Home Cart Sign in  
Chemical Structure| 951-87-1 Chemical Structure| 951-87-1

Structure of 951-87-1

Chemical Structure| 951-87-1

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Product Citations

Kaur, Gurkiran ; Dominique, Nathaniel L. ; Hu, Gaohe ; Nalaoh, Phattananawee ; Thimes, Rebekah L. ; Strausser, Shelby L. , et al.

Abstract: Controlling the chirality of mol.-surface systems is essential for applications ranging from heterogeneous catalysis to biosensing. N-heterocyclic carbenes (NHCs) are quickly becoming a dominant ligand for noble metal surface passivation, but the potential of chiral NHC scaffolds remains untapped. In this work, two stereoisomers, one C2 sym. and one Cs sym., of saturated N-heterocyclic carbenes (NHCs) and a structurally related unsaturated NHC (C2v sym.) were synthesized as NHC-CO2 adducts. These CO2-protected NHCs were deposited on gold films and their presence on the films was confirmed by laser desorption ionization mass spectrometry (LDI-MS) and surface enhanced Raman spectroscopy (SERS). Surprisingly, the Cs NHC, but not the chiral C2 NHC, partially degrades to the independently synthesized unsaturated NHC upon binding to the gold. Theor. calculations assist in explaining this phenomenon by showing that the NHCs primarily lie flat on the gold surfaces, which exposes the backbone protons on the Cs-sym. NHC to a formal elimination of H2, while the C2-sym. NHC remains protected from this elimination reaction. These results raise critical questions as to how the structure of NHC ligands may be tuned to influence binding and reactivity on gold surfaces.

Purchased from AmBeed: ;

Alternative Products

Product Details of [ 951-87-1 ]

CAS No. :951-87-1
Formula : C14H16N2
M.W : 212.29
SMILES Code : N[C@H](C1=CC=CC=C1)[C@H](C2=CC=CC=C2)N
MDL No. :MFCD00274328
InChI Key :PONXTPCRRASWKW-OKILXGFUSA-N
Pubchem ID :6931234

Safety of [ 951-87-1 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 951-87-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 951-87-1 ]

[ 951-87-1 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 951-87-1 ]
  • [ 145689-41-4 ]
  • N-((1R,2S)-2-Amino-1,2-diphenyl-ethyl)-2-(2,3-difluoro-phenyl)-acetamide [ No CAS ]
 

Historical Records

Technical Information

Categories

Related Functional Groups of
[ 951-87-1 ]

Aryls

Chemical Structure| 124842-96-2

A805703 [124842-96-2]

1,2-Di-p-tolylethylenediamine

Similarity: 1.00

Chemical Structure| 30339-30-1

A104667 [30339-30-1]

(S)-1-Phenyl-2-(p-tolyl)ethanamine

Similarity: 0.93

Chemical Structure| 5700-56-1

A570631 [5700-56-1]

1-Phenylethane-1,2-diamine

Similarity: 0.93

Chemical Structure| 30275-30-0

A276243 [30275-30-0]

1-Phenyl-2-(p-tolyl)ethanamine

Similarity: 0.93

Chemical Structure| 69810-77-1

A597190 [69810-77-1]

1-(m-Tolyl)ethane-1,2-diamine

Similarity: 0.93

Amines

Chemical Structure| 124842-96-2

A805703 [124842-96-2]

1,2-Di-p-tolylethylenediamine

Similarity: 1.00

Chemical Structure| 30339-30-1

A104667 [30339-30-1]

(S)-1-Phenyl-2-(p-tolyl)ethanamine

Similarity: 0.93

Chemical Structure| 5700-56-1

A570631 [5700-56-1]

1-Phenylethane-1,2-diamine

Similarity: 0.93

Chemical Structure| 30275-30-0

A276243 [30275-30-0]

1-Phenyl-2-(p-tolyl)ethanamine

Similarity: 0.93

Chemical Structure| 69810-77-1

A597190 [69810-77-1]

1-(m-Tolyl)ethane-1,2-diamine

Similarity: 0.93