Name: 87-88-7|2,5-Dichloro-3,6-dihydroxycyclohexa-2,5-diene-1,4-dione|95%
Brand: Ambeed
SKU: A332732
Price: 15.0 USD
Availability: InStock
Rating: 98 (28 reviews)

1
[ 87-88-7 ]
4,8-dichloro-benzo[1,2-<i>d</i>;4,5-<i>d</i>']bis[1,3,2]dioxaborole [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	With borane-THF In tetrahydrofuran at 20℃; for 12h;

Reference： [1]Aldridge; Calder; Cunningham; Malik; Steed [Journal of Organometallic Chemistry, 2000, vol. 614-615, p. 188 - 194]

2
[ 87-88-7 ]
[ 564480-29-1 ]
C₆H₂Cl₂O₄*C₉H₆N₂S₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	In dimethyl sulfoxide; acetonitrile at 20℃;

Reference： [1]Murata, Tsuyoshi; Morita, Yasushi; Yakiyama, Yumi; Fukui, Kozo; Yamochi, Hideki; Saito, Gunzi; Nakasuji, Kazuhiro [Journal of the American Chemical Society, 2007, vol. 129, # 35, p. 10837 - 10846]

3
[ 12126-50-0 ]
[ 87-88-7 ]
[ 7732-18-5 ]
[ 262427-13-4 ]

Reference： [1]Inorganica Chimica Acta,2001,vol. 318,p. 127 - 134

4
Iron(III) nitrate nonahydrate [ No CAS ]
[ 12126-50-0 ]
[ 87-88-7 ]
[ 493029-44-0 ]

Reference： [1]Journal of the American Chemical Society,2003,vol. 125,p. 221 - 232

5
hexaaquairon(III) perchlorate [ No CAS ]
[ 4199-89-7 ]
[ 87-88-7 ]
Fe₂(C₆Cl₂O₄)(ClC₁₂H₇N₂)4⁽⁴⁺⁾*4ClO₄^(1-)=[Fe₂(C₆Cl₂O₄)(ClC₁₂H₇N₂)4](ClO₄)4 [ No CAS ]

Reference： [1]Polyhedron,1998,vol. 17,p. 1423 - 1427

6
[ 87-88-7 ]
[ 123-03-5 ]
bis(hexadecylpyridinium) bis(3,6-dichloro-4,5-dihydroxy-3,5-cyclohexadiene-1,2-dionato-κ(2)O(4),O(5))beryllium [ No CAS ]

Reference： [1]Acta Crystallographica, Section C: Crystal Structure Communications,1995,vol. 51,p. 190 - 193

7
[ 67-56-1 ]
iron(II) tetrafluoroborate hexahydrate [ No CAS ]
[ 87-88-7 ]
[ 16858-01-8 ]
[(tris(2-pyridylmethyl)amine)(OH)FeOFe(OH)(tris(2-pyridylmethyl)amine)][Fe(chloranilato)3]0.5(BF₄)0.5*1.5MeOH*H₂O [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2006,vol. 128,p. 40 - 41

8
[ 67-56-1 ]
[ 15684-35-2 ]
[ 87-88-7 ]
[ 16858-01-8 ]
[(tris(2-pyridylmethyl)amine)Co(II)(chloranilic acid^(2-))Co(II)(tris(2-pyridylmethyl)amine)](BF₄)2*2MeOH [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2007,vol. 129,p. 2360 - 2368

9
[ 67-56-1 ]
iron(II) tetrafluoroborate hexahydrate [ No CAS ]
[ 87-88-7 ]
[ 16858-01-8 ]
[(tris(2-pyridylmethyl)amine)Fe(II)(chloranilic acid^(2-))Fe(II)(tris(2-pyridylmethyl)amine)](BF₄)2*2MeOH [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2007,vol. 129,p. 2360 - 2368

10
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] [ No CAS ]
[ 87-88-7 ]
[ 1050443-03-2 ]

Yield	Reaction Conditions	Operation in experiment
81%	With CH₃ONa In methanol (N2); ligand added to a soln. of CH3ONa, stirred for 1 h, Ir complex added at room temp., stirred for 6 h; solvent-removed, extd. (CH2Cl2), concd., Et2O added; elem. anal.;

Reference： [1]Han, Ying-Feng; Lin, Yue-Jian; Jia, Wei-Guo; Jin, Guo-Xin [Organometallics, 2008, vol. 27, # 16, p. 4088 - 4097]

11
[ 52462-29-0 ]
[ 87-88-7 ]
[ 1052687-67-8 ]

Yield	Reaction Conditions	Operation in experiment
85%	With CH₃ONa In methanol under N2; chloranilic acid added to soln. of CH3ONa in MeOH; stirred for1 h; Ru complex added at room temp.; stirred for 6 h; solvent removed; washed with H2O; elem. anal.;
74%	In methanol a mixt. of Ru-complex and benzoquinone-compound was suspd. in methanol and stirred for 2 h at room temp.; ppt. was filtered, washed with diethyl ether, dried in vac.; elem. anal.;

Reference： [1]Han, Ying-Feng; Jia, Wei-Guo; Lin, Yue-Jian; Jin, Guo-Xin [Organometallics, 2008, vol. 27, # 19, p. 5002 - 5008]
[2]Mattsson, Johan; Govindaswamy, Padavattan; Furrer, Julien; Sei, Yoshihisa; Yamaguchi, Kentaro; Suess-Fink, Georg; Therrien, Bruno [Organometallics, 2008, vol. 27, # 17, p. 4346 - 4356]

12
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer [ No CAS ]
[ 87-88-7 ]
[ 1064317-65-2 ]

