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[ CAS No. 612-87-3 ] {[proInfo.proName]}

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Chemical Structure| 612-87-3
Chemical Structure| 612-87-3
Structure of 612-87-3 * Storage: {[proInfo.prStorage]}
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Product Details of [ 612-87-3 ]

CAS No. :612-87-3 MDL No. :MFCD00845987
Formula : C14H10O4 Boiling Point : -
Linear Structure Formula :- InChI Key :KHZYMPDILLAIQY-UHFFFAOYSA-N
M.W : 242.23 Pubchem ID :96533
Synonyms :

Safety of [ 612-87-3 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 612-87-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 612-87-3 ]

[ 612-87-3 ] Synthesis Path-Downstream   1~50

  • 1
  • [ 612-75-9 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
With potassium permanganate
With sodium hydroxide; potassium permanganate Heating;
  • 4
  • [ 585-76-2 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
With potassium hydroxide; palladium on activated charcoal; Lindlar's catalyst; hydrazine hydrate at 140℃;
With potassium hydroxide; palladium on activated charcoal
  • 5
  • [ 580-82-5 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
With sulfuric acid
  • 7
  • [ 612-87-3 ]
  • [ 106-95-6 ]
  • [ 107240-39-1 ]
YieldReaction ConditionsOperation in experiment
With potassium carbonate In N,N-dimethyl-formamide for 18h; Ambient temperature;
  • 8
  • [ 618-89-3 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 1.) potassium iodide, nickel bromide, triphenylphosphine; 2.) zinc, nickel bromide, potassium iodide / 1.) DMF; 2.) DMF, hexamethylphosphoramide 2: alkaline hydrolysis
  • 9
  • [ 612-87-3 ]
  • [ 53172-64-8 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: SOCl2 / 2 h / Heating 2: AlCl3 / 3 h / Heating
Multi-step reaction with 2 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene
  • 10
  • [ 612-87-3 ]
  • [ 172603-95-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: SOCl2 / 2 h / Heating 2: AlCl3 / 3 h / Heating 3: 77 percent / N2H4*H2O / ethanol / 48 h / Heating 4: 74 percent / MnO2, KOH / CH2Cl2; ethanol / 1 h
  • 11
  • [ 612-87-3 ]
  • [ 172603-96-2 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: SOCl2 / 2 h / Heating 2: AlCl3 / 3 h / Heating 3: 77 percent / N2H4*H2O / ethanol / 48 h / Heating
  • 12
  • [ 19718-35-5 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: diethyl ether; aqueous hydrochloric acid 2: aqueous HCl / Diazotization.Behandlung der Diazoniumsalz-Loesung mit wss. H3PO2 3: butyl lithium; diethyl ether / Aufgiessen der Reaktionsloesungen auf festes Kohlendioxid
  • 13
  • [ 618-91-7 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: copper powder / 260 °C 2: sulfuric acid
  • 14
  • [ 577-19-5 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: tin; aq. NaOH solution 2: diethyl ether; aqueous hydrochloric acid 3: aqueous HCl / Diazotization.Behandlung der Diazoniumsalz-Loesung mit wss. H3PO2 4: butyl lithium; diethyl ether / Aufgiessen der Reaktionsloesungen auf festes Kohlendioxid
  • 15
  • [ 34237-98-4 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: aqueous HCl / Diazotization.Behandlung der Diazoniumsalz-Loesung mit wss. H3PO2 2: butyl lithium; diethyl ether / Aufgiessen der Reaktionsloesungen auf festes Kohlendioxid
  • 16
  • 3-methyl-1-<i>m</i>-tolyl-cyclohexa-1,3-diene [ No CAS ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: palladium/charcoal 2: KMnO4
