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Chemical Structure| 782504-35-2 Chemical Structure| 782504-35-2

Structure of 782504-35-2

Chemical Structure| 782504-35-2

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Product Details of [ 782504-35-2 ]

CAS No. :782504-35-2
Formula : C19H25N
M.W : 267.41
SMILES Code : CC(C1=CC=C(NC2=CC=C(C(C)(C)C)C=C2)C=C1)C
MDL No. :MFCD28130382
InChI Key :QSQSJBUBCKHJFG-UHFFFAOYSA-N
Pubchem ID :23106812

Safety of [ 782504-35-2 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501

Application In Synthesis of [ 782504-35-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 782504-35-2 ]

[ 782504-35-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 5433-01-2 ]
  • [ 5369-19-7 ]
  • [ 782504-35-2 ]
YieldReaction ConditionsOperation in experiment
88% With sodium t-butanolate;tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; In toluene; for 12h;Heating / reflux; Preparation Example 1-1: Preparation of 4-t-butyl-N- (4- isopropylphenyl ) benzenamine; As represented below in Reaction Scheme 1, 25g of 3-t- butylaniline (0.125mol) and 37.3g of 3-bromoisopropylbenzene(0.25mol) were dissolved in 25OmL of toluene, and 3.43g ofPd2(dba)3 (0.0037mol) was added thereto under a nitrogen atmosphere. Then, 14.4g of NaOBufc (0.15mol) and 1.157g of (t- Bu)3P (0.0075mol) were added to the reaction solvent, and the reaction mixture was refluxed and stirred for 12 hours. The reaction mixture was checked for the completion of the reaction by means of TLC, and if the reaction was completed, the reaction product was cooled down to room temperature. The reacted solution was poured onto a thin silica pad to perform short chromatography, and then was washed with methylene chloride (MC) . The washed solution was subjected to distillation under reduced pressure to thereby remove the solvent, and was chromatographed using n-hexane to thereby obtain a desired white solid product (29.4g, 88percent). [Reaction Scheme 1]
 

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