Yield	Reaction Conditions	Operation in experiment
87%	With CH₃ONa In methanol under N2; chloranilic acid added to soln. of CH3ONa in MeOH; stirred for1 h; Rh complex added at room temp.; stirred for 6 h; solvent removed; washed with H2O; elem. anal.;

Reference： [1]Han, Ying-Feng; Jia, Wei-Guo; Lin, Yue-Jian; Jin, Guo-Xin [Organometallics, 2008, vol. 27, # 19, p. 5002 - 5008]

13
[ 17455-13-9 ]
[ 87-88-7 ]
[(18C₆)(CLA)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform at 20℃; for 1h;	2.2. Synthesis of 18-crown-6 CT complexes General procedure: The solid CT complexes of 18-crown-6 with p-CHL, o-CHL, DDQ, TCNQ, DCQ, DBQ, CLA, NBS, and PA were prepared by mixing 1mM of the 18C6 as a donor in chloroform (30 mL) for all complexes except for (DCQ and DBQ in methanol) with 1mMof each acceptor. The mixture was stirred at room temperature for 1 h, where solid complexes were obtained. The complexes were filtered off, washed with chloroform, and dried under vacuum.

Reference： [1]Location in patent: experimental part Hossan, Aisha S.M.; Abou-Melha, Hanaa M.; Refat, Moamen S. [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2011, vol. 79, # 3, p. 583 - 593]

14
[ 87-88-7 ]
[ 119-93-7 ]
2,2'-[(3,3'-dimethylbiphenyl-4,4'-diyl)bis(aminohydroxy)]bis(3,6-dichloro-5-hydroxy-benzo-1,4-quinone) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol at 20℃; for 0.75h;	2.1. Synthesis of o-TOL/PA and o-TOL/CA charge-transfer complexes The two solid CT-complexes of o-TOL with PA or CA were prepared by mixing a saturated solution of the o-TOL donor in 10 ml MeOHto each of saturated solutions of PA or CA in the same solvent with continuously stirring for about 45 min at room temperature. The solutions were allowed to evaporate slowly at room temperature, the resulted complexes in the solid state filtered and washed several times with little amounts of solvent, and dried under vacuum over anhydrous calcium chloride. Charge-transfer complexes of o-TOL/PA formed with empirical formula C26H22N8O14 with molecular weight 670.5 g/mol and o-TOL/CA formed with empirical formula C26H20N2Cl4O8 with molecular weight 630.3 g/mol.

Reference： [1]Location in patent: experimental part Refat, Moamen S.; Saad, Hosam A.; Adam, Abdel Majid A. [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2011, vol. 79, # 3, p. 672 - 679]

15
[ 87-88-7 ]
[ 579-56-6 ]
C₆H₄Cl₂O₄^(1-)*C₁₈H₂₃NO₃⁽¹⁺⁾ [ No CAS ]

Reference： [1]Croatica Chemica Acta,2010,vol. 83,p. 415 - 420

16
[ 87-88-7 ]
[ 54965-21-8 ]
C₆H₂Cl₂O₄*C₁₂H₁₅N₃O₂S [ No CAS ]

Reference： [1]Chinese Journal of Chemistry,2011,vol. 29,p. 324 - 332

17
tin (IV) chloride pentahydrate [ No CAS ]
calcium(II) nitrate tetrahydrate [ No CAS ]
[ 87-88-7 ]
[ 429-06-1 ]
(Et₄N)2[SnCa(chloranilate)4]*H₂O [ No CAS ]

Reference： [1]Dalton Transactions,2011,vol. 40,p. 12242 - 12247

18
[ 87-88-7 ]
[ 84057-84-1 ]
C₆H₂Cl₂O₄*C₉H₇Cl₂N₅ [ No CAS ]

Reference： [1]Journal of the Indian Chemical Society,2011,vol. 88,p. 1273 - 1292

19
[ 87-88-7 ]
[ 90729-43-4 ]
C₆H₂Cl₂O₄^(1-)*C₃₂H₃₉NO₂⁽¹⁺⁾ [ No CAS ]

Reference： [1]Journal of Fluorescence,2012,vol. 22,p. 175 - 191

20
[ 1558-17-4 ]
[ 87-88-7 ]
[ 1250412-47-5 ]

Reference： [1]Physica B: Condensed Matter,2010,vol. 405,p. S341-S343

21
[ 141-86-6 ]
[ 87-88-7 ]
3C₅H₇N₃*2C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile at 20℃;	2.3 Synthesis of the solid CT-complex The solid CT-complex between 2,6-DAP and CLA was prepared by mixing equimolar amounts of 2,6-DAP and CLA in acetonitrile. The resulting complex solution was allowed to evaporate slowly at room temperature where the complex was isolated as dark pink crystals. The isolated complex was filtered, washed well with acetonitrile and dried over calcium chloride for 24 h. Analytical thin-layer chromatography (TLC) was performed on aluminum sheets protected with silica gel (Merck, Kieselgel 60F-254).Visualization was accomplished by UV light. Both the analytical and spectroscopic data confirmed ≥ 95% purity of the prepared compound. Anal. Calc. for [(2,6-DAP)3(CLA)2] C27H25N9Cl4O8 Complex: C, 43.48%; H, 3.36%; N, 16.91%. Found: C, 43.28%; H, 3.62%; N, 16.98%. MP > 380 ОC.

