Name: 778-24-5|Dimethyldiphenylsilane|97% GC
Brand: Ambeed
SKU: A975180
Price: 10.0 USD
Availability: InStock
Rating: 94 (25 reviews)

1
[ 778-24-5 ]
[ 4095-10-7 ]

Yield	Reaction Conditions	Operation in experiment
	With bromine

Reference： [1]McBride; Beachell [Journal of the American Chemical Society, 1952, vol. 74, p. 5247]

2
[ 778-24-5 ]
[ 15576-81-5 ]

Yield	Reaction Conditions	Operation in experiment
74%	With I₂; AlI₂
	With aluminium(III) iodide; iodine

Reference： [1]Eaborn, C. [Journal of the Chemical Society][Journal of the Chemical Society, 1950, p. 3077 - 3089] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 64, page 179 - 181]
[2]Eaborn [Journal of the Chemical Society, 1950, p. 3077,3084]

3
[ 778-24-5 ]
[ 18408-63-4 ]

Yield	Reaction Conditions	Operation in experiment
	With nickel; methyl cyclohexane Hydrogenation;

Reference： [1]Kanazashi; Takakusa [Bulletin of the Chemical Society of Japan, 1954, vol. 27, p. 441,443]

4
[ 78-62-6 ]
[ 591-51-5 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	In not given

Reference： [1]Larsson; van Gilse van der Pals [Svensk Kemisk Tidskrift, 1951, vol. 63, p. 179]
[2]Larsson, E.; Gilse van der Pals, E. van [Svensk Kemisk Tidskrift, 1951, vol. 63, p. 177 - 178] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 23, page 72 - 75]

5
phenylmagnesium bromide [ No CAS ]
[ 75-78-5 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	In diethyl ether

Reference： [1]McBride; Beachell [Journal of the American Chemical Society, 1952, vol. 74, p. 5247] Toptschiew et al. [Doklady Akademii Nauk SSSR, 1958, vol. 118, p. 731,732][Doklady Chemistry, 118-123<1958>117,118]
[2]Hengge,E.; Eberhardt,H. [Monatshefte fur Chemie, 1979, vol. 110, p. 39 - 50]

6
[ 75-78-5 ]
[ 108-90-7 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
75%	Stage #1: chlorobenzene With gallium(III) trichloride; magnesium Stage #2: dimethylsilicon dichloride In chlorobenzene at 70℃; for 8.5h; Further stages.;
	With sodium

Reference： [1]Grinberg; Rakhlin; Petrova; Voronkov; Strel'nikova; D'yachkova [Doklady Chemistry, 2007, vol. 412, # 1, p. 22 - 23]
[2]Kanazashi; Takakusa [Bulletin of the Chemical Society of Japan, 1954, vol. 27, p. 441,443]

7
[ 78-62-6 ]
[ 108-90-7 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium

Reference： [1]Takami [1957, vol. 52, p. 175,184][Chem.Abstr., 1958, p. 9982]

8
[ 917-64-6 ]
[ 80-10-4 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	With diethyl ether Erhitzen des Reaktionsprodukts auf 150grad;

Reference： [1]Kipping [Journal of the Chemical Society, 1927, p. 105]

9
[ 4353-77-9 ]
[ 778-24-5 ]
Dimethylsilyl-bis-benzolsulfonat [ No CAS ]

Reference： [1]Bourgeois,P. et al. [Bulletin de la Societe Chimique de France, 1966, p. 1171]

10
[ 4353-77-9 ]
[ 778-24-5 ]
[ 10090-03-6 ]

Reference： [1]Bourgeois,P. et al. [Bulletin de la Societe Chimique de France, 1966, p. 1171] Calas,R. et al. [Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1966, vol. 263, p. 243 - 246]

11
[ 1145-98-8 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	With dimethyl sulfoxide In 1,4-dioxane at 5℃; Irradiation;

Reference： [1]Okinoshima,H.; Weber,W.P. [Journal of Organometallic Chemistry, 1978, vol. 149, p. 279 - 287]

12
[ 67-56-1 ]
[ 37865-47-7 ]
[ 17881-88-8 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
1: 14% 2: 54%	In cyclohexane for 1h; Ambient temperature; Irradiation;

