Name: 61822-18-2|2,7-Dimethoxy-9H-carbazole|99%
Brand: Ambeed
SKU: A505678
Rating: 98 (26 reviews)

1
[ 61822-18-2 ]
[ 552860-96-5 ]

Yield	Reaction Conditions	Operation in experiment
85%	With N-Bromosuccinimide In chloroform; acetic acid at 20℃; for 12h;
	Multi-step reaction with 2 steps 1.1: 67 percent / bromine / acetic acid / 100 °C 2.1: butyllithium / tetrahydrofuran / -78 °C 2.2: H₂O / tetrahydrofuran
	With N-Bromosuccinimide In tetrahydrofuran at 0 - 20℃;	7 Synthesis example 7 3,6-dibromo-2,7-dimethoxycarbazole In a flask, covered with aluminum foil, a stirred solution of 1.48 g (6.5 mmol) 2,7-dimethoxycarbazole in 60 ml tetrahydrofuran was cooled to 0 °C. 2.3 g (13 mmol) N-bromosuccinimide was added in small portions. The mixture was allowed to warm to room temperature overnight. THF was evaporated and the product was used without further purification. 1H NMR (DMSO-d6): δ 11.30 (s, 1H), 8.30 (s, 2H), 7.13 (s, 2H), 3.90 (s, 6H). 13C NMR (DMSO-d6): δ 153, 140, 123, 116, 102, 94, 56.

Reference： [1]Bouchard, Jimmy; Belletete, Michel; Durocher, Gilles; Leclerc, Mario [Macromolecules, 2003, vol. 36, # 12, p. 4624 - 4630]
[2]Bouchard, Jimmy; Wakim, Salem; Leclerc, Mario [Synthetic Communications, 2004, vol. 34, # 15, p. 2737 - 2742]
[3]Current Patent Assignee: KONINKLIJKE PHILIPS ELECTRONICS NV - EP1838671, 2008, B1 Location in patent: Page/Page column 9; 10

2
[ 61822-18-2 ]
[ 758716-63-1 ]

Yield	Reaction Conditions	Operation in experiment
67%	With bromine In acetic acid at 100℃;

Reference： [1]Bouchard, Jimmy; Wakim, Salem; Leclerc, Mario [Synthetic Communications, 2004, vol. 34, # 15, p. 2737 - 2742]

3
[ 61822-18-2 ]
[ 552860-97-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 85 percent / N-bromosuccinimide / CHCl₃; acetic acid / 12 h / 20 °C 2: 95 percent / sodium hydroxide / tetrabutylammonium hydrogen sulfate / acetone / 24 h / Heating

Reference： [1]Bouchard, Jimmy; Belletete, Michel; Durocher, Gilles; Leclerc, Mario [Macromolecules, 2003, vol. 36, # 12, p. 4624 - 4630]

4
[ 61822-18-2 ]
2,7-dihydroxy-9H-carbazole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With pyridine hydrochloride In water	1.A A. A. Preparation of 2,7-dihydroxy-9H-carbazole 2,7-Dimethoxy-9H-carbazole (1.94 g; prepared according to the process described in M. H. Litt, et al., Macromolecules, 18, p. 1388 (1985)) was mixed with pyridine hydrochloride (6.39 g) and the resulting mixture was stirred at 232° C. for 20 minutes. The reaction liquid was cooled to room temperature. Water was added to the mixture to precipitate a crude product, which was then washed with water and dried under reduced pressure at 60° C. to yield the title compound (1.50 g). Rf=0.27 (1:1 hexane/ethyl acetate); 1H-NMR (CDCl3): 10.61 (1H, br), 9.13 (2H, s), 7.64 (2H, d, J=8.3), 6.71 (2H, d, J=2.0), 6.53 (2H, dd, J=8.3, 2.0); Mass (m/e): 199 (M+).