Reference： [1]Alghanmi, Reem M.; Habeeb, Moustafa M. [Journal of Molecular Liquids, 2013, vol. 181, p. 20 - 28]

22
[ 141-86-6 ]
[ 87-88-7 ]
2C₅H₇N₃*2C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile at 20℃;	2.3 Synthesis of the solid CT-complex The solid CT-complex between 2,6-DAP and CLA was prepared by mixing equimolar amounts of 2,6-DAP and CLA in acetonitrile. The resulting complex solution was allowed to evaporate slowly at room temperature where the complex was isolated as dark pink crystals. The isolated complex was filtered, washed well with acetonitrile and dried over calcium chloride for 24 h. Analytical thin-layer chromatography (TLC) was performed on aluminum sheets protected with silica gel (Merck, Kieselgel 60F-254).Visualization was accomplished by UV light. Both the analytical and spectroscopic data confirmed ≥ 95% purity of the prepared compound.

Reference： [1]Alghanmi, Reem M.; Habeeb, Moustafa M. [Journal of Molecular Liquids, 2013, vol. 181, p. 20 - 28]

23
[ 142-08-5 ]
[ 87-88-7 ]
[ 1438160-60-1 ]

Yield	Reaction Conditions	Operation in experiment
78.84%	In ethanol at 20℃;	2.2 2.2.2. [(H2PyO)(HCA)] (2) 2.2.2 [(H2PyO)(HCA)] (2) To a solution of HPyO (95.2 mg 1.0 mmol) in EtOH (20 mL), a solution of H2CA (211.0 mg, 1.01 mmol) in EtOH (30 mL) was added at room temperature. The formed violet precipitate was filtered off, washed with the same solvent (3 * 1/2 mL) and dried in vacuo overnight over CaCl2. Yield: 240.0 mg (78.84%). Anal. found (Calcd. for C11H7Cl2NO5, 304.08): C, 43.67 (43.45); H, 2.44 (2.32); N, 4.69 (4.61); Cl, 22.99 (23.32).

Reference： [1]Gaballa, Akmal S. [Journal of Molecular Structure, 2013, vol. 1043, p. 91 - 102]

24
[ 54-96-6 ]
[ 87-88-7 ]
C₅H₇N₃*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol	Preparation of the solid 1:1 complexes 2,3-DAP-CHA and 2,3-DAPDHBQ The solid CT-complexes (1:1) between 2,3-DAP and CHA and between 2,3-DAP and DHBQ were prepared by mixing equimolar amounts of 2,3-DAP with CHA and 2,3-DAP with DHBQ in EtOH.The resulting complexes solutions were allowed to evaporate slowly at room temperature where the complexes were isolated as reddish purple and reddish-brown crystals for 2,3-DAP-CHA and 2,3-DAP-DHBQ complexes respectively. The separated complexes were filtered off, washed well with EtOH and dried over calcium chloride for 24 h.
	In methanol at 20℃;

Reference： [1]Al-Ahmary, Khairia M. [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2014, vol. 117, p. 635 - 644]
[2]Alghanmi, Reem M.; Basha, Maram T.; Soliman, Saied M.; Alsaeedi, Razan K. [Journal of Molecular Liquids, 2021, vol. 326]

25
[ 87-88-7 ]
[ 1643-19-2 ]
[ 7705-08-0 ]
[(n-Bu)4N]3[Fe(Cl₂An)3] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	With sodium hydroxide In water at 60℃; for 0.5h;

Reference： [1]Atzori, Matteo; Artizzu, Flavia; Sessini, Elisa; Marchio, Luciano; Loche, Danilo; Serpe, Angela; Deplano, Paola; Concas, Giorgio; Pop, Flavia; Avarvari, Narcis; Mercuri, Maria Laura [Dalton Transactions, 2014, vol. 43, # 19, p. 7006 - 7019]

26
2,2'-(azanediylbis(ethane-2,1-diyl))bis(1H-benzo[de]isoquinoline-1,3(2H)-dione) [ No CAS ]
[ 87-88-7 ]
C₂₈H₂₁N₃O₄*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform at 20℃; for 0.5h;	Synthesis of CT complexes General procedure: An chloroformic solution of L1 or L2 (1 mmol) was stirred with an chloroformic solution of each acceptor (PA, CLA, TCNQ or DDQ) (1 mmol) for ca. 30 min on a magnetic stirrer at room temperature. Then the solution was reduced to one-half by evaporation on a water bath. All the complexes were prepared by the same method and isolated as powdered material. The formed complexes were isolated as yellow, violet, dark yellow, reddish-brown, olive green and reddish-brown powder for L1-PA, L1-CLA, L2-PA, L2-CLA, L2- TCNQ and L2-DDQ complexes, respectively. The solid products were filtered off and washed thoroughly with pure-grade chloroform. Then, the products were collected and dried in vacuo for 48 h.

Reference： [1]Refat, Moamen S.; Ismail, Lamia A.; Adam, Abdel Majid A. [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, vol. 134, p. 288 - 301]

27
[ 87-88-7 ]
[ 339531-80-5 ]
C₂₈H₁₉Cl₂N₃O₄*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform at 20℃; for 0.5h;	Synthesis of CT complexes General procedure: An chloroformic solution of L1 or L2 (1 mmol) was stirred with an chloroformic solution of each acceptor (PA, CLA, TCNQ or DDQ) (1 mmol) for ca. 30 min on a magnetic stirrer at room temperature. Then the solution was reduced to one-half by evaporation on a water bath. All the complexes were prepared by the same method and isolated as powdered material. The formed complexes were isolated as yellow, violet, dark yellow, reddish-brown, olive green and reddish-brown powder for L1-PA, L1-CLA, L2-PA, L2-CLA, L2- TCNQ and L2-DDQ complexes, respectively. The solid products were filtered off and washed thoroughly with pure-grade chloroform. Then, the products were collected and dried in vacuo for 48 h.

