Home Cart 0 Sign in  

[ CAS No. 935-14-8 ]

{[proInfo.proName]} ,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 935-14-8
Chemical Structure| 935-14-8
Structure of 935-14-8 * Storage: {[proInfo.prStorage]}

Quality Control of [ 935-14-8 ]

Related Doc. of [ 935-14-8 ]

SDS
Alternatived Products of [ 935-14-8 ]
Alternatived Products of [ 935-14-8 ]

Product Details of [ 935-14-8 ]

CAS No. :935-14-8 MDL No. :MFCD00078375
Formula : C10H6 Boiling Point : 182.8°C at 760 mmHg
Linear Structure Formula :- InChI Key :N/A
M.W :126.15 g/mol Pubchem ID :120463
Synonyms :

Safety of [ 935-14-8 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P280 UN#:N/A
Hazard Statements:H317 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 935-14-8 ]

  • Upstream synthesis route of [ 935-14-8 ]
  • Downstream synthetic route of [ 935-14-8 ]

[ 935-14-8 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 935-14-8 ]
  • [ 3032-92-6 ]
YieldReaction ConditionsOperation in experiment
67% With silver(I) nitrite; trichloroisocyanuric acid In acetonitrile at 20℃; for 8 h; Sealed tube 4-ethynylphenylacetylene 63 mg (0.50 mmol), silver nitrite 154 mg (1 mmol), trichloroisocyanuric acid 232.4 mg (1 mmol)Add 10 mL of pressure-resistant sealed container in turn, and then add 5 mL of acetonitrile.The mixture was stirred at room temperature, and the reaction was checked by TLC. The reaction was completed in 8 hours.The reaction solution was diluted with 10 mL of dichloromethane, and filtered to give a clear liquid.Separation by column chromatography (with petroleum ether / ethyl acetate volume ratio of 100:1 as eluent)The eluate containing the desired product were collected and the solvent was evaporated to give a white solid 4-ethynyl-benzonitrile 42.5mg (67percent yield).
Reference: [1] Patent: CN107641088, 2018, A, . Location in patent: Paragraph 0060; 0061; 0062
Historical Records

Related Functional Groups of
[ 935-14-8 ]

Alkynyls

Chemical Structure| 29079-00-3

[ 29079-00-3 ]

4-Ethynyl-1,1'-biphenyl

Similarity: 0.88

Chemical Structure| 501-65-5

[ 501-65-5 ]

Diphenylacetylene

Similarity: 0.88

Chemical Structure| 673-32-5

[ 673-32-5 ]

Prop-1-yn-1-ylbenzene

Similarity: 0.88

Chemical Structure| 2949-26-0

[ 2949-26-0 ]

2-Ethynyl-naphthalene

Similarity: 0.84

Chemical Structure| 23152-99-0

[ 23152-99-0 ]

1-Ethynyl-4-isopropylbenzene

Similarity: 0.81

Aryls

Chemical Structure| 29079-00-3

[ 29079-00-3 ]

4-Ethynyl-1,1'-biphenyl

Similarity: 0.88

Chemical Structure| 501-65-5

[ 501-65-5 ]

Diphenylacetylene

Similarity: 0.88

Chemical Structure| 673-32-5

[ 673-32-5 ]

Prop-1-yn-1-ylbenzene

Similarity: 0.88

Chemical Structure| 2949-26-0

[ 2949-26-0 ]

2-Ethynyl-naphthalene

Similarity: 0.84

Chemical Structure| 23152-99-0

[ 23152-99-0 ]

1-Ethynyl-4-isopropylbenzene

Similarity: 0.81