Reference： [1]Current Patent Assignee: ASAHI KASEI CORPORATION - US2003/40538, 2003, A1

5
[ 61822-18-2 ]
[ 696-62-8 ]
[ 815632-42-9 ]

Yield	Reaction Conditions	Operation in experiment
86%	With potassium carbonate In 1,2-dichloro-benzene for 20h; Heating / reflux;	26 Synthesis example 26 2,7-dimethoxy-9-(4-methoxyphenyl)carbazole A mixture of 0.5 g (2 mmol) 2,7-dimethoxycarbazole, 1.0 g (4 mmol) 4-iodoanisole, 0.35 g (2.5 mmol) potassium carbonate, 0.15 g (2 mmol) copper and 23 mg 18-crown-6 in 5 ml 1,2-dichlorobenzene was evacuated, charged with argon and refluxed during 20 hours. Afterwards, the reaction mixture was allowed to cool to room temperature and filtered. Then an extraction of the filtrate using toluene and water was performed, followed by drying the organic layer over MgSO4, filtration and evaporation of the solvents. 0.64 g (86 %) of product was obtained after column chromatography (SiO2, gradient from pure hexane to pure dichloromethane) followed by crystallisation from dichloromethane and methanol. 1H NMR (CDCl3): δ 7.90 (d, J=8 Hz, 2H), 7.44 (d, J=8 Hz, 2H), 7.12 (d, J=8 Hz, 1H), 6.86 (dd, J=1.5 Hz, J=8 Hz, 2H), 6.75 (d, J=1.5 Hz, 2H), 3.92 (s, 3H), 3.82 (s, 6H). 13C NMR (CDCl3): δ 159, 158, 143, 130, 129, 120, 117, 115, 108, 94, 56, 56. mp: 143 °C.

Reference： [1]Current Patent Assignee: KONINKLIJKE PHILIPS ELECTRONICS NV - EP1838671, 2008, B1 Location in patent: Page/Page column 19

6
[ 61822-18-2 ]
[ 529-28-2 ]
[ 890079-92-2 ]

Yield	Reaction Conditions	Operation in experiment
81%	With potassium carbonate In 1,2-dichloro-benzene for 40h; Heating / reflux;	27 Synthesis example 27 2,7-dimethoxy-9-(2-methoxyphenyl)carbazole A mixture of 0.5 g (2 mmol) 2,7-dimethoxycarbazole, 1.0 g (4 mmol) 2-iodoanisole, 0.35 g (2.5 mmol) potassium carbonate, 0.15 g (2 mmol) copper and 23 mg 18-crown-6 in 5 ml 1,2-dichlorobenzene was evacuated, charged with argon and refluxed during 40 hours. Afterwards, the reaction mixture was allowed to cool to room temperature and filtered. Then an extraction of the filtrate using toluene and water was performed, followed by drying the organic layer over MgSO4, filtration and evaporation of the solvents. 0.6 g (81 %) of product was obtained after column chromatography (SiO2, gradient from pure hexane to pure dichloromethane). 1H NMR (CDCl3): δ 7.90 (d, J=8 Hz, 2H), 7.50 (dt, J=1.5 Hz, J=8 Hz, 1H), 7.45 (dd, J=1.5 Hz, J=8 Hz, 1H), 7.18 (dd, J=1.5 Hz, J=8 Hz, 1H), 7.16 (dt, J=1.5 Hz, J=8 Hz, 1H), 6.86 (dd, J=1.5 Hz, J=8 Hz, 2H), 6.58 (d, J=1.5 Hz, 2H), 3.82 (s, 6H), 3.73 (s, 3H). 13C NMR (CDCl3): δ 158, 156, 143, 130, 130, 126, 121, 120, 117, 113, 108, 95, 56. mp: 148°C.

Reference： [1]Current Patent Assignee: KONINKLIJKE PHILIPS ELECTRONICS NV - EP1838671, 2008, B1 Location in patent: Page/Page column 19; 20

7
[ 13606-06-9 ]
[ 61822-18-2 ]