Reference： [1]Refat, Moamen S.; Ismail, Lamia A.; Adam, Abdel Majid A. [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, vol. 134, p. 288 - 301]

28
[ 87-88-7 ]
[ 124937-52-6 ]
C₂₂H₃₁NO*C₄H₆O₆*C₆H₂Cl₂O₄ [ No CAS ]

Reference： [1]Journal of the Chemical Society of Pakistan,2013,vol. 35,p. 333 - 337

29
crizotinib [ No CAS ]
[ 87-88-7 ]
C₂₁H₂₂Cl₂FN₅O*2C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile at 25℃; for 0.166667h;
	In methanol at 25℃; for 0.0833333h;	2.4 General analytical procedure General procedure: Aliquots (100µL) of the standard or sample solution containing different amounts of CZT (1-60, 4-1000 and 10-1000µgmL-1 for assays using iodine, CHBQ and TCNQ, respectively) were precisely measured and transmitted into of 96-microwell assay plates wells. One hundred microliters of iodine (0.02%, w/v), CHBQ (0.4%, w/v) and TCNQ (0.5%, w/v) were separately added. The reactions were allowed to proceed for 5min at room temperature (25±2°C) for iodine and CHBQ, and 15min at 25±2°C for TCNQ. The resulting solutions’ absorbances were measured by the microwell-plate reader at 292, 515 and 842nm for assays using iodine, CHBQ and TCNQ, respectively. Similarly, blank wells were handled except 100µL of solvent was accurately measured in place of sample, and the blank wells’ absorbances were deducted from those of the other wells. The guidelines of the International Conference on Harmonization (ICH) for validation of analytical procedures were adopted to validate the proposed assays.

Reference： [1]Darwish, Ibrahim A.; Alshehri, Jamilah M.; Alzoman, Nourah Z.; Khalil, Nasr Y.; Abdel-Rahman, Hamdy M. [Journal of Solution Chemistry, 2014, vol. 43, # 7, p. 1282 - 1295]
[2]Darwish, Ibrahim A.; Alzoman, Nourah Z.; Alshehri, Jamilah M.; Darwish, Hany W.; Hamidaddin, Mohammed A.; Sayed, Ahmed Y. [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2021, vol. 259]

30
[ 4704-94-3 ]
[ 87-88-7 ]
2,5-dichloro-3,6-dihydroxybenzo-1,4-quinone-2-(hydroxymethyl)propane-1,3-diol [ No CAS ]

Reference： [1]Russian Journal of General Chemistry,2014,vol. 84,p. 1417 - 1428

31
[ 87-88-7 ]
[ 274901-16-5 ]
C₂₃H₂₅Cl₂N₃O₆ [ No CAS ]

Reference： [1]Journal of the Chilean Chemical Society,2015,vol. 59,p. 2705 - 2709

32
[ 87-88-7 ]
[ 23978-09-8 ]
C₁₈H₃₆N₂O₆*2C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; at 20℃; for 1h;	General procedure: Two mmol of each donor (20 ml) was added to 20 ml of methanolic solutions containing CLA or PA (2 mmol) and stirred at room temperature for 1 h. Strong change in colors was observed upon mixing solutions of the donors with the acceptors. These changes in colors represent strong evidence of the CT interactions between the donors and the acceptors. The volume of the solution was reduced to one-half by evaporation on a water bath. The resulting solutions were allowed to stand at room temperature.The formed complexes were isolated, filtered off and washed twice thoroughly with the minimum given solvent to obtain the pure products. The complexes were then collected and dried in vacuofor 48 h. The four title complexes were characterized by spectroscopy(UV-vis., IR, Raman and 1H NMR), elemental and thermal analyses.

Reference： [1]Journal of Molecular Structure,2015,vol. 1085,p. 178 - 190

33
[ 87-88-7 ]
[ 31249-95-3 ]
C₁₀H₂₂N₂O₃*2C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; at 20℃; for 1h;	General procedure: Two mmol of each donor (20 ml) was added to 20 ml of methanolic solutions containing CLA or PA (2 mmol) and stirred at room temperature for 1 h. Strong change in colors was observed upon mixing solutions of the donors with the acceptors. These changes in colors represent strong evidence of the CT interactions between the donors and the acceptors. The volume of the solution was reduced to one-half by evaporation on a water bath. The resulting solutions were allowed to stand at room temperature.The formed complexes were isolated, filtered off and washed twice thoroughly with the minimum given solvent to obtain the pure products. The complexes were then collected and dried in vacuofor 48 h. The four title complexes were characterized by spectroscopy(UV-vis., IR, Raman and 1H NMR), elemental and thermal analyses.

Reference： [1]Journal of Molecular Structure,2015,vol. 1085,p. 178 - 190

34
[ 14285-68-8 ]
[ 87-88-7 ]
1,4-bis((2-(thiophen-2-yl)benzimidazol-1-yl)methyl)benzene [ No CAS ]
[(CO)₃Re(μ-CA)(μ-(1,4-bis(2-(2-thiophen-yl)benzimidazol-1-ylmethyl)benzene))Re(CO)₃] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	In 1,3,5-trimethyl-benzene; at 160℃; for 48.0h;High pressure;	General procedure: A mixture <strong>[14285-68-8]Re2(CO)10</strong>, flexible ditopic N-donors L1/L2/L3/L4 and H2-dhnq/H2-CA/H2-THBQ in mesitylene in a Teflon flask was placed in a steel bomb. The bomb was placed in an oven maintained at 160C for 48h and then cooled to 25C. The resulting products were separated by filtration, washed with distilled mesitylene and hexane and air-dried.

