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Chemical Structure| 64334-96-9 Chemical Structure| 64334-96-9

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Chemical Structure| 64334-96-9

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Zhengyi Bian ; Alison Wallum ; Arshad Mehmood ; Eric Gomez ; Ziwen Wang ; Subhendu Pandit , et al.

Abstract: A major challenge in the “bottom-up” solvothermal synthesis of carbon dots (CDs) is the removal of small-molecule byproducts, noncarbonized polyamides, or other impurities that confound the optical properties. In previously reported benzene diamine-based CDs, the observed fluorescence signal already has been shown to arise from free small molecules, not from nanosized carbonized dots. Here we have unambiguously identified the small-molecule species in the synthesis of CDs starting with several isomers of benzene diamine by directly matching their NMR, mass spectrometry, and optical data with commercially available small organic molecules. By combining dialysis and chromatography, we have sufficiently purified the CD reaction mixtures to measure the CD size by TEM and STM, elemental composition, optical absorption and emission, and single-particle blinking dynamics. The results can be rationalized by electronic structure calculations on small model CDs. Our results conclusively show that the purified benzene diamine-based CDs do not emit red fluorescence, so the quest for full-spectrum fluorescence from isomers of a single precursor molecule remains open.

Keywords: carbon dots ; STM ; fluorescence ; organic fluorophore ; fluorescence mechanism

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Product Details of [ 64334-96-9 ]

CAS No. :64334-96-9
Formula : C10H10N2
M.W : 158.20
SMILES Code : CC1=NC2=C(C=CC(N)=C2)C=C1
MDL No. :MFCD18377735
InChI Key :PRLKZXXDECGQOK-UHFFFAOYSA-N
Pubchem ID :459655

Safety of [ 64334-96-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
 

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