Reference： [1]Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro [Journal of Organometallic Chemistry, 1991, vol. 412, # 1.2, p. 9 - 19]

13
[ 1066-35-9 ]
phenylmagnesium chloride [ No CAS ]
[ 766-77-8 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
1: 11.5% 2: 83.4%	In tetrahydrofuran at 90℃; for 1h;

Reference： [1]Zhun', V. I.; Zhun', A. B.; Vlasenko, S. D.; Belorusskaya, L. A.; Chernyshev, E. A.; Sheludyakov, V. D. [Journal of general chemistry of the USSR, 1982, vol. 52, # 11, p. 2266 - 2270][Zhurnal Obshchei Khimii, 1982, vol. 52, # 11, p. 2565 - 2570]

14
[ 1493-13-6 ]
[ 778-24-5 ]
[ 99542-59-3 ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform-d1

Reference： [1]Matyjaszewski, K.; Chen, Y. L. [Journal of Organometallic Chemistry, 1988, vol. 340, p. 7 - 12]

15
[ 766-77-8 ]
phenylmagnesium chloride [ No CAS ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
3.9%	In tetrahydrofuran at 50℃; for 2h;

Reference： [1]Zhun', V. I.; Zhun', A. B.; Vlasenko, S. D.; Belorusskaya, L. A.; Chernyshev, E. A.; Sheludyakov, V. D. [Journal of general chemistry of the USSR, 1982, vol. 52, # 11, p. 2266 - 2270][Zhurnal Obshchei Khimii, 1982, vol. 52, # 11, p. 2565 - 2570]

16
[ 62383-81-7 ]
[ 778-24-5 ]
[ 124081-20-5 ]
[ 124081-31-8 ]

Yield	Reaction Conditions	Operation in experiment
	With tin(IV) chloride; nickel 1.) CH₂Cl₂, RT, 30 min; Multistep reaction. Title compound not separated from byproducts;

Reference： [1]Ishibashi, Hiroyuki; Sakashita, Hiroshi; Morita, Satoko; Mitani, Sumiyo; Ikeda, Masazumi [Chemistry Letters, 1989, p. 603 - 606]

17
[ 62383-81-7 ]
[ 778-24-5 ]
[ 124081-19-2 ]
[ 124081-17-0 ]

Yield	Reaction Conditions	Operation in experiment
	With tin(IV) chloride In dichloromethane for 0.5h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Reference： [1]Ishibashi, Hiroyuki; Sakashita, Hiroshi; Morita, Satoko; Mitani, Sumiyo; Ikeda, Masazumi [Chemistry Letters, 1989, p. 603 - 606]

18
[ 778-24-5 ]
[ 768-33-2 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogenchloride In dichloromethane

Reference： [1]Cella; Carpenter [Journal of labelled compounds and radiopharmaceuticals, 1994, vol. 34, # 5, p. 427 - 430]

19
[ 37865-47-7 ]
[ 17881-88-8 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
1: 54% 2: 14%	With methanol In cyclohexane for 1h; Ambient temperature; Irradiation;

Reference： [1]Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro [Journal of Organometallic Chemistry, 1991, vol. 412, # 1.2, p. 9 - 19]

20
phenylmagnesium bromide [ No CAS ]
[ 79035-76-0 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
50 % Chromat.	In tetrahydrofuran 1.) -78 deg C, 30 min, 2.) RT, 1 h;

Reference： [1]Fuchikami, Takamasa; Ojima, Iwao [Journal of Organometallic Chemistry, 1981, vol. 212, # 2, p. 145 - 153]

21
[ 100-42-5 ]
[ 661-68-7 ]
[ 591-51-5 ]
[ 62257-76-5 ]
[ 778-24-5 ]
[ 128756-74-1 ]
[ 129165-25-9 ]

Yield	Reaction Conditions	Operation in experiment
	With tetrakis(triphenylphosphine)platinum In benzene at 150℃; for 22h; other alkene;

Reference： [1]Hayashi, Teruyuki; Kawamoto, Aparecida M.; Kobayashi, Toshi-aki; Tanaka, Masato [Journal of the Chemical Society. Chemical communications, 1990, # 7, p. 563 - 564]

22
[ 591-51-5 ]
[ 90185-40-3 ]
[ 766-77-8 ]
[ 778-24-5 ]
[ 128756-77-4 ]
[ 82877-25-6 ]