Reference： [1]Journal of Organometallic Chemistry,2014,vol. 771,p. 68 - 77

35
[ 14285-68-8 ]
[ 87-88-7 ]
1,4-bis(2-(2-thiophen-yl)benzimidazol-1-ylmethyl)-2,5-dimethoxybenzene [ No CAS ]
[(CO)₃Re(μ-CA)(μ-(1,4-bis(2-(2-thiophen-yl)benzimidazol-1-ylmethyl)-2,5-dimethoxybenzene))Re(CO)₃] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
71%	In 1,3,5-trimethyl-benzene; at 160℃; for 48.0h;High pressure;	General procedure: A mixture <strong>[14285-68-8]Re2(CO)10</strong>, flexible ditopic N-donors L1/L2/L3/L4 and H2-dhnq/H2-CA/H2-THBQ in mesitylene in a Teflon flask was placed in a steel bomb. The bomb was placed in an oven maintained at 160C for 48h and then cooled to 25C. The resulting products were separated by filtration, washed with distilled mesitylene and hexane and air-dried.

Reference： [1]Journal of Organometallic Chemistry,2014,vol. 771,p. 68 - 77

36
[ 14285-68-8 ]
[ 87-88-7 ]
1,4-bis(2-(2-furan-yl)benzimidazol-1-ylmethyl)benzene [ No CAS ]
[(CO)₃Re(μ-CA)(μ-(1,4-bis(2-(2-furan-yl)benzimidazol-1-ylmethyl)benzene))Re(CO)₃] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In 1,3,5-trimethyl-benzene; at 160℃; for 48.0h;High pressure;	General procedure: A mixture <strong>[14285-68-8]Re2(CO)10</strong>, flexible ditopic N-donors L1/L2/L3/L4 and H2-dhnq/H2-CA/H2-THBQ in mesitylene in a Teflon flask was placed in a steel bomb. The bomb was placed in an oven maintained at 160C for 48h and then cooled to 25C. The resulting products were separated by filtration, washed with distilled mesitylene and hexane and air-dried.

Reference： [1]Journal of Organometallic Chemistry,2014,vol. 771,p. 68 - 77

37
[ 14285-68-8 ]
[ 87-88-7 ]
1,4-bis(2-(2-furan-yl)benzimidazol-1-ylmethyl)-2,5-dimethoxybenzene [ No CAS ]
[(CO)₃Re(μ-CA)(μ-(1,4-bis(2-(2-furan-yl)benzimidazol-1-ylmethyl)-2,5-dimethoxybenzene))Re(CO)₃] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	In 1,3,5-trimethyl-benzene; at 160℃; for 48.0h;High pressure;	General procedure: A mixture <strong>[14285-68-8]Re2(CO)10</strong>, flexible ditopic N-donors L1/L2/L3/L4 and H2-dhnq/H2-CA/H2-THBQ in mesitylene in a Teflon flask was placed in a steel bomb. The bomb was placed in an oven maintained at 160C for 48h and then cooled to 25C. The resulting products were separated by filtration, washed with distilled mesitylene and hexane and air-dried.

Reference： [1]Journal of Organometallic Chemistry,2014,vol. 771,p. 68 - 77

38
[ 87-88-7 ]
[ 64485-93-4 ]
C₁₆H₁₆N₅O₇S₂^(1-)*Na⁽¹⁺⁾*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; at 20℃; for 2h;	General procedure: The solid [(CFX)2I]·I3 (I), [(HCFX)(PA)] (II), [(HCFX)(HCA)] (III), [(CFX-H)(HDDQ)] (IV), and [(CFX-H)(HTCNQ)] (V) complexes were prepared by adding a methanolic solution (20.0 mL) of the acceptors (1.00 mmol) to a methanolic solution (10.0 mL) of the donor CFX (1.00 mmol). The resultant dark brown, scarlet yellow, dark violet, dark red and dark green solutions of complexes I-V, respectively, were stirred for about 2 h at room temperature then left overnight to separate the solid complexes. The precipitated complexes were filtrated off, washed with MeOH (3 × 0.5 mL) and dried in vacuo over CaCl2.

Reference： [1]Russian Journal of General Chemistry,2015,vol. 85,p. 731 - 745

39
[ 87-88-7 ]
iron(III) chloride hexahydrate [ No CAS ]
[ 10052-47-8 ]
[ 68-12-2 ]
[ 1310-73-2 ]
C₁₈Cl₆FeO₁₂^(3-)*2Na⁽¹⁺⁾*C₃H₇NO*C₇H₁₈N⁽¹⁺⁾ [ No CAS ]

Reference： [1]Inorganic Chemistry,2015,vol. 54,p. 5410 - 5418

40
[ 87-88-7 ]
[ 630-93-3 ]
[phenytoin sodium][2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone] [ No CAS ]

Reference： [1]Russian Journal of General Chemistry,2015,vol. 85,p. 939 - 950

41
[ 87-88-7 ]
[ 57-24-9 ]
C₂₁H₂₂N₂O₂*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; chloroform at 20℃; for 0.5h;	Preparation of the salts General procedure: A simple synthetic protocol has been used for the preparation ofPT complexes of Sy donor. A typical procedure for the preparation isbriefly described as follows. First, 2 mmol of Sy in chloroform(20 ml) was added to 20 ml of a solution containing 2 mmol of theacceptor (either PA, DNBA or CLA) in the methanol solvent. Theresulting mixture was stirred at room temperature for approximatelyhalf an hour, where the resulting precipitation were isolatedas yellow canary, white and reddish-brown powder for SyePA,SyeDNBA and SyeCLA salts, respectively. The formed productswere isolated, filtered and further purified using methanolchloroformsolvent and a recrystallization process to obtain thepure products. The products were then collected and dried in vacuofor 48 h. The products were characterized by spectroscopy (UVeVis,IR, 1H and 13C NMR) as well as elemental and thermal analyses. Theexcellent agreement between the experimental and calculatedvalues of C, H and N indicates that the obtained products are free ofimpurities. The stoichiometry of the Sy interaction with the acceptorswas found to have a 1:1 ratio.

