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Chemical Structure| 60839-74-9 Chemical Structure| 60839-74-9

Structure of 60839-74-9

Chemical Structure| 60839-74-9

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Product Details of [ 60839-74-9 ]

CAS No. :60839-74-9
Formula : C18H33I
M.W : 376.36
SMILES Code : CCCCC/C=C\C/C=C\CCCCCCCCI

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Application In Synthesis of [ 60839-74-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 60839-74-9 ]

[ 60839-74-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 4102-60-7 ]
  • [ 60839-74-9 ]
YieldReaction ConditionsOperation in experiment
With sodium iodide; In acetone; at 55℃; for 2h;Inert atmosphere; Reflux; Intermediate 127b: (6Z,9Z)-18-iodooctadeca-6,9-diene To a solution of intermediate 127a (14.0 g, 42.659 mmol) in acetone (150 mL) in a RBF charged with a magnetic stir bar under N2 was added sodium iodide (12.7 g, 85.3 mmol). The reaction was heated to reflux (55 C) for 2 hours, after which it was cooled to room temperature and the solids were filtered off. The solvent was evaporated and the remaining solids were removed by dissolution in H20 (100 mL) and extraction with DCM (2 x 200 mL). The combined organic layers were dried over Na2S04 and evaporated to dryness to afford the desired product as a crude pale brown liquid (15.5 g, 97%). This material was used in the next step without further purification. TLC: Rf = 0.6 (100% pentane), PMA active.
 

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