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[ CAS No. 97614-42-1 ] {[proInfo.proName]}

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Cat. No.: {[proInfo.prAm]}
Chemical Structure| 97614-42-1
Chemical Structure| 97614-42-1
Structure of 97614-42-1 * Storage: {[proInfo.prStorage]}
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Product Details of [ 97614-42-1 ]

CAS No. :97614-42-1 MDL No. :MFCD07367507
Formula : C29H24N2O10S Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 592.57 Pubchem ID :-
Synonyms :

Safety of [ 97614-42-1 ]

Signal Word: Class:N/A
Precautionary Statements: UN#:N/A
Hazard Statements: Packing Group:N/A

Application In Synthesis of [ 97614-42-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 97614-42-1 ]
  • Downstream synthetic route of [ 97614-42-1 ]

[ 97614-42-1 ] Synthesis Path-Upstream   1~3

  • 1
  • [ 97614-42-1 ]
  • [ 97614-43-2 ]
YieldReaction ConditionsOperation in experiment
66.4% With triethylamine tris(hydrogen fluoride) In ethyl acetate at 60 - 70℃; for 4.5 h; The synthesis of compound viii: The compound vii (2.2mmol) was dissolved in ethyl acetate (54ml), and Et3N .bul. 3HF (2.08ml, 0.013mmol) was added while stirring the solution. The solution was heated up to 60°C, stirred for 3h, and then heated to 70 °C and stirred for 1.5h. The solution was added with ice-salt (10 ml) to terminate the reaction, and extracted with dichloromethane. The organic layers were combined and then washed sequentially with saline, water and saturated sodium bicarbonate, and dried over anhydrous sodium sulfate for over 4 hours. The solvent was drawn off under a reduced pressure to obtain dark yellow syrup. The syrup was purified (dichloromethane elution) by means of a silica gel funnel (5cm .x. 5cm) to yield light yellow syrup(86.8percent). Finally the crude product was crystallized in 95percent ethanol solution to obtain the white compound viii crystalline (66.4percent). 1H NMR(CDCl3) δppm: 7.31.similar.8.10 (m, 15H, OBz), 6.71 (d, J=9.0Hz, 1H, H-1), 5.68 (dd, J=19.44Hz, 1H, H-3), 5.32 (d, J=48.2Hz, 1H, H-2), 4.65.similar.4.77 (m, 3H, H-4, H-5). M.p.80.similar.82°C.
Reference: [1] Patent: EP2177527, 2010, A1, . Location in patent: Page/Page column 11-12
[2] Journal of Labelled Compounds and Radiopharmaceuticals, 1999, vol. 42, # SUPPL. 1, p. S638-S640
[3] Tetrahedron Letters, 1996, vol. 37, # 1, p. 17 - 20
  • 2
  • [ 97614-42-1 ]
  • [ 97614-43-2 ]
  • [ 97614-50-1 ]
Reference: [1] Journal of Organic Chemistry, 1985, vol. 50, # 19, p. 3644 - 3647
  • 3
  • [ 107-21-1 ]
  • [ 97614-42-1 ]
  • [ 38491-60-0 ]
  • [ 97614-43-2 ]
  • [ 97614-49-8 ]
Reference: [1] Journal of Organic Chemistry, 1985, vol. 50, # 19, p. 3644 - 3647
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