Reference： [1]Adam, Abdel Majid A.; Refat, Moamen S.; Saad, Hosam A.; Hegab, Mohamed S. [Journal of Molecular Structure, 2015, vol. 1102, p. 170 - 185]

42
[ 87-88-7 ]
[ 186826-86-8 ]
C₆H₂Cl₂O₄*C₂₁H₂₄FN₃O₄*ClH [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; at 20℃; for 0.5h;	General procedure: A simple synthetic protocol was used for the preparationof nanostructured complexes of MOX. A typicalprocedure for the preparation is briefly described asfollows. First, 2 mmol of MOX in a methanol solvent(20 mL) was added to 20 mL of a solution containing2 mmol of the acceptor (either PA, CLA or CHL) in the same solvent. The resulting mixture was stirred at roomtemperature for approximately half an hour. A change incolor occurred, and the solution was allowed to evaporateslowly at room temperature, resulting in the precipitationof the solid complexes. The precipitates were isolated,filtered and further purified using the same system and arecrystallization process to obtain the pure product. Theproducts were then collected and dried in vacuo for 48 h.The excellent agreement between the experimental andcalculated values of C, H and N indicated that thesynthesized nanoparticles were free of impurities. Thestoichiometry of the interaction between the drug MOXand the acceptors was found to have a 1:1 ratio.

Reference： [1]Comptes Rendus Chimie,2015,vol. 18,p. 914 - 928

43
[ 87-88-7 ]
[ 1069-66-5 ]
C₆H₂Cl₂O₄*C₈H₁₅O₂^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; acetone;UV-irradiation;	Method I: aliquots (300-1800muL) of VP stock standard solution (800mug/mL) were transferred into a series of 10-mL volumetric flasks. Volumes were adjusted to 2mL with methanol and 0.6mL of p-CA solution was added. The volume was completed with acetone and the absorbance was measured at 524nm against reagent blank.

Reference： [1]Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,2016,vol. 155,p. 47 - 53

44
[ 87-88-7 ]
[ 1662-01-7 ]
bathophenanthroline [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; dichloromethane at 20℃; for 0.5h;	Preparation of the CT products General procedure: A simple synthetic protocol that was used for the preparation of CTcomplexes of Bath donor is briefly described as follows. First, 2 mmolof Bath donor in a 1:1 MeOH/CH2Cl2 mixture (20 mL) was added to 20 mL of a solution containing 2 mmol of the acceptor (either PA,DNBA or CLA) in the same solvent mixture. The resulting mixture wasstirred at room temperature for approximately 0.5 h, where theresulting precipitation were isolated as shiny yellow, pale yellow, andviolet crystals for Bath-PA, Bath-DNBA, and Bath-CLA products, respectively.The formed products were isolated, filtered, and further purifiedusing solventmixture and a recrystallization process to obtain the pureproducts. The products were then collected and dried in vacuo for 48 h.The products were characterized by spectroscopy (UV-Vis, IR, 1H NMR,and 13C NMR) as well as elemental analysis. The excellent agreementbetween the experimental and calculated values of C, H, and N indicatesthat the obtained productswere free of impurities. The stoichiometry ofthe Bath interaction with the acceptors was found to have a 1:1 ratio.

Reference： [1]Adam, Abdel Majid A.; Refat, Moamen S. [Journal of Molecular Liquids, 2016, vol. 219, p. 377 - 389]

45
[ 578-68-7 ]
[ 87-88-7 ]
C₉H₈N₂*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol;	The solid complex of 4AQ with CLA was synthesized by mixing of 5 ml saturated solutions of both 4AQ (0.144 g, 1 mmol) and CLA (0.209 g, 1 mmol) in methanol. A pink color solution was obtainedupon mixing that changed to pink precipitate. The precipitate was filtered off and washed several times with little portions of methanol to remove the free donor and acceptor molecules. The precipitate was dried under vacuum over CaCl2. The complex thus obtained was characterized by elemental analysis (theoretical values are shown in parenthesis): [(donor) (acceptor)], (C15H10N2O4Cl2)HBCT complex (M/W: 353.18 g): C, 50.81 (50.97); H, 2.43 (2.83);N, 7.38 (7.93).

Reference： [1]Journal of Molecular Liquids,2016,vol. 220,p. 166 - 182

46
[ 582-60-5 ]
[ 87-88-7 ]
C₉H₁₀N₂*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol at 20℃; for 7h;	2.2. Synthesis of solid CT complex The novel CT complex of DMBI with ChA was synthesized by mixing saturated solution of DMBI (0.731 g, 5mmol) in methanol with saturated solution of ChA (1.045 g, 5 mmol) in methanol. Purple colored solution formed upon mixing. The solution mixture was stirred continuously for7 h and left standing overnight at room temperature. Purple colored fibers of CT complex were formed in solution. The fibers were filtered off, washed several times with small amounts of methanol and dried over anhydrous calcium chloride. The solubility of CT complex differs as compared to reactants. The results of elemental analysis of CT complex with theoretical values (in bracket) are: C15H12N2O4Cl2 (M.W. 355.17 g,m.p.=252 °C): C, 50.73% (51.13%): H, 3.40% (3.54%): N, 15.77% (15.98%).

