[ CAS No. 83056-79-5 ] {[proInfo.proName]}

Name: 83056-79-5|(S)-tert-Butyl 1-methyl-2-oxoimidazolidine-4-carboxylate|97%
Brand: Ambeed
SKU: A165043
Price: 6.0 USD
Availability: InStock
Rating: 99 (25 reviews)

,{[proInfo.pro_purity]}

Cat. No.: {[proInfo.prAm]}

2D 3D

Structure of 83056-79-5 * Storage: {[proInfo.prStorage]}

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 83056-79-5 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 83056-79-5 ]

SDS Specification

Alternatived Products of [ 83056-79-5 ]

Product Details of [ 83056-79-5 ]

CAS No. :	83056-79-5	MDL No. :	MFCD09952527
Formula :	C₉H₁₆N₂O₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	JHSLVEQWBDYFQN-LURJTMIESA-N
M.W :	200.24	Pubchem ID :	13053976
Synonyms :

Safety of [ 83056-79-5 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 83056-79-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 83056-79-5 ]
Downstream synthetic route of [ 83056-79-5 ]

[ 83056-79-5 ] Synthesis Path-Upstream 1~4

1
[ 83056-78-4 ]
[ 83056-79-5 ]

Reference： [1] Journal of Medicinal Chemistry, 1989, vol. 32, # 2, p. 289 - 297
[2] Patent: US4380644, 1983, A,
[3] Patent: US4508727, 1985, A,

2
[ 157163-04-7 ]
[ 100-51-6 ]
[ 83056-79-5 ]

Reference： [1] Journal of Organic Chemistry, 1995, vol. 60, # 21, p. 6776 - 6784
[2] Journal of Organic Chemistry, 1995, vol. 60, # 21, p. 6776 - 6784

3
[ 77999-24-7 ]
[ 83056-79-5 ]

Reference： [1] Journal of Medicinal Chemistry, 1989, vol. 32, # 2, p. 289 - 297

4
[ 83056-79-5 ]
[ 89396-94-1 ]

Reference： [1] Journal of Medicinal Chemistry, 1989, vol. 32, # 2, p. 289 - 297
[2] Journal of Medicinal Chemistry, 1989, vol. 32, # 2, p. 289 - 297

[ 83056-79-5 ] Synthesis Path-Downstream 1~39

1
[ 22118-12-3 ]
[ 83056-79-5 ]
[ 195828-76-3 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

2
[ 88081-65-6 ]
[ 83056-79-5 ]
[ 130368-70-6 ]

Reference： [1]Chemical and Pharmaceutical Bulletin,1992,vol. 40,p. 1619 - 1622
[2]Chemical and Pharmaceutical Bulletin,1991,vol. 39,p. 1374 - 1377

3
[ 83261-13-6 ]
[ 83056-79-5 ]
[ 143996-80-9 ]

Reference： [1]Chemical and Pharmaceutical Bulletin,1992,vol. 40,p. 1619 - 1622

4
[ 85277-55-0 ]
[ 83056-79-5 ]
[ 130368-72-8 ]

Reference： [1]Chemical and Pharmaceutical Bulletin,1991,vol. 39,p. 1374 - 1377

5
[ 83056-79-5 ]
(S)-2-[(S)-1-(2,5-Dioxo-pyrrolidin-1-yloxycarbonyl)-ethylamino]-4-phenyl-butyric acid benzyl ester [ No CAS ]
[ 89460-20-8 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

6
[ 83056-79-5 ]
[ 89371-34-6 ]
[ 89371-38-0 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

7
[ 83056-79-5 ]
[ 89371-34-6 ]
[ 117605-22-8 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

8
[ 83056-78-4 ]
[ 83056-79-5 ]

