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Chemical Structure| 75168-99-9 Chemical Structure| 75168-99-9

Structure of 75168-99-9

Chemical Structure| 75168-99-9

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Product Details of [ 75168-99-9 ]

CAS No. :75168-99-9
Formula : C8H7F3OS
M.W : 208.20
SMILES Code : FC(F)(SC1=C(OC)C=CC=C1)F

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Application In Synthesis of [ 75168-99-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 75168-99-9 ]

[ 75168-99-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 126-33-0 ]
  • [ 13920-94-0 ]
  • [ 2923-16-2 ]
  • [ 75168-99-9 ]
YieldReaction ConditionsOperation in experiment
In carbon dioxide; Example 3 2Methoxyphenyl trifluoromethyl sulfide A mixture of 6.04 g of bis(2-methoxyphenyl) disulfide, 6.60 g of anhydrous potassium trifluoroacetate, and 9 ml of dry tetramethylene sulfone was stirred in a vacuum distillation apparatus at a pressure of 65 mbar. The mixture was slowly heated in an oil bath up to a maximum of 220 C., during which time volatile products were collected in a receiver that was cooled using dry ice. Redistillation of the crude product gave 3.20 g (70% of theory) of analytically pure 2-methoxyphenyl trifluoromethyl sulfide (boiling point 80 C. at 20 mbar). The 19F NMR data agreed with the data published in J. Org. Chem., 59, 4047 (1985). The structure was additionally confirmed by the 1H NMR and MS spectra.
 

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