67368-93-8|(SP-4-1)-[5,10,15,20-Tetrakis(4-methylphenyl)-21H,23H-porphinato-κN21,κN22,κN23,κN24]-Manganese| Ambeed

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CAS No. :	67368-93-8
Formula :	C₄₈H₃₆MnN₄
M.W :	723.76
SMILES Code :	CC(C=C1)=CC=C1C(C2=CC=C3C(C4=CC=C(C)C=C4)=C5C=CC(C(C6=CC=C(C)C=C6)=C7C=C8)=[N]95)=C%10C=CC%11=[N]%10[Mn+2]9([N-]23)[N-]7C8=C%11C%12=CC=C(C)C=C%12
MDL No. :	N/A

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H315-H319-H335
Precautionary Statements:	P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide; at 150℃; for 16h;Inert atmosphere;	General procedure: The metallization of porphyrins was achieved through refluxing theligand with corresponding metal acetate in DMF according to the reportedprocedure [48-50]. In a typical procedure, porphyrin ligand(0.20 mmol) and corresponding anhydrous metal acetate (2.0 mmol)were dissolved in DMF (60 mL), and the obtained solution was heatedto refluxing (150 C) with stirring under N2 atmosphere. After refluxingfor 16.0 h, the resultant mixture was cooled to room temperaturenaturally. Then the obtained solid residue from rotary evaporationunder reduced pressure was dissolved in dichloromethane (60 mL), andthe purplish red solution was washed with water five times(5×200 mL) until the upper water layer became clear and colorless.The isolated lower layer liquid was dried over anhydrous Na2SO4. Thepurple solid obtained from rotary evaporation of the solvent was subjectedto silica column chromatography separation with eluent of cyclohexaneand dichloromethane in the volume ratio of 4:1∼1:1. Themetalloporphyrins synthesized in this work were dried at 80 C for 8.0 hunder reduced pressure before used, and characterized qualitativelythrough 1H NMR, 13C NMR and ESI-MS. The details for the synthesesand characterizations of metalloporphyrins have been illustrated in theSupplementary Information.
71 mg	In N,N-dimethyl-formamide; at 155℃; for 2h;Inert atmosphere;	Dissolve 67 mg of <strong>[14527-51-6]TTP</strong> (that is,R5 = R6 = R7 = R8 = methyl in formula (III)) in 15 mL of N,N'-dimethylformamide solution, and then add 48 mg of manganese acetate to the above solution; Blow in nitrogen to remove the air in the system, and then heat and stir at 155C under the protection of a nitrogen ball. The progress of the reaction was monitored by UV, and the reaction was stopped after 2 hours. Add 50 mL of ice water to the reaction system, after refrigerating overnight, suction filtration to obtain 85 mg of grass green solid powder; The grass green precipitate was dissolved in chloroform, and separated and purified by gel column chromatography. The mobile phase is methanol to obtain a purified product; Then, the purified product was dissolved in chloroform and separated by silica gel column chromatography (developing solvent chloroform:methanol = 5:1) to obtain 71 mg of product.

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CAS No.: 67368-93-8

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CAS No.: 67368-93-8

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[ 67368-93-8 ] Synthesis Path-Downstream 1~1

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