  • 17
  • [ 82942-79-8 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: diethyl ether 2: palladium/charcoal 3: KMnO4
  • 18
  • [ 28987-79-3 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: diethyl ether 2: diethyl ether 3: palladium/charcoal 4: KMnO4
  • 19
  • [ 401-81-0 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: copper-powder 2: H2SO4
  • 20
  • [ 612-87-3 ]
  • [ 53172-65-9 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene
  • 21
  • [ 612-87-3 ]
  • C70H64P2(2+)*2ClO4(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene 3: (i) LiAlH4, THF, (ii) /BRN= 3633387/, DMF 4: (i) NaOMe, DMF, (ii) AgClO4, Et2O
  • 22
  • [ 612-87-3 ]
  • C62H50P2(2+)*2Br(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene 3: (i) LiAlH4, THF, (ii) /BRN= 3633387/, DMF
  • 23
  • [ 612-87-3 ]
  • (R)-[3'-((S)-Hydroxy-phenyl-methyl)-biphenyl-3-yl]-phenyl-methanol [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene 3: LiAlH4 / tetrahydrofuran
  • 24
  • [ 612-87-3 ]
  • (R)-[3'-((R)-Hydroxy-phenyl-methyl)-biphenyl-3-yl]-phenyl-methanol [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene 3: LiAlH4 / tetrahydrofuran
  • 25
  • [ 612-87-3 ]
  • (S)-(4-tert-Butyl-phenyl)-{3'-[(R)-(4-tert-butyl-phenyl)-hydroxy-methyl]-biphenyl-3-yl}-methanol [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene 3: LiAlH4 / tetrahydrofuran
  • 26
  • [ 612-87-3 ]
  • (S)-(4-tert-Butyl-phenyl)-{3'-[(S)-(4-tert-butyl-phenyl)-hydroxy-methyl]-biphenyl-3-yl}-methanol [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: POCl3 2: (i) CdCl2, Et2O, (ii) /BRN= 2458036/, benzene 3: LiAlH4 / tetrahydrofuran
  • 27
  • [ 74124-79-1 ]
  • [ 612-87-3 ]
  • [ 1029978-09-3 ]
YieldReaction ConditionsOperation in experiment
71%
  • 28
  • [ 4916-57-8 ]
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 612-87-3 ]
  • [(1,1'-biphenyl-3,3'-diacetate)2(1,2-di(4-pyridyl))(cadmium(II))2](n) [ No CAS ]
YieldReaction ConditionsOperation in experiment
54% With NaOH In water High Pressure; H2bdpa:dpe:Cd:NaOH=2:2:2:3 molar ratio, heated at 180°C for 72 h; cooled at room temp. for 24 h, crysts. filtered, washed (H2O), dried (air); elem. anal.;
  • 29
  • [ 1092688-49-7 ]
  • [ 612-87-3 ]
  • [ 1092688-50-0 ]
YieldReaction ConditionsOperation in experiment
100% In toluene for 6h; Reflux;
  • 30
  • [ 612-87-3 ]
  • (R)-3,3'-bis(hydroxymethyl)-2,2'-dimethoxy-1,1'-binaphthyl [ No CAS ]
  • C76H56O12 [ No CAS ]
YieldReaction ConditionsOperation in experiment
5% With dmap; 4-(dimethylamino)pyridinium tosylate; diisopropyl-carbodiimide In dichloromethane Inert atmosphere;
  • 31
  • [ 480425-35-2 ]
  • [ 612-87-3 ]
  • 32
  • [ 612-87-3 ]
  • C52H48N2O18 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: thionyl chloride / tetrahydrofuran / Reflux 2.1: pyridine / tetrahydrofuran / 0.25 h / 20 °C 2.2: 15 h
  • 33
  • [ 612-87-3 ]
  • [ 1332636-98-2 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1.1: thionyl chloride / tetrahydrofuran / Reflux 2.1: pyridine / tetrahydrofuran / 0.25 h / 20 °C 2.2: 15 h 3.1: methanol; triethylamine / 14 h
  • 34
  • [ 19438-10-9 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 16 h / 20 - 90 °C 3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate / 1,4-dioxane / 14 h / 20 - 90 °C 4: water; lithium hydroxide / tetrahydrofuran; methanol / 20 °C
