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Chemical Structure| 945400-88-4 Chemical Structure| 945400-88-4

Structure of 945400-88-4

Chemical Structure| 945400-88-4

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Product Details of [ 945400-88-4 ]

CAS No. :945400-88-4
Formula : C12H13BrN2O2S
M.W : 329.21
SMILES Code : O=C(OC(C)(C)C)NC1=CC=C2N=C(Br)SC2=C1

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Application In Synthesis of [ 945400-88-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 945400-88-4 ]

[ 945400-88-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 22514-58-5 ]
  • [ 75-65-0 ]
  • [ 945400-88-4 ]
YieldReaction ConditionsOperation in experiment
With diphenylphosphoranyl azide; triethylamine; at 80℃; for 4.0h; Triethylamine (1.94 mL, 13.9 mmol) and diphenylphosphoryl azide (2.76 niL, 12.8 mmol) were added to a solution of 2-bromo-l,3-benzothiazole-6-carboxylic acid (3.0 g, 11.6 mmol) in tert-butanol (100 mL) and the reaction mixture was stirred at 80 0C for 4 h. The solvent was evaporated under reduced pressure and the residue was subjected to flash chromatography (Heptane/EtOAc gradient) to give tert-butyl (2-bromo-l,3-benzothiazol- 6-yl)carbamate (1.1 g) as a white solid. MS m/z (M+H) 329, 331.
 

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