Yield	Reaction Conditions	Operation in experiment
1: 34 % Chromat. 2: 19 % Chromat. 3: 3 % Chromat. 4: 13 % Chromat.	In tetrahydrofuran; hexane at -30 - 25℃; for 1h;
1: 34 % Chromat. 2: 19 % Chromat. 3: 21 % Chromat. 4: 3 % Chromat.	In tetrahydrofuran; hexane at -30 - 25℃; for 1h;

Reference： [1]Gevorgyan, Vladimir; Borisova, Larisa; Lukevics, Edmunds [Journal of Organometallic Chemistry, 1992, vol. 441, # 3, p. 381 - 387]
[2]Gevorgyan, Vladimir; Borisova, Larisa; Lukevics, Edmunds [Journal of Organometallic Chemistry, 1992, vol. 441, # 3, p. 381 - 387]

23
[ 591-51-5 ]
[ 82877-25-6 ]
[ 778-24-5 ]
[ 128756-77-4 ]

Yield	Reaction Conditions	Operation in experiment
	In tetrahydrofuran; hexane at -30 - 25℃; for 1h;

Reference： [1]Gevorgyan, Vladimir; Borisova, Larisa; Lukevics, Edmunds [Journal of Organometallic Chemistry, 1992, vol. 441, # 3, p. 381 - 387]

24
[ 113800-12-7 ]
[ 778-24-5 ]
[ 103-29-7 ]

Yield	Reaction Conditions	Operation in experiment
1: 12 % Chromat. 2: 16 % Chromat.	With acetophenone In benzene at 20℃; Irradiation;

Reference： [1]Step, E. N.; Tarasov, V. F.; Buchachenko, A. L. [Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1988, vol. 37, # 10, p. 2024 - 2028][Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988, # 10, p. 2250 - 2255]

25
[ 113800-12-7 ]
[ 778-24-5 ]
[ 17938-20-4 ]
[ 103-29-7 ]

Yield	Reaction Conditions	Operation in experiment
1: 43 % Chromat. 2: 9 % Chromat. 3: 12 % Chromat.	In benzene at 20℃; Irradiation;
1: 6 % Chromat. 2: 13 % Chromat. 3: 17 % Chromat.	With triphenylene In benzene at 20℃; Irradiation;

Reference： [1]Step, E. N.; Tarasov, V. F.; Buchachenko, A. L. [Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1988, vol. 37, # 10, p. 2024 - 2028][Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988, # 10, p. 2250 - 2255]
[2]Step, E. N.; Tarasov, V. F.; Buchachenko, A. L. [Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1988, vol. 37, # 10, p. 2024 - 2028][Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988, # 10, p. 2250 - 2255]

26
[ 87938-59-8 ]
[ 13688-68-1 ]
[ 778-24-5 ]

Reference： [1]Journal of Organometallic Chemistry,1984,vol. 271,p. 319 - 326

27
[ 778-24-5 ]
[ 13247-99-9 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogen bromide

Reference： [1]Hengge,E.; Eberhardt,H. [Monatshefte fur Chemie, 1979, vol. 110, p. 39 - 50]

28
[ 1145-98-8 ]
[ 622-29-7 ]
[ 766-77-8 ]
[ 778-24-5 ]
[1-[2-(Dimethyl-phenyl-silanyl)-phenyl]-meth-(E)-ylidene]-methyl-amine [ No CAS ]
[1-[2,6-Bis-(dimethyl-phenyl-silanyl)-phenyl]-meth-(E)-ylidene]-methyl-amine [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
1: 15% 2: 15%	In toluene at 160℃; for 120h; Further byproducts given. Yields of byproduct given;

Reference： [1]Williams, Neil A.; Uchimaru, Yuko; Tanaka, Masato [Journal of the Chemical Society. Chemical communications, 1995, # 11, p. 1129 - 1130]

29
[ 375-73-5 ]
[ 778-24-5 ]
[ 142294-81-3 ]

Yield	Reaction Conditions	Operation in experiment
90.5%	at 0℃; for 0.5h;

Reference： [1]Sundermeyer, Wolfgang; Walch, Andreas [Chemische Berichte, 1996, vol. 129, # 2, p. 161 - 167]

