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Chemical Structure| 66965-44-4 Chemical Structure| 66965-44-4

Structure of 66965-44-4

Chemical Structure| 66965-44-4

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Product Details of [ 66965-44-4 ]

CAS No. :66965-44-4
Formula : C10H16O2
M.W : 168.23
SMILES Code : O=C1CC2C(C)(C)OC1(C)CC2
MDL No. :MFCD24688330

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Application In Synthesis of [ 66965-44-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 66965-44-4 ]

[ 66965-44-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 98-55-5 ]
  • [ 66965-44-4 ]
YieldReaction ConditionsOperation in experiment
With 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; In diethyl ether; dichloromethane; 1,2-dichloro-ethane; EXAMPLE 1 1,3,3-Trimethyl-2-oxabicyclo[2,2,2]octan-6-one A mixture of 3.08 g. (0.02 mole) alpha-<strong>[98-55-5]terpineol</strong> and 4.45 g. (0.022 mole) of 85 percent m-chloroperbenzoic acid in 70 ml. of ethylene dichloride is refluxed under nitrogen for 20 hours, then cooled to room temperature and washed with aqueous sodium bisulfite and sodium bicarbonate solutions. The solvent is removed in vacuo and the resulting oil is treated in situ with 2.94 g. (0.0136 mole) pyridinium chlorochromate. The resulting mixture is stirred under nitrogen in 35 ml. of methylene chloride at ambient temperatures for 2.5 hours. After addition of 200 ml. diethyl ether, the mixture is filtered through celite and the solvent evaporated to give, on steam distillation, 1,3,3-trimethyl-2-oxabicyclo [2,2,2]octan-6-one; m.p. 50 to 52 C.
 

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