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[ CAS No. 68965-62-8 ] {[proInfo.proName]}

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Chemical Structure| 68965-62-8
Chemical Structure| 68965-62-8
Structure of 68965-62-8 * Storage: {[proInfo.prStorage]}
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Product Details of [ 68965-62-8 ]

CAS No. :68965-62-8 MDL No. :MFCD24479649
Formula : C7H9BrO2 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W :205.05 Pubchem ID :-
Synonyms :

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Application In Synthesis of [ 68965-62-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 68965-62-8 ]
  • Downstream synthetic route of [ 68965-62-8 ]

[ 68965-62-8 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 68965-62-8 ]
  • [ 124-42-5 ]
  • [ 19178-21-3 ]
YieldReaction ConditionsOperation in experiment
71% With copper; sodium t-butanolate In N,N-dimethyl-formamide at 100℃; for 0.5 h; Microwave irradiation General procedure: A 10 mL microwave reaction tube was charged with the appropriate β-bromo α,β-unsaturated carboxylic acid 1 (0.5mmol) and amidine hydrochloride 2 (1 mmol), together withCu powder (0.05 mmol), t-BuONa (2 mmol), and DMF (3mL). The mixture was heated to 100 °C for 30 min by microwave irradiation (CEM Discover Microwave System) at 100 W initial power. The mixture was then cooled to r.t.and filtered through a short column of silica gel (CHCl3–MeOH) to remove inorganic salts. Evaporation of the solvent gave a crude mixture that was purified by TLC [silica gel 60 GF254 (Merck), CHCl3–MeOH].
Reference: [1] Applied Organometallic Chemistry, 2012, vol. 26, # 11, p. 576 - 582,7
[2] Synlett, 2013, vol. 24, # 20, p. 2705 - 2708
[3] Synlett, 2010, # 17, p. 2611 - 2616
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