Yield	Reaction Conditions	Operation in experiment
98.2%	In methanol; hydrogen;	(3) 8.5 g of tert.-butyl (4S)-1-methyl-3-benzyloxycarbonyl-2-oxo-imidazolidine-4-carboxylate are dissolved in 200 ml of methanol, and 0.1 g of palladium-black is added thereto. The mixture is shaken at room temperature in hydrogen gas atmosphere under atmospheric pressure. After the reaction the catalyst is removed by filtration, and the filtrate is condensed under reduced pressure. The residue obtained is washed with n-hexane. 5.0 g of tert.-butyl (4S)-1-methyl-2-oxo-imidazolidine-4-carboxylate are obtained as colorless crystals. Yield: 98.2percent M.p. 135°-136° C.
98.2%	palladium; In methanol; hydrogen;	(3) 8.5 g of tert.-butyl (4S)-1-methyl-3-benzyloxycarbonyl-2-oxo-imidazolidine-4-carboxylate are dissolved in 200 ml of methanol, and 0.1 g of palladium black is added thereto. The mixture is shaken at room temperature in hydrogen gas atmosphere under atmospheric pressure. After the reaction the catalyst is removed by filtration, and the filtrate is concentrated under reduced pressure. The residue obtained is washed with n-hexane. 5.0 g of tert.-butyl (4S)-1-methyl-2-oxo-imidazolidine-4-carboxylate are obtained as colorless crystals. Yield: 98.2percent M.p. 135°-136° C. IR numaxnujol (cm-1): 3300, 1735, 1700

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297
[2]Patent: US4380644,1983,A
[3]Patent: US4508727,1985,A

9
[ 83056-79-5 ]
[ 3401-36-3 ]
[ 117560-20-0 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

10
[ 83056-79-5 ]
[ 7148-74-5 ]
[ 195828-75-2 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

11
[ 74204-03-8 ]
[ 83056-79-5 ]
[ 195828-77-4 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

12
[ 83056-79-5 ]
2-Bromo-4-phenyl-butyryl bromide [ No CAS ]
[ 195828-78-5 ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

13
[ 157163-04-7 ]
[ 100-51-6 ]
[ 83056-79-5 ]
Benzyl N-benzyl-D-alaninate [ No CAS ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784
[2]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

14
[ 83056-79-5 ]
[ 82820-87-9 ]
(S)-3-(2,4-Dibromo-butyryl)-1-methyl-2-oxo-imidazolidine-4-carboxylic acid tert-butyl ester [ No CAS ]

Reference： [1]Chemical and Pharmaceutical Bulletin,1998,vol. 46,p. 787 - 796

15
[ 83056-79-5 ]
tert-Butyl (4S)-3-<(2R)-2-(N-benzylamino)-4-methylvaleryl>-1-methyl-2-oxoimidazolidine-4-carboxylate [ No CAS ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

16
[ 83056-79-5 ]
tert-Butyl (4S)-3-<(2S)-2-(N-benzylamino)-4-methylvaleryl>-1-methyl-2-oxoimidazolidine-4-carboxylate [ No CAS ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

17
[ 83056-79-5 ]
tert-Butyl (4S)-3-<(2S)-2-(N-benzylamino)-4-phenylbutyryl>-1-methyl-2-oxoimidazolidine-4-carboxylate [ No CAS ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

18
[ 83056-79-5 ]
tert-Butyl (4S)-3-<(2R)-2-(N-benzylamino)-4-phenylbutyryl>-1-methyl-2-oxoimidazolidine-4-carboxylate [ No CAS ]

Reference： [1]Journal of Organic Chemistry,1995,vol. 60,p. 6776 - 6784

19
[ 83056-79-5 ]
[ 89396-94-1 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297
[2]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

20
[ 83056-79-5 ]
[ 117605-23-9 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297
[2]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

21
[ 83056-79-5 ]
[ 89371-38-0 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

22
[ 83056-79-5 ]
[ 117605-21-7 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

23
[ 83056-79-5 ]
[ 89371-44-8 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

24
[ 83056-79-5 ]
[ 117581-62-1 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

25
[ 83056-79-5 ]
[ 89371-74-4 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

26
[ 83056-79-5 ]
[ 89371-73-3 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

27
[ 83056-79-5 ]
[ 117605-19-3 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297
[2]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297
[3]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