Yield	Reaction Conditions	Operation in experiment
86%	With 1,10-Phenanthroline; sodium palladium(II) tetrachloride; formyloxybenzene; sodium salt of phosphorous acid In N,N-dimethyl-formamide at 170℃; for 5h; Inert atmosphere; Schlenk technique; Sealed tube;	2.3. General procedure for catalytic reactions General procedure: The catalyst precursors were handled, weighed and stored inthe air except for Pd(OAc)2 that was stored under dinitrogen. Inorder to avoid weighing very small amounts of the catalysts, stocksolutions (under dinitrogen) of palladium catalysts were preparedin the appropriate solvent. For catalytic runs that required anamount of Phen less than 10 mg, a stock solution was preparedto avoid large weighing errors. In a typical reaction, the substratewas weighed in the air and placed in a 23 mL heavy-walled glasspressure tube with screw thread (Duran) containing a magneticstirring bar. (For an in-depth discussion of the different kinds ofpressure tubes that can be employed, and the correspondingadvantages and disadvantages see ref. [33]). The tube was placedin a Schlenk tube with a wide mouth. The tube was evacuatedand filled with dinitrogen three times to remove air. The catalystand ligand solutions and the amount of solvent required to reacha total volume of 10 mL were added and the reaction mixturewas stirred for 10 min to allow Phen to coordinate to palladium.Finally, HCOOPh and the base were added in this order. The pressuretube was plugged with a Schott PTB screw cap completed witha PTFE-protected seal and immersed in an oil bath preheated at theappropriate temperature. At the end of the reaction, the pressuretube was lifted from the oil and let to cool to room temperature.Then, the screw cap was carefully removed, the excess of CO wasvented, and the content was analyzed by GC or subjected to columnchromatography. (Caution: evolution of dissolved CO fromthe solution may continue for several minutes; keep the tubeunder a hood).
82%	With triethyl phosphite at 160℃; for 16h; Inert atmosphere;
81%	With triethyl phosphite at 200℃; for 0.166667h; Microwave irradiation;

75%	With 1,2,2,3,4,4-hexamethylphosphetane 1-oxide; phenylsilane In acetic acid butyl ester at 120℃; for 12h;
74%	With triethyl phosphite for 16h; Heating / reflux;	6 Synthesis example 6 2,7-dimethoxycarbazole 10 g (38.6 mmol) 4,4'-dimethoxy-2-nitro-1,1'-biphenyl in 35 ml triethylphosphite is refluxed during 16 hours in argon atmosphere. The mixture was allowed to cool to room temperature, upon which the product precipitates. Filtration and washing with methanol gave 6.5 g (74 %) of a white solid. 1H NMR (DMSO-d6): δ 11.00 (s, 1H), 7.85 (d, J=8 Hz, 2H), 6.94 (d, J=1.5 Hz, 2H), 6.74 (dd, J=1.5 Hz, J=8 Hz, 2H), 3.82 (s, 6H). 13C NMR (DMSO-d6): δ 157, 141, 119, 116, 107, 94, 55. mp: 285 °C.
70.1%	With triethyl phosphite at 170℃; for 4h; Inert atmosphere;
68%	With phenyl magensium bromide In tetrahydrofuran at 0℃; for 0.25h; Inert atmosphere;
60%	With triethyl phosphite at 140℃; Sealed tube;

Reference： [1]Ferretti, Francesco; Ragaini, Fabio; Ramadan, Doaa R. [Journal of Catalysis, 2022, vol. 409, p. 41 - 47]
[2]Location in patent: experimental part Kamino, Brett A.; Mills, Bridget; Reali, Christopher; Gretton, Michael J.; Brook, Michael A.; Bender, Timothy P. [Journal of Organic Chemistry, 2012, vol. 77, # 4, p. 1663 - 1674]
[3]Kuethe, Jeffrey T.; Childers, Karla G. [Advanced Synthesis and Catalysis, 2008, vol. 350, # 10, p. 1577 - 1586]
[4]Nykaza, Trevor V.; Ramirez, Antonio; Harrison, Tyler S.; Luzung, Michael R.; Radosevich, Alexander T. [Journal of the American Chemical Society, 2018, vol. 140, # 8, p. 3103 - 3113]
[5]Current Patent Assignee: KONINKLIJKE PHILIPS ELECTRONICS NV - EP1838671, 2008, B1 Location in patent: Page/Page column 9
[6]Location in patent: experimental part Tsuchiya, Kousuke; Sakaguchi, Kota; Kasuga, Hidemasa; Kawakami, Akira; Taka, Hideo; Kita, Hiroshi; Ogino, Kenji [Polymer, 2010, vol. 51, # 3, p. 616 - 622]
[7]Gao, Hongyin; Xu, Qing-Long; Yousufuddin, Muhammed; Ess, Daniel H.; Kuerti, Laszlo [Angewandte Chemie - International Edition, 2014, vol. 53, # 10, p. 2701 - 2705][Angew. Chem., 2014, vol. 53, # 10, p. 2739 - 2743,5]
[8]Kumar, Sangit; Kumar, Amit; Yadav, Abhimanyu; Verma, Ajay; Jana, Sadhan; Sattar, Moh.; Kumar, Shailesh; Prasad, Ch. Durga [Chemical Communications, 2014, vol. 50, # 67, p. 9481 - 9484]