30
[ 1145-98-8 ]
[ 3839-31-4 ]
[ 778-24-5 ]
[ 4098-97-9 ]
[ 18753-27-0 ]

Yield	Reaction Conditions	Operation in experiment
1: 10 % Spectr. 2: 25 % Spectr. 3: 10 % Spectr.	In tetrahydrofuran at 4℃; for 192h;

Reference： [1]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]

31
[ 3839-31-4 ]
[ 766-77-8 ]
[ 5272-18-4 ]
[ 778-24-5 ]
[ 1145-98-8 ]

Yield	Reaction Conditions	Operation in experiment
1: 26 % Chromat. 2: 38 % Chromat. 3: 6 % Chromat. 4: 2.5 % Chromat.	With oxygen In tetrahydrofuran at 0℃; for 0.0166667h; Further byproducts given. Title compound not separated from byproducts;

Reference： [1]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]

32
[ 3839-31-4 ]
[ 5272-18-4 ]
[ 778-24-5 ]
[ 1145-98-8 ]
[ 56-33-7 ]

Yield	Reaction Conditions	Operation in experiment
1: 26 % Chromat. 2: 38 % Chromat. 3: 6 % Chromat. 4: 0.3 % Chromat.	With oxygen In tetrahydrofuran at 0℃; for 0.0166667h; Title compound not separated from byproducts;

Reference： [1]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]

33
[ 768-32-1 ]
[ 75-76-3 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	at 40℃;
	at 60℃;

Reference： [1]Russell [Journal of the American Chemical Society, 1959, vol. 81, p. 4825,4826,4828]
[2]Russell [Journal of the American Chemical Society, 1959, vol. 81, p. 4825,4826,4828]

34
[ 778-24-5 ]
[ 71-43-2 ]

Yield	Reaction Conditions	Operation in experiment
100 % Chromat.	With ammonia; iron(III) chloride; sodium amide at 20℃; for 0.05h;
98 %Chromat.	With potassium trimethylsilonate In dimethyl sulfoxide at 70℃; for 6h; Sealed tube; Schlenk technique;

Reference： [1]Sun, Guang-Ri; He, Jin-Bao; Zhu, Hua-Jie; Pittman Jr., Charles U. [Synlett, 2000, # 5, p. 619 - 622]
[2]Yao, Wubing; Li, Rongrong; Jiang, Huajiang; Han, Deman [Journal of Organic Chemistry, 2018, vol. 83, # 4, p. 2250 - 2255]

35
phenylmagnesium bromide [ No CAS ]
[ 768-33-2 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	In diethyl ether at 20℃; for 15h;

Reference： [1]Tsukada, Naofumi; Hartwig, John F. [Journal of the American Chemical Society, 2005, vol. 127, # 14, p. 5022 - 5023]

36
[ 766-77-8 ]
[ 71-43-2 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
71%	With (hydridotris(3,5-dimethylpyrazolyl)borate)PtMe₂H at 200℃; for 24h;
61%	With norbornene; [Ir(hydride)₂(1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(pyridine)₃][BF₄] In tetrahydrofuran at 110℃; for 24h; Sealed tube; Inert atmosphere; Schlenk technique;

Reference： [1]Tsukada, Naofumi; Hartwig, John F. [Journal of the American Chemical Society, 2005, vol. 127, # 14, p. 5022 - 5023]
[2]Rubio-Pérez, Laura; Iglesias, Manuel; Munárriz, Julen; Polo, Victor; Passarelli, Vincenzo; Pérez-Torrente, Jesús J.; Oro, Luis A. [Chemical Science, 2017, vol. 8, # 7, p. 4811 - 4822]

37
[ 13029-09-9 ]
[ 768-33-2 ]
[ 13688-68-1 ]
[ 778-24-5 ]
5-methyl-5-phenyl-5H-dibenzo[b,d]silole [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,2006,vol. 691,p. 1257 - 1264

38
[ 766-77-8 ]
[ 1111-74-6 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	With carbon dioxide; [(1,3-bis(3-tBu-5-Me-2-oxy-benzyl)-4-Me-MeOC₆H₂]Zr(CH₂Ph)2; tris(pentafluorophenyl)borate In benzene-d6 at 20℃; for 0.25h; Title compound not separated from byproducts;