28
[ 83056-79-5 ]
[ 89384-26-9 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

29
[ 83056-79-5 ]
[ 117605-20-6 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

30
[ 83056-79-5 ]
[ 117605-22-8 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297
[2]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

31
[ 83056-79-5 ]
[ 89371-81-3 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

32
[ 83056-79-5 ]
[ 89397-13-7 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

33
[ 77999-24-7 ]
[ 83056-79-5 ]

Reference： [1]Journal of Medicinal Chemistry,1989,vol. 32,p. 289 - 297

34
[ 136622-16-7 ]
[ 83056-79-5 ]
[ 130368-72-8 ]

Yield	Reaction Conditions	Operation in experiment
75.8%		(1) D-lactic acid O-mesylate, namely (2R)-2-(methanesulfonyloxy)propionic acid (2.5 g) and t-butyl (4S)-1-methyl-2-oxoimidazolidine-4-carboxylate (3.42 g) were treated similarly as in Example 1 - (1), and the crude product was purified by silica gel chromatography (chloroform:ethyl acetate=1:2) and crystallized from n-hexane to give t-butyl (4S)-1-methyl-3-[(2R)-2-(methanesulfonyloxy)-propionyl]-2-oxoimidazolidine-4carboxylate (3.95 g). Yield: 75.8percent., m.p.: 97°-100° C. [alpha]D25: -3.2° (C=2, chloroform). IR upsilonmaxNujol (cm-1); 1740, 1700. NMR (CDCl3) delta: 1.46 (9H,s), 1.61 (3H,d,J=7 Hz) 2.89 (3H,s), 3.02 (3H,s), 3.35 (1H,dd,J=4,10 Hz), 3.74(1H,t,J=10 Hz), 4.58 (1H,dd,J=4,10 Hz), 6.35 (1H,q,J=7 Hz).

Reference： [1]Patent: US5013845,1991,A

35
toluene-ethyl acetate [ No CAS ]
[ 865-47-4 ]
[ 83056-79-5 ]
[ 72679-02-8 ]
[ 72679-01-7 ]
tert.-butyl (4S)-1-methyl-3-[(2S)-3-benzoylthio-2-methylpropionyl]-2-oxo-imidazolidine-4-carboxylate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
73.9%	With thionyl chloride; In tetrahydrofuran; ethyl acetate;	(2) 3.0 g of <strong>[83056-79-5]tert.-butyl (4S)-1-methyl-2-oxo-imidazolidine-4-carboxylate</strong> are dissolved in 20 ml of tetrahydrofuran. 1.7 g of potassium tert.-butoxide are added to the solution under cooling at about -30° C. and stirring, and the mixture is further stirred at the same temperature for 10 minutes. A solution of (2S)-3-benzoylthio-2-methylpropionyl chloride (prepared by heating the mixture of 3.4 g of (2S)-3-benzoylthio-2-methylpropionic acid and 10 ml of thionyl chloride at 50°-60° C. for 2 hours and then evaporating excess thionyl chloride under reduced pressure) in 10 ml of tetrahydrofuran is added dropwise to the mixture under ice-cooling and stirring. Then, said mixture is further stirred at room temperature overnight. After the reaction, the mixture is condensed under reduced pressure, and the residue is dissolved in ethyl acetate. The ethyl acetate solution is washed with water and an aquous sodium bicarbonate solution, dried and then evaporated to remove solvent. The oily residue thus obtained is purified by silica gel column chromatography (Solvent, toluene-ethyl acetate(20:1)). 4.5 g of tert-butyl (4S)-1-methyl-3-[(2S)-3-benzoylthio-2-methylpropionyl]-2-oxo-imidazolidine-4-carboxylate are obtained as colorless crystals. Yield: 73.9percent M.p. 128° C.