8
[ 92248-06-1 ]
[ 61822-18-2 ]

Yield	Reaction Conditions	Operation in experiment
90%	With copper diacetate; palladium diacetate; In N,N-dimethyl-formamide; at 130℃; for 1.16667h;Inert atmosphere; Microwave irradiation;	General procedure: A mixture of 5a (0.100 g, 0.47 mmol), Pd(AcO)2 (0.0105 g,0.047 mmol) and Cu(AcO)2 (0.211 g, 1.17 mmol) in dry DMF (0.5 mL), under N2 atmosphere, wasstirred and heated at 130 C for 70 min under MW irradiation (100 W). The solvent was removed under vacuum by adding toluene, and the azeotropic distillation was continued until no solventremained. The residue was purified by column chromatography over silica gel (10 g/g of crude,hexane/EtOAc, 95:5), to give 1h (0.079 g, 80%) as a white solid.

Reference： [1]Molecules,2013,vol. 18,p. 10334 - 10351
[2]Synlett,2008,p. 1870 - 1876

9
[ 61822-18-2 ]
[ 1122-91-4 ]
[ 1220125-46-1 ]

Yield	Reaction Conditions	Operation in experiment
42%	With tri-tert-butyl phosphine; palladium diacetate; potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 120℃; for 6h; Inert atmosphere;

Reference： [1]Location in patent: experimental part Tsuchiya, Kousuke; Sakaguchi, Kota; Kasuga, Hidemasa; Kawakami, Akira; Taka, Hideo; Kita, Hiroshi; Ogino, Kenji [Polymer, 2010, vol. 51, # 3, p. 616 - 622]

10
[ 5344-78-5 ]
[ 61822-18-2 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: copper / 180 - 210 °C 2: triethyl phosphite / 4 h / 170 °C / Inert atmosphere
	Multi-step reaction with 2 steps 1: tri-tert-butyl phosphine; cesium fluoride; bis(dibenzylideneacetone)-palladium⁽⁰⁾ / tetrahydrofuran; toluene / 24 h / 20 °C / Inert atmosphere 2: triethyl phosphite / 16 h / 160 °C / Inert atmosphere
	Multi-step reaction with 3 steps 1: potassium <i>tert</i>-butylate / dimethyl sulfoxide / 25 °C 2: potassium carbonate / acetone / 10 h / 60 °C 3: triethyl phosphite / 140 °C / Sealed tube

Reference： [1]Tsuchiya, Kousuke; Sakaguchi, Kota; Kasuga, Hidemasa; Kawakami, Akira; Taka, Hideo; Kita, Hiroshi; Ogino, Kenji [Polymer, 2010, vol. 51, # 3, p. 616 - 622]
[2]Kamino, Brett A.; Mills, Bridget; Reali, Christopher; Gretton, Michael J.; Brook, Michael A.; Bender, Timothy P. [Journal of Organic Chemistry, 2012, vol. 77, # 4, p. 1663 - 1674]
[3]Kumar, Sangit; Kumar, Amit; Yadav, Abhimanyu; Verma, Ajay; Jana, Sadhan; Sattar, Moh.; Kumar, Shailesh; Prasad, Ch. Durga [Chemical Communications, 2014, vol. 50, # 67, p. 9481 - 9484]

11
[ 61822-18-2 ]
[ 1283116-61-9 ]
[ 1338080-13-9 ]

Yield	Reaction Conditions	Operation in experiment
60%	With potassium carbonate In dimethyl sulfoxide at 150℃;

Reference： [1]Location in patent: experimental part Zheng, Yonghao; Batsanov, Andrei S.; Jankus, Vygintas; Dias, Fernando B.; Bryce, Martin R.; Monkman, Andrew P. [Journal of Organic Chemistry, 2011, vol. 76, # 20, p. 8300 - 8310]

12
[ 61822-18-2 ]
[ 1338080-03-7 ]
[ 1338080-12-8 ]

