Alternatived Products of [ 983-79-9 ]
Product Details of [ 983-79-9 ]
CAS No. : | 983-79-9 |
MDL No. : | |
Formula : |
C26H20N2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
360.45
|
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 983-79-9 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 983-79-9 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 983-79-9 ]
- Downstream synthetic route of [ 983-79-9 ]
- 1
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[ 14066-73-0 ]
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[ 110-21-4 ]
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[ 16240-68-9 ]
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[ 1111-78-0 ]
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[ 983-79-9 ]
- 2
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[ 273-77-8 ]
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[ 908093-98-1 ]
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[ 119-61-9 ]
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[ 35500-04-0 ]
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[ 632-50-8 ]
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[ 79249-48-2 ]
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[ 79249-49-3 ]
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[ 983-79-9 ]
- 3
-
[ 115975-19-4 ]
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[ 612-59-9 ]
-
[ 119-61-9 ]
-
[ 67-72-1 ]
-
[ 983-79-9 ]
- 4
-
[ 120569-14-4 ]
-
[ 1532-91-8 ]
-
[ 119-61-9 ]
-
[ 67-72-1 ]
-
[ 983-79-9 ]
- 5
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[ 530-48-3 ]
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[ 908093-98-1 ]
-
[ 1499-10-1 ]
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[ 1053-23-2 ]
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[ 602-15-3 ]
-
[ 4960-55-8 ]
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[ 983-79-9 ]
-
[ 632-51-9 ]
- 6
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[ 908093-98-1 ]
-
[ 1708-40-3 ]
-
[ 81712-48-3 ]
-
[ 983-79-9 ]
- 7
-
[ 107264-18-6 ]
-
[ 71-43-2 ]
-
[ 119-61-9 ]
-
[ 827-52-1 ]
-
[ 983-79-9 ]
- 8
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[ 100-42-5 ]
-
[ 908093-98-1 ]
-
[ 896-65-1 ]
-
[ 983-79-9 ]
Yield | Reaction Conditions | Operation in experiment |
1: 68%
2: 30% |
In toluene at 20℃; for 26h; |
2; 4
To a solution of [Me2NN]Cu (ethylene) (0.015g, 0.038 mmol) and styrene (0.780 g, 7.50 mmol) in 10 mL toluene, a solution of N2CPh2 (0.165 g, 0.757 mmol) in 9 mL of toluene was added by syringe pump at room temperature over a period of 20 h. After stirring at RT for another 6 h, naphthalene (0.112 g) was added as an internal standard and an aliquot of the resulting solution was passed through silica gel and analyzed by GC-MS to give a 68% yield of 1,1,2-triphenylcyclopropane along with the azine Ph2C=N-N=CPh2 in ca. 30% yield. |
1: 68 % Chromat.
2: 30 % Chromat. |
With [Me2NN]Cu(ethylene) In toluene at 20℃; for 26h; |
|
- 9
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[ 100-42-5 ]
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[ 908093-98-1 ]
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[ 896-65-1 ]
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[ 101-81-5 ]
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[ 983-79-9 ]
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[ 632-51-9 ]
Yield | Reaction Conditions | Operation in experiment |
|
In toluene at 20℃; for 20h; |
30
Catalytic cyclopropanation of styrene by 9. To a solution of [Me2NN]Co(toluene) (0.014g, 0.031 mmol) and styrene (0.625 g, 6.01 mmol) in 10 mL toluene, a solution of N2CPh2 (0.132 g, 0.606 mmol) in 8 mL of toluene was added by syringe pump at room temperature over a period of 14 h. After stirring at RT for another 6 h, the resulting solution was passed through silica gel and analyzed by GC-MS to give a mixture of Ph2CH2, 1,1,2-triphenylcyclopropane along, tetraphenylethylene and Ph2C=N-N=CPh2 with an approximate ratio of 1 : 2 : 2 : 5. |
- 10
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[ 501-65-5 ]
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[ 983-79-9 ]
-
[ 30081-56-2 ]
Yield | Reaction Conditions | Operation in experiment |
93% |
With carbonyl(pentamethylcyclopentadienyl)cobalt diiodide; sodium acetate In 2,2,2-trifluoroethanol at 110℃; for 12h; Sealed tube; Inert atmosphere; |
|
91% |
With [(eta.(5)-pentamethylcyclopentadienyl)Rh(H2O)3](OTf)2; benzoic acid In methanol at 25℃; for 24h; |
|
91% |
With Cp*Rh(H2O)3(OTf)2; benzoic acid In methanol at 25℃; for 24h; |
70 Example 70, 1-phenyl-3,4-diphenyl-isoquinoline 4la
The phenylhydrazone 4l (0.3mmol), 1,2-diphenylacetylene 2a (0.5mmol), Cp*Rh (H2O)3(OTf)2(0.01mmol), benzoic acid (0.125mmol), by adding 4.0 ml methanol, the air lower, 25oC reaction 24 hours after cessation of the reaction, pure product of column chromatography to obtain 1-phenyl-3,4-diphenyl-isoquinoline 4la. The product is white solid, yield 91%. |
90% |
With potassium hexafluorophosphate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 at 150℃; for 0.166667h; Microwave irradiation; |
|
Reference:
[1]Deshmukh, Dewal S.; Yadav, Prashant A.; Bhanage, Bhalchandra M.
[Organic and Biomolecular Chemistry, 2019, vol. 17, # 14, p. 3489 - 3496]
[2]Han, Wenjia; Zhang, Guoying; Li, Guangxing; Huang, Hanmin
[Organic Letters, 2014, vol. 16, # 13, p. 3532 - 3535]
[3]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN105218426, 2016, A
Location in patent: Paragraph 0090; 0091
[4]Deshmukh, Dewal S.; Gangwar, Neha; Bhanage, Bhalchandra M.
[European Journal of Organic Chemistry, 2019, vol. 2019, # 18, p. 2919 - 2927]