate, and the solvent was removed under reduced pressure. Crystallized solids were collected by filtration and washed with diethyl ether to give 3-(4-methoxybenzyl)-4(5H),10-dioxo-3H-1,2,3-triazolo[5.4-c][1]benzazepine (d-1: LP) (2.96 g, 47.1%) as a yellow crystalline powder.
  • 13
  • [ 34626-95-4 ]
  • [ 58086-67-2 ]
  • [ 58501-81-8 ]
YieldReaction ConditionsOperation in experiment
With triethylamine In chloroform for 1h;
  • 14
  • poly(trimellitic anhydride-co-(4,4\-methylenedianiline)), derivatized with N-methylethanolamine [ No CAS ]
  • [ 58086-67-2 ]
  • poly(trimellitic anhydride-co-(4,4\-methylenedianiline)), derivatized with N-methylethanolamine followed by 2-fluoro-1-methylpyridinium p-toluenesulfonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine In chloroform; N,N-dimethyl-formamide at 20℃; for 3.5h;
  • 15
  • [ 58086-67-2 ]
  • C14H14NO(1+)*F6P(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: NH4PF6 / acetonitrile / 2 h / 80 °C 2: cc. HCl / 3 h / Heating
Historical Records

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[ 58086-67-2 ]

Fluorination Reagents

Chemical Structure| 59387-91-6

[ 59387-91-6 ]

1,3-Dimethyl-2-fluoropyridiniumtoluene-4-sulfonate

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