Alternatived Products of [ 822-24-2 ]
Product Details of [ 822-24-2 ]
CAS No. : | 822-24-2 |
MDL No. : | MFCD00056263 |
Formula : |
C22H44O2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
340.58
|
Pubchem ID : | - |
Synonyms : |
|
Application In Synthesis of [ 822-24-2 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 822-24-2 ]
- 1
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[ 629-96-9 ]
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[ 2754-27-0 ]
-
[ 822-24-2 ]
Yield | Reaction Conditions | Operation in experiment |
97% |
With trifluorormethanesulfonic acid In neat (no solvent) at 0 - 20℃; for 4h; Inert atmosphere; |
O-Acetylation Reaction; General Procedure
General procedure: To a round-bottomed flask charged with a magnetic stirrer and 1a-l(1.0 equiv) was added trimethylsilyl acetate (2.0 equiv for 1a-g and1j-k; 5.0 equiv for 1l) and TfOH (0.05 equiv for 1a-g and 1j-k; 0.1equiv for 1l) under a N2 atmosphere in an ice bath. The reaction mixturewas removed from the ice bath and then stirred at rt for an appropriateperiod (4 h for 1a-g and 1j-k; 12 h for 1l). After completionof the reaction, the mixture was concentrated. The crude productswere purified by column chromatography on silica gel to give the desiredproducts 2a-l. |
Reference:
[1]Chen, Jyun-Siao; Huang, Po-Hsun; Hsieh, Ya-Chi; Liu, Jen-Wei; Hsu, Hsiao-Lin; Zhang, Kai-Min; Wu, Ren-Tsung; Chang, Ting-Shuo; Liu, Yu-Hao; Wu, Hsin-Ru; Luo, Shun-Yuan
[Synthesis, 2021, vol. 54, # 3, p. 754 - 762]