Multi-step reaction with 3 steps 1: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate / 1,4-dioxane / 14 h / 20 - 90 °C 3: water; lithium hydroxide / tetrahydrofuran; methanol / 20 °C
  • 35
  • [ 107658-28-6 ]
  • [ 612-87-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 16 h / 20 - 90 °C 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate / 1,4-dioxane / 14 h / 20 - 90 °C 3: water; lithium hydroxide / tetrahydrofuran; methanol / 20 °C
Multi-step reaction with 2 steps 1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate / 1,4-dioxane / 14 h / 20 - 90 °C 2: water; lithium hydroxide / tetrahydrofuran; methanol / 20 °C
  • 36
  • [ 7631-99-4 ]
  • [ 617-84-5 ]
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 612-87-3 ]
  • [Cd3Na4(1,1'-biphenyl-3,3'-dicarboxylate)5(N,N'-diethylformamide)7]·N,N'-diethylformamide [ No CAS ]
YieldReaction ConditionsOperation in experiment
86% at 20 - 90℃; for 168h; Synthesis of 1: A mixture of Cd(NO3)2·4H2O (0.25mmol, 0.0771g), 1,1′-biphenyl-3,3′-dicarboxylic acid (0.50mmol, 0.1211g), NaNO3 (0.25mmol, 0.0212g) was placed in a 20mL of Teflon-lined stainless steel vessel with 3mL of DME. The mixture was sealed and heated at 90°C for five days under autogeneous pressure and then cooled to room temperature in two days. Colorless crystals were collected, washed several times with ethanol and dried in air (yield 86% based on Cd). Anal. calcd for Cd3Na4C110H128N8O28 (2439.36): C, 54.11; H, 5.25; N, 4.59. Found: C, 53.96; H, 4.37; N, 4.22%. IR (KBr pellet, cm-1): 3434(w), 2978(w), 1655(vs), 1558(vs), 1386(vs), 1264(w), 1021(w), 761(s), 698(w).
  • 37
  • [ 617-84-5 ]
  • [ 100-26-5 ]
  • [ 64-17-5 ]
  • [ 612-87-3 ]
  • [ 7732-18-5 ]
  • indiun(III) nitrate [ No CAS ]
  • [Et2NH2]18[In18(biphenyl-3,3'-dicarboxylate)6(2,5-pyridinedicarboxylate)30]*12EtOH*12H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
30% With nitric acid at 110℃; for 168h;
  • 38
  • [ 366-18-7 ]
  • cobalt(II) nitrate hexahydrate [ No CAS ]
  • [ 612-87-3 ]
  • [Co(3,3'-biphenyldicarboxylato)(2,2'-bipyridine)]n [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% With sodium hydroxide In water at 140℃; for 72h; Autoclave; Synthesis of compound I. A mixture of Co(NO3)2 6H2O (29.7 mg, 0.10 mmol), 3,3'H2Bpdc (24.2 mg,0.10 mmol), 2,2'Bipy (15.6 mg, 0.10 mmol), and NaOH (8.0 mg, 0.20 mmol) in a solution of H2O (7 mL) were sealed into a 23 mL Teflon-lined stainless steel container under autogenous pressure, heated at 140°C for 3 days and cooled to room temperature for 24 h. Purple prismatic single crystals suitable for X-ray analyses were obtained. The yield was 67% (based on Co(II)). IR (KBr pellet; ν, cm-1): 2968 w, 1606 w, 1560 m, 1542 s,1473 w, 1441 m, 1419 s, 1385 m, 1361 s, 1269 w, 1157 w,1081w, 1022 w, 904 w, 863 w, 757 s.
  • 39
  • [ 37968-97-1 ]
  • cobalt(II) nitrate hexahydrate [ No CAS ]
  • [ 612-87-3 ]
  • [Co2(3,3'-biphenyldicarboxylato)2(4,4'-dipyridyl sulfide)2]n [ No CAS ]
YieldReaction ConditionsOperation in experiment
43% With sodium hydroxide In water at 140℃; for 72h; Autoclave; Synthesis of compound I. General procedure: A mixture of Co(NO3)2 6H2O (29.7 mg, 0.10 mmol), 3,3'H2Bpdc (24.2 mg,0.10 mmol), 2,2'Bipy (15.6 mg, 0.10 mmol), and NaOH (8.0 mg, 0.20 mmol) in a solution of H2O (7 mL) were sealed into a 23 mL Teflon-lined stainless steel container under autogenous pressure, heated at 140°C for 3 days and cooled to room temperature for 24 h. Purple prismatic single crystals suitable for X-ray analyses were obtained.
