Alternatived Products of [ 6362-58-9 ]
Product Details of [ 6362-58-9 ]
CAS No. : | 6362-58-9 |
MDL No. : | MFCD11934791 |
Formula : |
C10H10O3
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
178.18
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Pubchem ID : | - |
Synonyms : |
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Application In Synthesis of [ 6362-58-9 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 6362-58-9 ]
- 1
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[ 6362-58-9 ]
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[ 13674-16-3 ]
- 2
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[ 6362-58-9 ]
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[ 17672-21-8 ]
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methyl (Z)-3-benzylidene-3,4-dihydro-2-oxo-2H-1,4-benzoxazine-5-carboxylate
[ No CAS ]
- 3
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[ 6362-58-9 ]
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[ 27000-00-6 ]
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[ 13673-95-5 ]
- 4
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[ 3070-71-1 ]
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[ 6362-58-9 ]
Yield | Reaction Conditions | Operation in experiment |
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General procedure: A solution of a given enoate (45-51, 1 mmol) in MeOH(15 mL) was treated with a flow of ozone, at -78 C, for 15-30 min. to give the corresponding -keto-esters. After thecompletion of the reaction, a flow of dry N2 was passed through the reaction flask, for 15 min., in order to remove the excessof oxone. To the resulting solution, hydroxylamine hydrochloride and pyridine was added and . The mixture was stirred atroom temperature for 50 minutes. After that, the solvent was removed and the crude residue was purified by silica gel flashchromatography (hexane: ethyl acetate 20%) to afford the corresponding non-coded -amino esters. Compounds 53, 55, 57and 58 are known. Spectroscopic data of our compounds are compatible with data available in literature for each knowncompounds. |
- 5
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[ 6362-58-9 ]
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[ 1426129-50-1 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 5 steps
1.1: bromine / dichloromethane / 10 h / 10 - 20 °C
2.1: copper(l) chloride; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; sodium t-butanolate / toluene / 15 h / 80 °C / Inert atmosphere
3.1: nicotinamide adenine dinucleotide phosphate; alpha-D-glucopyranose / aq. phosphate buffer / 14 h / 25 - 30 °C / pH 7 / Enzymatic reaction
3.2: 8 h / 0 - 20 °C
4.1: tetrahydrofuran; water / 0.17 h
4.2: 3 h
5.1: boron trifluoride diethyl etherate / tetrahydrofuran / 0.17 h
5.2: 11 h / 0 - 20 °C |
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