Reference： [1]Patent: US4380644,1983,A

36
[ 865-47-4 ]
[ 83056-79-5 ]
[ 7148-74-5 ]
[ 195828-75-2 ]

Yield	Reaction Conditions	Operation in experiment
72.7%	In tetrahydrofuran;	(1) 6.0 g of <strong>[83056-79-5]tert.-butyl (4S)-1-methyl-2-oxo-imidazolidine-4-carboxylate</strong>, 5.2 g of 2-bromopropionyl chloride, 3.4 g of potassium tert.-butoxide and 80 ml of tetrahydrofuran are treated in the same manner as described in Example 10-(1), whereby 7.3 g of tert.-butyl (4S)-1-methyl-3-(2-bromopropionyl)-2-oxo-imidazolidine-4-carboxylate are obtained as colorless crystals. Yield: 72.7percent IR numaxnujol (cm-1): 1740, 1680

Reference： [1]Patent: US4508727,1985,A

37
[ 22118-12-3 ]
[ 865-47-4 ]
[ 83056-79-5 ]
[ 195828-76-3 ]

Yield	Reaction Conditions	Operation in experiment
80.3%	In tetrahydrofuran;	(1) 5.0 g of <strong>[83056-79-5]tert.-butyl (4S)-1-methyl-2-oxo-imidazolidine-4-carboxylate</strong>, 4.7 g of 2-bromo-n-butyryl chloride, 2.8 g of potassium tert.-butoxide and 60 ml of tetrahydrofuran are treated in the same manner as described in Example 10-(1), whereby 7.0 g of tert.-butyl (4S)-1-methyl-3-(2-bromo-n-butyryl)-2-oxo-imidazolidine-4-carboxylate are obtained as colorless crystals. Yield: 80.3percent M.p. 61°-62° C.

Reference： [1]Patent: US4508727,1985,A

38
[ 83056-79-5 ]
[ 84793-24-8 ]
[ 928142-34-1 ]

Yield	Reaction Conditions	Operation in experiment
		150gms of <strong>[83056-79-5]t-butyl 4(S)-1-methyl-2-oxoimidazolidine-4-carboxylate</strong> charged into 450ml of tetrahydrofuran and cooled a temperature of -45 to -5O0C. 235gms of (S)-ethyl~2-[(S)- 4-methyl-2,5-dioxooxazolidin-3-yl]-4-phenylbutanoate was dissolved in 550ml of tetrahydrofuran and added to above reaction mixture at -45 to -5O0C. The reaction mass was stirred for 90min at -45 to -5O0C and quenched into another flask which contains 1.2lts of ethyl acetate and 600ml of water. The organic layer, after separation, was washed with saturated sodium chloride and dried over anhydrous sodiumsulphate. 350ml of 10percent isopropanolic hydrochloride added to the organic layer and concentrated under reduced pressure. After complete removal of the solvent, 600ml of diisopropylether was added. The precipitated crystals were filtered and dried. The product obtained was 338gms with a specific rotation of -57.4°. (The product was characterized by 1H NMR)1.28 (3H, -CH3); 1.30 (3H, -CH3); 1.40 (9H, 3 x -CH3); 2.70 ( 3H;-CH3); 2.09(2H, -CH2) ; 2.55 (2H, -CH2);3.64 (2H1 -CH2); 4.12 (2H, -CH2); 3.45 (1 H1-CH); 3.74 (1 H1-CH); 5.05 (1H, -CH); 7.08-7.21 (5H, aromatic CH);2.00 (1H, NH)

Reference： [1]Patent: WO2007/29267,2007,A1 .Location in patent: Page/Page column 8-9

39
[ 83056-79-5 ]
[ 84793-24-8 ]
[ 89371-38-0 ]

Reference： [1]Chemistry - A European Journal,2019,vol. 25,p. 14527 - 14531

Same Skeleton Products

Related Products

Historical Records

Related Functional Groups of
[ 83056-79-5 ]

Amides

[ 171504-96-4 ]

Methyl 1-acetylpiperazine-2-carboxylate

Similarity: 0.71

[ 252990-05-9 ]

1-(tert-Butyl) 2-methyl (R)-piperazine-1,2-dicarboxylate

Similarity: 0.70

[ 314741-39-4 ]