Reference： [1]Singh, Neelam; Khan, Ishaat M.; Ahmad, Afaq; Javed, Saleem [Journal of Molecular Liquids, 2016, vol. 221, p. 1111 - 1120]

47
[ 61-90-5 ]
[ 87-88-7 ]
C₆H₁₃NO₂*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	In water; acetone at 50℃;	2. Experimental L-leucine, D-leucine and chloranilic acid were obtained from theAldrich Chemical Co. They were used in syntheses of the complexeswithout any further treatments. The title materials were synthesizedby reacting L-leucine and D-leucine with chloranilic acid takenin equimolar ratio. The given amounts of L-leucine and D-leucinewere first dissolved in double distilled water. To these solutionsequimolar amounts of chloranilic acid dissolved in acetone wereadded by simultaneous slow instilling of their solutions. Theresulting solutions were stirred well for about 2e3 h at 50 C untilhomogeneous solutions were formed. The solutions were filteredoff and kept undisturbed at ambient temperature. After few weekscrystalline materials were collected and recrystallized usingmixture of double distilled water and ethanol (1:4 mixtures) toimprove the purity of the material since high quality crystal arerequired. L-leucine e chloranilic acid: dark brown crystal, mp.219.0 C (decomp.) fromwater e ethanol (1:4) mixture, Yield: 83%,Anal. Calc. for C12H15Cl2NO6 (340.16): C, 42.33; H, 4.41; N, 4.12;Found: C, 42.34, H, 4.61, N, 4.02%.

Reference： [1]Pawlukojć; Hetmańczyk; Nowicka-Scheibe; Maurin, Jan K.; Schilf; Rozwadowski [Journal of Molecular Structure, 2017, vol. 1133, p. 464 - 471]

48
[ 328-38-1 ]
[ 87-88-7 ]
C₆H₁₃NO₂*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	In water; acetone at 50℃;	2. Experimental General procedure: L-leucine, D-leucine and chloranilic acid were obtained from theAldrich Chemical Co. They were used in syntheses of the complexeswithout any further treatments. The title materials were synthesizedby reacting L-leucine and D-leucine with chloranilic acid takenin equimolar ratio. The given amounts of L-leucine and D-leucinewere first dissolved in double distilled water. To these solutionsequimolar amounts of chloranilic acid dissolved in acetone wereadded by simultaneous slow instilling of their solutions. Theresulting solutions were stirred well for about 2e3 h at 50 C untilhomogeneous solutions were formed. The solutions were filteredoff and kept undisturbed at ambient temperature. After few weekscrystalline materials were collected and recrystallized usingmixture of double distilled water and ethanol (1:4 mixtures) toimprove the purity of the material since high quality crystal arerequired. D-leucine e chloranilic acid: darkbrown crystal, mp. 219.0 C (decomp.) from water e ethanol (1:4)mixture, Yield: 83%, Anal. Calc. for C12H15Cl2NO6 (340.16): C, 42.33;H, 4.41; N, 4.12; Found: C, 42.38, H, 4.57, N, 4.08%.

Reference： [1]Pawlukojć; Hetmańczyk; Nowicka-Scheibe; Maurin, Jan K.; Schilf; Rozwadowski [Journal of Molecular Structure, 2017, vol. 1133, p. 464 - 471]

49
[ 87-88-7 ]
[ 123373-51-3 ]
C₁₀H₈N₄*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol	The solid HBCT complex of DAQC with CAwas synthesized by mixing of 5 ml saturated solutions of bothDAQC (0.184 g, 1 mmol) and CA (0.209 g, 1 mmol) in methanol. Apink color solution was obtained upon mixing that changed to pinkprecipitate. The precipitate was filtered off and washed severaltimes with little portions of methanol to remove the free donor andacceptor molecules. The precipitate was dried under vacuum overCaCl2. The complex thus obtained was characterized by elementalanalyses (theoretical values are shown in parenthesis): [(donor)(acceptor)], (C15H10N2O4Cl2) HBCT complex (M/W: 353.18 g): C,48.44 (48.85); H, 2.14 (2.54); N, 13.98 (14.25).

Reference： [1]Al-Ahmary, Khairia M.; Soliman, Saied M.; Mekheimer, Ramadan Ahmed; Habeeb, Moustafa M.; Alenezi, Maha S. [Journal of Molecular Liquids, 2017, vol. 231, p. 602 - 619]

50
[ 87-88-7 ]
[ 6156-78-1 ]
[ 16858-01-8 ]
C₃₀H₁₈Cl₄MnN₄O₈^(2-)*CH₄O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
38%		A solution of Mn(O2CMe)24H2O (64.0 mg; 0.262 mmol) dissolvedin 15 mL of methanol was added to a solution of TPyA(100 mg, 0.344 mmol) dissolved in 7 mL of methanol in a 100 mLround bottom flask. To the resulting pale-pink solution was addedof chloranilic acid (36.0 mg; 0.172 mmol) dissolved in 10 mL ofmethanol resulting in a dark purple solution and formation of adark precipitate. To the mixture was added 0.05 mL (0.344 mmol)triethylamine and was then refluxed for 30 min. After filtrationwhile hot, the dark purple solution was allowed to stand for 3 daysupon which dark red crystals formed. The crystals were collectedand washed with 5 mL of methanol and allowed to dry in air(Yield: 79 mg, 38%). Key IR (cm-1; KBr): 1604 m, 1557 s, 1494 s,1434 m, 1377 m, 1356 m, 1017 m, 992 m, 865 m, 840 m, 765 m,578 m.