  • 40
  • [ 17252-51-6 ]
  • [ 612-87-3 ]
  • [ 557-34-6 ]
  • [Zn(3,3′-dpdc)(1,3-bis(4-pyridyl)propane)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% With sodium hydroxide In water at 120℃; for 72h;
  • 41
  • [ 17252-51-6 ]
  • cadmium(II) sulfate*8/3H2O [ No CAS ]
  • [ 612-87-3 ]
  • [Cd(3,3′-dpdc)(1,3-bis(4-pyridyl)propane)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
61% With sodium hydroxide In water at 140℃; for 72h;
  • 42
  • copper(ll) sulfate pentahydrate [ No CAS ]
  • [ 17252-51-6 ]
  • [ 612-87-3 ]
  • [Cu(3,3′-dpdc)(1,3-bis(4-pyridyl)propane)0.5] [ No CAS ]
YieldReaction ConditionsOperation in experiment
59% With sodium hydroxide In water at 160℃; for 72h;
  • 43
  • zinc(II) sulfate heptahydrate [ No CAS ]
  • [ 17252-51-6 ]
  • [ 612-87-3 ]
  • [Zn(3,3′-dpdc)(1,3-bis(4-pyridyl)propane)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide In water at 120℃; for 72h;
  • 44
  • [ 612-87-3 ]
  • [ 82409-02-7 ]
  • C46H72N6O10 [ No CAS ]
  • 45
  • [ 612-87-3 ]
  • [ 82409-02-7 ]
  • (x)C2HF3O2*C26H40N6O2 [ No CAS ]
  • 46
  • [ 612-87-3 ]
  • (x)C2HF3O2*C22H32N6O2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate / N,N-dimethyl-formamide / 0.08 h / 20 °C 1.2: 20 °C 2.1: dichloromethane / 6 h / 20 °C
  • 47
  • [ 612-87-3 ]
  • [ 117499-16-8 ]
  • C42H64N6O10 [ No CAS ]
YieldReaction ConditionsOperation in experiment
Stage #1: biphenyl-3,3'-dicarboxylic acid With (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Stage #2: bis(2-tert-butyloxycarbonylaminoethyl)amine With triethylamine In N,N-dimethyl-formamide at 20℃;
  • 48
  • terbium(III) nitrate pentahydrate [ No CAS ]
  • [ 612-87-3 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [(CH3)2NH2]2[(terbium(III))63-OH)8(3,3′-biphenyldicarboxylate)6(H2O)4] [ No CAS ]
YieldReaction ConditionsOperation in experiment
With o-fluoro-benzoic acid at 120℃; for 48h; High pressure;
  • 49
  • [ 849585-22-4 ]
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 612-87-3 ]
  • [ 33513-42-7 ]
  • 6C3H4O3(2-)*6C3H7NO*18H2O*6C14H8O4(2-)*2C2H8N(1+)*11Zn(2+) [ No CAS ]
  • 6C3H4O3(2-)*6C3H7NO*18H2O*6C14H8O4(2-)*2C2H8N(1+)*11Zn(2+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In ethanol at 140℃; for 96h; Sealed tube; Overall yield = 43 percent;
  • 50
  • [ 25487-66-5 ]
  • methyl 2-(6-bromobenzofuran-3-yl)acetate [ No CAS ]
  • [ 612-87-3 ]
  • C18H14O5 [ No CAS ]
YieldReaction ConditionsOperation in experiment
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In water; acetonitrile at 90℃; for 24h; Inert atmosphere; General Procedure A1: Preparation of 5- and 6-aryl analogues via Suzuki-Miyaura cross-coupling. General procedure: A solution of acetonitrile:water (4:1) was degassed by bubbling a stream of nitrogen through the solution for one hour. The aryl halide, boronic acid (6 eq.), caesium fluoride (3 eq.) and Pd(dppf)Cl2 (5 mol%) were added to the degassed solution (25 mL/mmol) and the suspension was heated to 90 °C under an atmosphere of nitrogen. After 16-24h the reaction mixture was partitioned between ethyl acetate and brine. The organic layer was washed with brine (x2), dried over magnesium sulfate then concentrated to the crude residue. In cases where the aryl halide or boronic acid contained a carboxylic acid the organic phase was washed with a saturated solution of sodium hydrogen carbonate (x3). The combined aqueous phases were acidified with concentrated HCl to pH 2, extracted with ethyl acetate (x3) then worked up as above to afford the crude compound.
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