Yield	Reaction Conditions	Operation in experiment
50%	With potassium carbonate In dimethyl sulfoxide at 150℃;

Reference： [1]Location in patent: experimental part Zheng, Yonghao; Batsanov, Andrei S.; Jankus, Vygintas; Dias, Fernando B.; Bryce, Martin R.; Monkman, Andrew P. [Journal of Organic Chemistry, 2011, vol. 76, # 20, p. 8300 - 8310]

13
[ 61822-18-2 ]
[ 145694-80-0 ]
[ 1338080-15-1 ]

Yield	Reaction Conditions	Operation in experiment
73%	With potassium carbonate In dimethyl sulfoxide at 150℃;

Reference： [1]Location in patent: experimental part Zheng, Yonghao; Batsanov, Andrei S.; Jankus, Vygintas; Dias, Fernando B.; Bryce, Martin R.; Monkman, Andrew P. [Journal of Organic Chemistry, 2011, vol. 76, # 20, p. 8300 - 8310]

14
[ 591-50-4 ]
[ 61822-18-2 ]
2,7-dimethoxy-9-phenyl-9<i>H</i>-carbazole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%	With copper(l) iodide; potassium carbonate; <i>L</i>-proline In dimethyl sulfoxide at 180℃; for 2h; Inert atmosphere;

Reference： [1]Location in patent: experimental part Kamino, Brett A.; Mills, Bridget; Reali, Christopher; Gretton, Michael J.; Brook, Michael A.; Bender, Timothy P. [Journal of Organic Chemistry, 2012, vol. 77, # 4, p. 1663 - 1674]

15
[ 67-56-1 ]
[ 124-41-4 ]
[ 136630-39-2 ]
[ 61822-18-2 ]

Yield	Reaction Conditions	Operation in experiment
61.1%	With copper(l) iodide In N,N-dimethyl-formamide at 110℃; for 20h; Inert atmosphere; Sealed tube;

Reference： [1]Louillat, Marie-Laure; Patureau, Frederic W. [Organic Letters, 2013, vol. 15, # 1, p. 164 - 167]

16
[ 61822-18-2 ]
[ 1416575-67-1 ]

Yield	Reaction Conditions	Operation in experiment
27%	With (p-cymene)ruthenium(II) chloride; copper diacetate; acetic acid In 1,2-dichloro-ethane; chlorobenzene at 140℃; for 168h; Sealed tube;

Reference： [1]Louillat, Marie-Laure; Patureau, Frederic W. [Organic Letters, 2013, vol. 15, # 1, p. 164 - 167]

17
[ 1424799-10-9 ]
[ 61822-18-2 ]

Yield	Reaction Conditions	Operation in experiment
83%	Stage #1: 9-benzyl-2,7-dimethoxy-9H-carbazole With potassium <i>tert</i>-butylate; oxygen In tetrahydrofuran; dimethyl sulfoxide at 20℃; for 26h; Stage #2: With water In tetrahydrofuran; dimethyl sulfoxide

Reference： [1]Qiu, Youai; Ma, Dengke; Fu, Chunling; Ma, Shengming [Organic and Biomolecular Chemistry, 2013, vol. 11, # 10, p. 1666 - 1671]

18
[ 61822-18-2 ]
C₄₁H₂₉IN₄NiO [ No CAS ]
[ 1501993-59-4 ]

Yield	Reaction Conditions	Operation in experiment
	With copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine In dimethyl sulfoxide at 120℃; for 12h; Inert atmosphere;

Reference： [1]Haumesser, Julien; Pereira, Ana M. V. M.; Gisselbrecht, Jean-Paul; Merahi, Khalissa; Choua, Sylvie; Weiss, Jean; Cavaleiro, Jose A. S.; Ruppert, Romain [Organic Letters, 2013, vol. 15, # 24, p. 6282 - 6285]

19
[ 61822-18-2 ]
[ 1415021-87-2 ]
[ 1501993-59-4 ]

Yield	Reaction Conditions	Operation in experiment
70%	With copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine In dimethyl sulfoxide at 120℃; for 12h; Inert atmosphere;