(S)-1-tert-Butyl 3-methyl piperazine-1,3-dicarboxylate

Similarity: 0.70

[ 796096-64-5 ]

(S)-1-tert-Butyl 2-methyl piperazine-1,2-dicarboxylate

Similarity: 0.70

[ 438631-77-7 ]

(R)-1-tert-Butyl 3-methyl piperazine-1,3-dicarboxylate

Similarity: 0.70

Esters

[ 171504-96-4 ]

Methyl 1-acetylpiperazine-2-carboxylate

Similarity: 0.71

[ 252990-05-9 ]

1-(tert-Butyl) 2-methyl (R)-piperazine-1,2-dicarboxylate

Similarity: 0.70

[ 314741-39-4 ]

(S)-1-tert-Butyl 3-methyl piperazine-1,3-dicarboxylate

Similarity: 0.70

[ 796096-64-5 ]

(S)-1-tert-Butyl 2-methyl piperazine-1,2-dicarboxylate

Similarity: 0.70

[ 438631-77-7 ]

(R)-1-tert-Butyl 3-methyl piperazine-1,3-dicarboxylate

Similarity: 0.70

Related Parent Nucleus of
[ 83056-79-5 ]

Aliphatic Heterocycles

[ 171504-96-4 ]

Methyl 1-acetylpiperazine-2-carboxylate

Similarity: 0.71

[ 252990-05-9 ]

1-(tert-Butyl) 2-methyl (R)-piperazine-1,2-dicarboxylate

Similarity: 0.70

[ 314741-39-4 ]

(S)-1-tert-Butyl 3-methyl piperazine-1,3-dicarboxylate

Similarity: 0.70

[ 796096-64-5 ]

(S)-1-tert-Butyl 2-methyl piperazine-1,2-dicarboxylate

Similarity: 0.70

[ 438631-77-7 ]

(R)-1-tert-Butyl 3-methyl piperazine-1,3-dicarboxylate

Similarity: 0.70

Imidazolidines

[ 89396-94-1 ]

(S)-3-((S)-2-(((S)-1-Ethoxy-1-oxo-4-phenylbutan-2-yl)amino)propanoyl)-1-methyl-2-oxoimidazolidine-4-carboxylic acid hydrochloride

Similarity: 0.65

[ 59564-78-2 ]

1,3-Bisbenzyl-2-oxoimidazolidine-4,5-dicarboxylic acid

Similarity: 0.61

[ 87219-22-5 ]

2-(2-Oxoimidazolidin-1-yl)acetic acid

Similarity: 0.59

[ 119838-38-9 ]

(S)-tert-Butyl 2-(tert-butyl)-3-methyl-4-oxoimidazolidine-1-carboxylate

Similarity: 0.51

[ 6440-58-0 ]

1,3-Bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione

Similarity: 0.51

Ghs Precautionary Statements

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Purity	Size	Price	VIP Price	USA Stock *0-1 Day	Global Stock *5-7 Days	Quantity
{[ item.p_purity ]}	{[ item.pr_size ]}	{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]}	{[ getRatePrice(item.pr_usd, 1,1) ]}	Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]}	{[ item.pr_usastock ]}	Inquiry -	{[ item.pr_chinastock ]}	Inquiry -

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 83056-79-5 ] {[proInfo.proName]}

Quality Control of [ 83056-79-5 ]

Related Doc. of [ 83056-79-5 ]

Product Details of [ 83056-79-5 ]

Safety of [ 83056-79-5 ]

Application In Synthesis of [ 83056-79-5 ]

[ 83056-79-5 ] Synthesis Path-Upstream 1~4

[ 83056-79-5 ] Synthesis Path-Downstream 1~39

Related Functional Groups of [ 83056-79-5 ]

Amides

Esters

Related Parent Nucleus of [ 83056-79-5 ]

Aliphatic Heterocycles

Imidazolidines

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry

Related Functional Groups of
[ 83056-79-5 ]

Related Parent Nucleus of
[ 83056-79-5 ]