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Chemical Structure| 74255-38-2 Chemical Structure| 74255-38-2

Structure of 74255-38-2

Chemical Structure| 74255-38-2

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Product Details of [ 74255-38-2 ]

CAS No. :74255-38-2
Formula : C8H6N2O3
M.W : 178.14
SMILES Code : O=[N+](C1=C(OC(C)=N2)C2=CC=C1)[O-]

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Application In Synthesis of [ 74255-38-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 74255-38-2 ]

[ 74255-38-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 603-87-2 ]
  • [ 78-39-7 ]
  • [ 74255-38-2 ]
YieldReaction ConditionsOperation in experiment
32% With Montmorillonite KSF clay; In toluene;Heating / reflux; To a solution of <strong>[603-87-2]2-amino-6-nitrophenol</strong> (Description 34,8 g, 51.9 mmol) in anhydrous toluene (150 ml) was added triethyl orthoacetate (9.51 ml, 51.9 mmol) and Montmorillonite KSF clay (2 g). The resulting mixture was then heated at reflux overnight. The cooled reaction mixture was filtered through CELITE AND the filtrate evaporated to dryness. The residue was triturated with diethyl ether and the solid collected by filtration and dried to give the title compound (2. 96 g, 32%). 1H NMR (400 MHz, CDC13) 8 2.77 (3H, s), 7.45 (1H, T, J8. 1), 7.98 (1H, dd, J7. 9 and 0.9), 8.14 (1 H, dd, J 8. 4 and 0.9).
 

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