Home Cart 0 Sign in  
X

[ CAS No. 77166-01-9 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
3d Animation Molecule Structure of 77166-01-9
Chemical Structure| 77166-01-9
Chemical Structure| 77166-01-9
Structure of 77166-01-9 * Storage: {[proInfo.prStorage]}
Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Quality Control of [ 77166-01-9 ]

Related Doc. of [ 77166-01-9 ]

Alternatived Products of [ 77166-01-9 ]

Product Details of [ 77166-01-9 ]

CAS No. :77166-01-9 MDL No. :MFCD03990465
Formula : C6H8N2O2S Boiling Point : -
Linear Structure Formula :- InChI Key :LWSFXJZBVVGVIO-UHFFFAOYSA-N
M.W : 172.21 Pubchem ID :2772379
Synonyms :

Safety of [ 77166-01-9 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 77166-01-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 77166-01-9 ]
  • Downstream synthetic route of [ 77166-01-9 ]

[ 77166-01-9 ] Synthesis Path-Upstream   1~6

  • 1
  • [ 110-85-0 ]
  • [ 77166-01-9 ]
  • [ 59215-36-0 ]
Reference: [1] Chemical and Pharmaceutical Bulletin, 1991, vol. 39, # 9, p. 2288 - 2300
  • 2
  • [ 135645-65-7 ]
  • [ 77166-01-9 ]
YieldReaction ConditionsOperation in experiment
21% With manganese(II) triflate; 1-Adamantanecarboxylic acid; C32H38N4O2; dihydrogen peroxide In water; acetonitrile at -30 - 20℃; for 0.5 h; Inert atmosphere; Resolution of racemate General procedure: Mn(OTf)2 (1.4 mg, 0.004 mmol) and L2 (2.0 mg, 0.004 mmol) were dissolved in acetonitrile, and the mixture was stirred at room temperature for 12 h. To the solution of manganese complex were added substrate (0.4 mmol), 0.2 equiv of aca (14.4 mg, 0.08 mmol), and 49 percent aqeous hydrogen peroxide (56.5 mg, 0.4 mmol). Then decreased the temperature to -30 °C, and the reaction mixture was stirred at -30 °C for 0.5 h. The aqueous was separated, the organic layer was dried over MgSO4, filtered, concentrated at reduced pressure. The product was purified by silica gel column chromatography to afford the corresponding sulfoxide and sulfone.
Reference: [1] Tetrahedron Letters, 2018, vol. 59, # 2, p. 156 - 159
  • 3
  • [ 135645-65-7 ]
  • [ 77166-01-9 ]
Reference: [1] Journal of Organic Chemistry, 1991, vol. 56, # 19, p. 5610 - 5614
  • 4
  • [ 14001-63-9 ]
  • [ 135645-65-7 ]
  • [ 77166-01-9 ]
Reference: [1] Journal of Organic Chemistry, 1991, vol. 56, # 19, p. 5610 - 5614
[2] Journal of Organic Chemistry, 1991, vol. 56, # 19, p. 5610 - 5614
  • 5
  • [ 14001-63-9 ]
  • [ 77166-01-9 ]
Reference: [1] Chemical and Pharmaceutical Bulletin, 1991, vol. 39, # 9, p. 2288 - 2300
  • 6
  • [ 35071-17-1 ]
  • [ 77166-01-9 ]
Reference: [1] Chemical and Pharmaceutical Bulletin, 1991, vol. 39, # 9, p. 2288 - 2300
Recommend Products
Same Skeleton Products
Historical Records

Related Functional Groups of
[ 77166-01-9 ]

Sulfones

Chemical Structure| 14161-09-2

[ 14161-09-2 ]

2-(Methylsulfonyl)pyrimidine

Similarity: 0.90

Chemical Structure| 35144-22-0

[ 35144-22-0 ]

4,6-Dimethyl-2-methylsulfonylpyrimidine

Similarity: 0.89

Chemical Structure| 55329-22-1

[ 55329-22-1 ]

4-Chloro-6-methyl-2-(methylsulfonyl)pyrimidine

Similarity: 0.86

Chemical Structure| 38275-48-8

[ 38275-48-8 ]

5-Bromo-2-(methylsulphonyl)pyrimidine

Similarity: 0.82

Chemical Structure| 56621-92-2

[ 56621-92-2 ]

2-(Methylsulfonyl)pyrimidin-5-amine

Similarity: 0.80

Related Parent Nucleus of
[ 77166-01-9 ]

Pyrimidines

Chemical Structure| 14161-09-2

[ 14161-09-2 ]

2-(Methylsulfonyl)pyrimidine

Similarity: 0.90

Chemical Structure| 35144-22-0

[ 35144-22-0 ]

4,6-Dimethyl-2-methylsulfonylpyrimidine

Similarity: 0.89

Chemical Structure| 55329-22-1

[ 55329-22-1 ]

4-Chloro-6-methyl-2-(methylsulfonyl)pyrimidine

Similarity: 0.86

Chemical Structure| 38275-48-8

[ 38275-48-8 ]

5-Bromo-2-(methylsulphonyl)pyrimidine

Similarity: 0.82

Chemical Structure| 56621-92-2

[ 56621-92-2 ]

2-(Methylsulfonyl)pyrimidin-5-amine

Similarity: 0.80