Reference： [1]Matsuo, Tsukasa; Kawaguchi, Hiroyuki [Journal of the American Chemical Society, 2006, vol. 128, # 38, p. 12362 - 12363]

39
[ 778-24-5 ]
[ 1626-24-0 ]
[ 1074-29-9 ]
[ 1613-66-7 ]

Yield	Reaction Conditions	Operation in experiment
1: 6 % Chromat. 2: 6 % Chromat. 3: 11 % Chromat.	With aluminium trichloride at 110 - 120℃; for 3h;

Reference： [1]Zhun; Sbitneva; Polivanov; Chernyshev [Russian Journal of General Chemistry, 2006, vol. 76, # 10, p. 1564 - 1570]

40
[ 56-33-7 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: tetrahydrofuran; various solvent(s) / 6 h / 0 °C 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C

Reference： [1]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]

41
[ 3839-31-4 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 74 percent / tetrahydrofuran; benzene-d6 / 16 h / Ambient temperature 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 2 steps 1: 38 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 2 steps 1: 38 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C

	Multi-step reaction with 3 steps 1: 0.3 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C 2: tetrahydrofuran; various solvent(s) / 6 h / 0 °C 3: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 2 steps 1: 45 percent Spectr_. / 1,2-dibromoethane / tetrahydrofuran; diethyl ether / 0 °C 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 3 steps 1: 35 percent / tetrahydrofuran / 1 h 2: 74 percent / N-bromosuccinimide / CCl₄ / 48 h / Heating 3: 50 percent Chromat_. / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) RT, 1 h

Reference： [1]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[2]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[3]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[4]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[5]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[6]Fuchikami, Takamasa; Ojima, Iwao [Journal of Organometallic Chemistry, 1981, vol. 212, # 2, p. 145 - 153]

42
[ 768-33-2 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 74 percent / tetrahydrofuran; benzene-d6 / 16 h / Ambient temperature 3: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 2 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 3 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 38 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C 3: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C

	Multi-step reaction with 2 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 6 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C
	Multi-step reaction with 3 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 38 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C 3: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 4 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 0.3 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C 3: tetrahydrofuran; various solvent(s) / 6 h / 0 °C 4: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 2 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 6 percent Chromat_. / O₂ / tetrahydrofuran / 0.02 h / 0 °C
	Multi-step reaction with 3 steps 1: Li / tetrahydrofuran / 6 h / 0 °C 2: 45 percent Spectr_. / 1,2-dibromoethane / tetrahydrofuran; diethyl ether / 0 °C 3: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 2 steps 1: 59 percent / Li / tetrahydrofuran / 4 h 2: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C
	Multi-step reaction with 3 steps 1: 89 percent / NaHCO₃, H₂O / acetone / 1 h / 0 °C 2: tetrahydrofuran; various solvent(s) / 6 h / 0 °C 3: 10 percent Spectr_. / tetrahydrofuran / 192 h / 4 °C

Reference： [1]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[2]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[3]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[4]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[5]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[6]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[7]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[8]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[9]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]
[10]Fleming, Ian; Roberts, Richard S.; Smith, Stephen C. [Journal of the Chemical Society. Perkin transactions I, 1998, # 7, p. 1209 - 1214]

43
[ 778-24-5 ]
1,3-bis(dimethylphenylsiloxy)-2,4-bis(dimethylphenylsilyl)-1,3-dioxo-1λ⁶,3λ⁶-dithiete [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 90.5 percent / 0.5 h / 0 °C 2: 1.6 M nBuLi / tetrahydrofuran; hexane / 1) -40 deg C, 60 min, 2) to r.t., 60 min

Reference： [1]Sundermeyer, Wolfgang; Walch, Andreas [Chemische Berichte, 1996, vol. 129, # 2, p. 161 - 167]

44
[ 79035-77-1 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 74 percent / N-bromosuccinimide / CCl₄ / 48 h / Heating 2: 50 percent Chromat_. / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) RT, 1 h

Reference： [1]Fuchikami, Takamasa; Ojima, Iwao [Journal of Organometallic Chemistry, 1981, vol. 212, # 2, p. 145 - 153]

