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Chemical Structure| 932-94-5 Chemical Structure| 932-94-5

Structure of 932-94-5

Chemical Structure| 932-94-5

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Product Details of [ 932-94-5 ]

CAS No. :932-94-5
Formula : C6H6O2S
M.W : 142.17
SMILES Code : O=CC1=CC=C(SC)O1
MDL No. :MFCD18378742

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Application In Synthesis of [ 932-94-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 932-94-5 ]

[ 932-94-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 13529-27-6 ]
  • [ 624-92-0 ]
  • [ 932-94-5 ]
YieldReaction ConditionsOperation in experiment
94% 5-(Methylthio)furan-2-carbaldehyde. To a solution of <strong>[13529-27-6]2-(diethoxymethyl)furan</strong> (2.00 g, 11.75 mmol) in dry THF (8 mL) was added a solution of n-BuLi (1.6 M in Hexane) (8.80 mL, 14.1 mmol) at -78 C. The resulting mixture was stirred at -78 C. for 1 h and treated with methyldisulfide (1.06 mL, 11.75 mmol). The reaction mixture was stirred at -78 C. for 30 min followed by warming to 0 C. for 1 hour. HCl (1N) (20 mL) was added and the organic material was extracted with ether (2×50 mL). The combined organic fractions were dried (MgSO4) and concentrated in vacuo to afford 1. 58 g (94%) of crude title compound. LCMS (+ESI, M+H+) m/z 143.
 

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