Reference： [1]Haumesser, Julien; Pereira, Ana M. V. M.; Gisselbrecht, Jean-Paul; Merahi, Khalissa; Choua, Sylvie; Weiss, Jean; Cavaleiro, Jose A. S.; Ruppert, Romain [Organic Letters, 2013, vol. 15, # 24, p. 6282 - 6285]

20
[ 61822-18-2 ]
[ 883148-62-7 ]
[ 1501993-62-9 ]

Yield	Reaction Conditions	Operation in experiment
51%	With copper(l) iodide; caesium carbonate; N-benzoyl-N'-phenylhydrazine In dimethyl sulfoxide at 120℃; for 12h; Inert atmosphere;

Reference： [1]Haumesser, Julien; Pereira, Ana M. V. M.; Gisselbrecht, Jean-Paul; Merahi, Khalissa; Choua, Sylvie; Weiss, Jean; Cavaleiro, Jose A. S.; Ruppert, Romain [Organic Letters, 2013, vol. 15, # 24, p. 6282 - 6285]

21
[ 61822-18-2 ]
[ 122-39-4 ]
[ 1612774-94-3 ]

Yield	Reaction Conditions	Operation in experiment
51%	With Isopropylbenzene; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; oxygen; copper diacetate In 1,1,2,2-tetrachloroethylene; acetic acid at 150℃; for 24h;

Reference： [1]Louillat, Marie-Laure; Biafora, Agostino; Legros, Fabien; Patureau, Frederic W. [Angewandte Chemie - International Edition, 2014, vol. 53, # 13, p. 3505 - 3509][Angew. Chem., 2014, vol. 53, # 13, p. 3573 - 3577,5]

22
[ 124-41-4 ]
[ 136630-39-2 ]
[ 61822-18-2 ]

Yield	Reaction Conditions	Operation in experiment
61%	With copper(l) iodide In methanol; N,N-dimethyl-formamide at 110℃; for 20h; Schlenk technique; Inert atmosphere;

Reference： [1]Louillat, Marie-Laure; Biafora, Agostino; Legros, Fabien; Patureau, Frederic W. [Angewandte Chemie - International Edition, 2014, vol. 53, # 13, p. 3505 - 3509][Angew. Chem., 2014, vol. 53, # 13, p. 3573 - 3577,5]

23
[ 61822-18-2 ]
[ 1736-85-2 ]
C₂₂H₂₀N₂O₄ [ No CAS ]

Reference： [1]Chemistry of Materials,2015,vol. 27,p. 1772 - 1779

24
[ 18908-66-2 ]
[ 61822-18-2 ]
9-(2-ethylhexyl)-2,7-dimethoxycarbazole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	With tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; potassium hydroxide In acetone Reflux;
75%	With tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; potassium hydroxide In acetone for 12h; Reflux;

Reference： [1]Bucinskas, Audrius; Bagdziunas, Gintautas; Tomkeviciene, Ausra; Volynyuk, Dmytro; Kostiv, Nataliya; Gudeika, Dalius; Jankauskas, Vygintas; Rutkis, Martins; Grazulevicius, Juozas V. [RSC Advances, 2015, vol. 5, # 61, p. 49577 - 49589]
[2]Bucinskas, Audrius; Waghray, Deepali; Bagdziunas, Gintautas; Thomas, Joice; Grazulevicius, Juozas Vidas; Dehaen, Wim [Journal of Organic Chemistry, 2015, vol. 80, # 5, p. 2521 - 2528]

25
[ 61822-18-2 ]
2,7-dimethoxy-3,6-bis(5-iodo-1-mesityl-1H-1,2,3-triazol-4-yl)-9-isopropylcarbazole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 6 steps 1.1: potassium hydroxide / dimethyl sulfoxide / 16 h / 20 °C 2.1: N-iodo-succinimide / chloroform / 5 h / 20 °C / Darkness; Inert atmosphere 3.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / tetrahydrofuran / 19 h / 20 °C / Inert atmosphere 4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Darkness 5.1: copper(II) sulfate; sodium L-ascorbate / ethanol; water; dichloromethane / 50 °C / Inert atmosphere; Darkness 5.2: 0.5 h / 35 °C 6.1: n-butyllithium / tetrahydrofuran; hexane / -78 - 0 °C / Inert atmosphere; Schlenk technique 6.2: Inert atmosphere; Schlenk technique