45
phenylmagnesium chloride [ No CAS ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 83.4 percent / tetrahydrofuran / 1 h / 90 °C 2: 3.9 percent / tetrahydrofuran / 2 h / 50 °C

Reference： [1]Zhun', V. I.; Zhun', A. B.; Vlasenko, S. D.; Belorusskaya, L. A.; Chernyshev, E. A.; Sheludyakov, V. D. [Journal of general chemistry of the USSR, 1982, vol. 52, # 11, p. 2266 - 2270][Zhurnal Obshchei Khimii, 1982, vol. 52, # 11, p. 2565 - 2570]

46
[ 24964-64-5 ]
[ 778-24-5 ]
[ 403-42-9 ]
3-[3-(4-fluorophenyl)-3-oxo-1-propenyl]-benzonitrile [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With trifluorormethanesulfonic acid; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine In dichloromethane	17.A Step A: Step A: Preparation of 3-[3-(4-Fluorophenyl)-3-oxo-1-propenyl]-benzonitrile Triflic acid (3.2 g, 21 mmol) is added portionwise to diphenyldimethylsilane (2.22 g, 10.5 mmol) in 20 mL of dichloromethane and stirred for 1 hour. After cooling to -78° C., diisopropylethylamine (1.42 g, 11 mmol) and 4'-fluoroacetophenone (1.38 g, 10 mmol) are added and the reaction mixture stirred for another hour before adding 3-cyanobenzaldehyde (1.0 g, 7.62 mmol). After the reaction mixture is stirred 18 hours, it is diluted with 100 mL of dichloromethane and stirred 1 hour with a saturated solution of sodium bicarbonate. The organic layer is separated, dried (MgSO4), concentrated and columned over SiO2 eluding with dichloromethane to provide 0.8 g of the title compound; mp 170°-172° C.

Reference： [1]Current Patent Assignee: PFIZER INC - US5430047, 1995, A

47
cis-bis(phenyldimethylsilyl)bis(triethylphosphine)platinum(II) [ No CAS ]
[ 768-32-1 ]
[ 778-24-5 ]
[ 1145-98-8 ]

Yield	Reaction Conditions	Operation in experiment
1: 24.1% 2: 13.5% 3: 42.4%	In benzene-d6 heating in benzene-d6 soln. in a sealed NMR tube (80°C, 40 h); further product: polymers;

Reference： [1]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1988, # 8, p. 1411 - 1414]

48
cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum [ No CAS ]
[ 67-64-1 ]
[ 768-32-1 ]
[ 778-24-5 ]
[ 1145-98-8 ]

Yield	Reaction Conditions	Operation in experiment
1: 27% 2: 13.3% 3: 34.1%	80°C, 31 h;

Reference： [1]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1989, p. 467 - 470]

49
[ 591-51-5 ]
[ 75-78-5 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
86%	In not given

Reference： [1]Larsson, E.; Gilse van der Pals, E. van [Svensk Kemisk Tidskrift, 1951, vol. 63, p. 177 - 178] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 23, page 72 - 75]

50
[ 931-53-3 ]
cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum [ No CAS ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
17.5%	100°C, 15 h;

Reference： [1]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1989, p. 467 - 470]

51
[ 80-10-4 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
89%	With CH₃MgBr In not given
	With methyl magnesium iodide In not given
	With CH₃MgI In not given

Reference： [1]Freiser, H.; Eagle, M. V.; Speier, J. L. [Journal of the American Chemical Society, 1953, vol. 75, p. 2821 - 2824] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 22, page 68 - 71]
[2]Kipping, F. S. [Journal of the Chemical Society][Journal of the Chemical Society, 1927, p. 104 - 107]
[3][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 22, page 68 - 71]

52
cis-{PdMe₂(PMePh₂)2} [ No CAS ]
[ 776-76-1 ]
[ 778-24-5 ]
[ 7440-05-3 ]

Yield	Reaction Conditions	Operation in experiment
	In benzene (N2), dried solvents, room temp., gas evolution, Pd separates; SiMe2Ph2detected by GC, Si2Me2Ph4 is not formed;

Reference： [1]Schubert, Ulrich; Mueller, Christine [Journal of Organometallic Chemistry, 1989, vol. 373, p. 165 - 172]

53
[ 766-77-8 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	With Na In not given