Reference： [1]Polyhedron,2018,vol. 139,p. 215 - 221

51
[ 87-88-7 ]
[ 14667-55-1 ]
C₇H₁₀N₂*C₆H₂Cl₂O₄ [ No CAS ]

Reference： [1]CrystEngComm,2018,vol. 20,p. 2016 - 2028

52
[ 87-88-7 ]
C₃₄H₄₉Cl₄Ir₃N₄ [ No CAS ]
[ 2923-28-6 ]
C₇₂H₉₈Ir₆N₈O₈⁽⁴⁺⁾*4CF₃O₃S^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
86%	Stage #1: C₃₄H₄₉Cl₄Ir₃N₄; silver trifluoromethanesulfonate In methanol at 20℃; for 3h; Darkness; Stage #2: 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone With sodium methylate In methanol for 12h;

Reference： [1]Dang, Li-Long; Lin, Yue-Jian; Jin, Guo-Xin [Dalton Transactions, 2018, vol. 47, # 18, p. 6378 - 6385]

53
[ 87-88-7 ]
[ 59-43-8 ]
C₁₂H₁₇N₄OS⁽¹⁺⁾*Cl^(1-)*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80.1%	In methanol; at 25℃; for 1h;	Solid [(HVB1)(HCA)] complexwas prepared by adding a saturated solution ofchloranilic acid (106.0 mg, 0.51 mmol) in MeOH (30 mL)to a concentrated solution of <strong>[59-43-8]thiamine hydrochloride</strong>(168.6 mg, 0.50 mmol) in MeOH (10 mL) and stirring for 1 h. The formed violet precipitate was filtered off,washed with the least amount (3×0.5 mL) of MeOHand dried under vacuum over CaCl2. Yield 80.1%. Found, %: C 42.33; H 3.85; Cl 20.73; N 10.87; S 6.26.C18H19Cl3N4O5S. Calculated, %: C 42.41; H 3.76; Cl20.86; N 10.99; S 6.29.

Reference： [1]Russian Journal of General Chemistry,2018,vol. 88,p. 797 - 803
Zh. Obshch. Khim.,2018,vol. 88,p. 797 - 803,7

54
[ 87-88-7 ]
[ 35100-92-6 ]
C₆H₂Cl₂O₄*C₅H₉N₃ [ No CAS ]

Reference： [1]Journal of Molecular Structure,2019,vol. 1181,p. 48 - 60

55
[ 87-88-7 ]
[ 357-57-3 ]
C₂₃H₂₆N₂O₄⁽¹⁺⁾*C₆H₂Cl₂O₄^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile at 25℃; for 2h;	2.2. Synthesis of Bru-CT complexes General procedure: Bru-ChA, Bru-DDQ and Bru-TCNQ complexes of reddish and violetcolors were prepared by mixing 1 mmol (1.1 g) of Bru with 1 mmol acceptorcorresponding to 0.21 g, 0.23 or 0.21 g of ChA, DDQ and TCNQ respectively,in 25 ml of acetonitrile. The compositions of CT wereobtained with ChA or DDQ at 25 °C for 2 h while with TCNQ was obtainedat 70 °C. The products were then filtered, washed with a lowervolume of acetonitrile and dried under vacuum with anhydrous CaCl2.The melting points of Bru-ChA, Bru-DDQ and Bru-TCNQ were 240 °C,194 °C and 204 °C, respectively and that of Bruwas 185 °C. The resultingcomplexes were investigated by FTIR, NMR and MS spectrometry.

Reference： [1]AlRabiah, Haitham; Abdel-Aziz, Hatem A.; Mostafa, Gamal A.E. [Journal of Molecular Liquids, 2019, vol. 286]

56
[ 57-44-3 ]
[ 87-88-7 ]
C₈H₁₂N₂O₃*C₆H₂Cl₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol at 60℃; for 0.75h;	2.2. CT product synthesis General procedure: The CT products obtained fromthe reaction of Barwith the acceptorsCLA (Product 1), CHL (Product 2), TCNQ (Product 3), and DBQ (Product4) were prepared by heating 25-mL solutions containing 2 mmol of theacceptor inmethanol solvent for 15 min at 60 °C. Then, this solutionwasadded slowly to a magnetically stirred 25-mL solution that contained2mmol of Bar also dissolved inmethanol solvent. The magnetic stirringwas run continuously for 45min. After that, awater bathwas employedto reduce the solution volume by one-half, and then the solution wasleft standing for 24 h at roomtemperature to precipitate the final product.All the precipitates were isolated, filtered off, rinsed well with thesame solvent, and vacuumdried using CaCl2 (anhydrous) for 60 h. Product1, Product 2, Product 3, and Product 4 are colored light reddishorange,light yellow, light green, and dark red, respectively. The CTproducts were characterized spectroscopically (IR, Raman and 1HNMR), thermally, and by elemental analysis.

Reference： [1]Al-Saif, Foziah A.; El-Habeeb, Abeer A.; Refat, Moamen S.; Adam, Abdel Majid A.; Saad, Hosam A.; El-Shenawy, Ahmed I.; Fetooh, Hammad [Journal of Molecular Liquids, 2019, vol. 287]

57
lanthanum(III) nitrate hexahydrate [ No CAS ]
[ 87-88-7 ]
[ 56-34-8 ]
[ 7732-18-5 ]
(tetraethylammonium)[La(chloranilate)2(H₂O)] [ No CAS ]