Reference： [1]Benkeser, R. A.; Foster, D. J. [Journal of the American Chemical Society, 1952, vol. 74, p. 5314 - 5317] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 36, page 111 - 115]

54
[ 33085-81-3 ]
[ 778-24-5 ]
[ 108008-86-2 ]
[ 108008-82-8 ]
(Si(CH₃)2(C₆H₅)2)2Cr₂(C₁₀H₈) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
0%	In tetrahydrofuran byproducts: naphthalene; sealed glass ampule with (C10H8)2Cr, Ph2SiMe2 and dried THF was heated in a boiling water bath for 1 h with occasional agitation; under rigorous exclusion of the atmosphere; evapd., naphthalene and byproducts were removed by vac. sublimation, final residue was carefully sublimed yielding the mixt. of the products, total yield 16%; high-resolution mass spectral anals.;

Reference： [1]Bush, Benjamin F.; Lynch, Vincent M.; Lagowski [Organometallics, 1987, vol. 6, # 6, p. 1267 - 1275]

55
[ 768-32-1 ]
[ 1450-14-2 ]
[ 75-76-3 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrogen In neat (no solvent) byproducts: benzene; High Pressure; heating of (CH3)3Si(C6H5) at 300°C and 100 atm H2 pressure;;
	With H₂ In neat (no solvent) byproducts: benzene; High Pressure; heating of (CH3)3Si(C6H5) at 300°C and 100 atm H2 pressure;;

Reference： [1]Dolgov, B. N.; Vol'nov, Ju. N. [Zhurnal Obshchei Khimii, 1931, vol. 1, p. 91 - 104]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 20, page 62 - 66]

56
cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum [ No CAS ]
[ 768-32-1 ]
[ 778-24-5 ]
[ 1145-98-8 ]

Yield	Reaction Conditions	Operation in experiment
1: 82.9% 2: 0% 3: 0%	With P(C₆H₅)2CH₃ In benzene-d6 heating in benzene-d6 soln. in a sealed NMR tube (80°C, 40 h) with addn. of diphenylmethylphosphine (8 equiv. per Pt-complex); further products: polymers; detn. by GLC;
1: 81.3% 2: 0% 3: 0%	With P(C₆H₅)2CH₃ In benzene-d6 heating in benzene-d6 soln. in a sealed NMR tube (80°C, 40 h) with addn. of diphenylmethylphosphine (2 equiv. per Pt-complex); further products: polymers; detn. by GLC;
1: 65.6% 2: 12.6% 3: 5.2%	With P(C₆H₅)2CH₃ In benzene-d6 heating in benzene-d6 soln. in a sealed NMR tube (80°C, 40 h) with addn. of diphenylmethylphosphine (0.5 equiv. per Pt-complex); further products: polymers; detn. by GLC;

1: 50.3% 2: 27.2% 3: 12%	With P(C₅H₆)2CH₃ In benzene-d6 heating in benzene-d6 soln. in a sealed NMR tube (80°C, 40 h); further products: polymers; detn. by GLC;
1: 48.7% 2: 28.6% 3: 19.1%	In benzene-d6 heating in benzene-d6 soln. in a sealed NMR tube (80°C, 40 h); further products: polymers; detn. by 1H-NMR;

Reference： [1]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1988, # 8, p. 1411 - 1414]
[2]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1988, # 8, p. 1411 - 1414]
[3]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1988, # 8, p. 1411 - 1414]
[4]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1988, # 8, p. 1411 - 1414]
[5]Kobayashi, Toshi-aki; Hayashi, Teruyuki; Yamashita, Hiroshi; Tanaka, Masato [Chemistry Letters, 1988, # 8, p. 1411 - 1414]

57
[ 37865-47-7 ]
[ 136266-28-9 ]
[ 766-77-8 ]
[ 17881-88-8 ]
[ 778-24-5 ]
[ 1449-63-4 ]

Yield	Reaction Conditions	Operation in experiment
1: 3% 2: 4% 3: 14% 4: 54%	With methanol In benzene Irradiation (UV/VIS); irradiation of catenate in benzene containing an excess of methanol with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;

Reference： [1]Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro [Journal of Organometallic Chemistry, 1991, vol. 412, # 1.2, p. 9 - 19]

58
[ 15279-31-9 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
87%	With C₆H₅MgBr In not given

Reference： [1]McBride; Beachell [Journal of the American Chemical Society, 1952, vol. 74, p. 5247] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 68, page 188 - 190]

59
[ 96647-88-0 ]
[ 778-24-5 ]
[ 75061-54-0 ]
[ 75061-50-6 ]

Yield	Reaction Conditions	Operation in experiment
1: 42% 2: 5%	In 1,4-dioxane refluxing for 6.5 h (N2), evapn.; trituration, extn., filtered, pptn. of mono complex on cooling of filtrate, working up of residue from extn. gave bis complex; elem. anal.;
1: 26% 2: 7%	In 1,4-dioxane Ar-atmosphere; refluxing for 6 h; evapn. (vac.), chromy. (Al2O3, CH2Cl2/petroleum ether), recrystn. (hexane); elem. anal.;

Reference： [1]Nagelberg, S. B.; Reinhold, C. E.; Willeford, B. R.; Bigwood, M. P.; Molloy, K. C.; Zuckerman, J. J. [Organometallics, 1982, vol. 1, p. 851 - 858]
[2]Kolehmainen, E.; Laihia, K.; Korvola, J.; Kaganovich, V. S.; Rybinskaya, M. I.; Kerzina, Z. A. [Journal of Organometallic Chemistry, 1995, vol. 487, # 1-2, p. 215 - 222]

60
[ 778-24-5 ]
[ 13007-92-6 ]
[ 75061-54-0 ]

Yield	Reaction Conditions	Operation in experiment
44%	In tetrahydrofuran; diethylene glycol dimethyl ether heating at 150°C for 61 h (N2), chromy on silica gel (benzene), concn., pptn. with hexane, filtration, washing with hexane, drying in vac.; sepn. of mono complex by sublimation, chromy. on silica gel (benzene), concn., pptn. with hexane, washing with hexane, drying in vac., soln. in hot CHCl3, crystn. on addn. of petroleum ether and cooling; elem. anal.;

Reference： [1]Nagelberg, S. B.; Reinhold, C. E.; Willeford, B. R.; Bigwood, M. P.; Molloy, K. C.; Zuckerman, J. J. [Organometallics, 1982, vol. 1, p. 851 - 858]

61
dicobalt octacarbonyl [ No CAS ]
[ 778-24-5 ]
dimethyldiphenylsilane nonacarbonyltetracobalt [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
28%	In hexane; n-heptane Ar-atmosphere; stoich. amts., refluxing in hexane/heptane=2:1 v/v for 24h; chromy. (Al2O3, CH2Cl2/petroleum ether), recrystn. (hexane); elem. anal.;
	In hexane Ar-atmosphere; stoich. amts., refluxing;

Reference： [1]Kolehmainen, E.; Laihia, K.; Korvola, J.; Kaganovich, V. S.; Rybinskaya, M. I.; Kerzina, Z. A. [Journal of Organometallic Chemistry, 1995, vol. 487, # 1-2, p. 215 - 222]
[2]Kolehmainen, E.; Laihia, K.; Korvola, J.; Kaganovich, V. S.; Rybinskaya, M. I.; Kerzina, Z. A. [Journal of Organometallic Chemistry, 1995, vol. 487, # 1-2, p. 215 - 222]

62
[ 3839-31-4 ]
[ 583-55-1 ]
[ 544-97-8 ]
[ 778-24-5 ]

Yield	Reaction Conditions	Operation in experiment
100%	Stage #1: dimethyl(phenyl)silyl lithium; dimethyl zinc(II) In tetrahydrofuran; hexane at 0℃; for 0.5h; Stage #2: 1-Bromo-2-iodobenzene In tetrahydrofuran; hexane at 20℃; for 16h; Further stages.;

Reference： [1]Uchiyama, Masanobu; Kobayashi, Yuri; Furuyama, Taniyuki; Nakamura, Shinji; Kajihara, Yumiko; Miyoshi, Tomoko; Sakamoto, Takao; Kondo, Yoshinori; Morokuma, Keiji [Journal of the American Chemical Society, 2008, vol. 130, # 2, p. 472 - 480]

63
[ 1120-90-7 ]
[ 778-24-5 ]
3-(dimethylphenylsilanyl)pyridine [ No CAS ]