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Chemical Structure| 33454-82-9 Chemical Structure| 33454-82-9
Chemical Structure| 33454-82-9

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Synonyms: Triflate lithium; Trifluoromethylsulfonate lithium; Trifluoromethanesulphonic acid lithium

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Product Citations

Product Citations

Chaminda P. Nawarathne ; Abdul Hoque ; Abdul Hoque ; Chethani K. Ruhunage ; Connor E. Rahm ; Noe T. Alvarez

Abstract: The exceptional physical properties of carbon nanotubes (CNTs) have the potential to transform materials science and various industrial applications. However, to exploit their unique properties in carbon-based electronics, CNTs regularly need to be chemically interfaced with metals. Although CNTs can be directly synthesized on metal substrates, this process typically requires temperatures above 350 °C, which is not compatible for many applications. Additionally, the CNTs employed here were highly densified, making them suitable as interconnecting materials for electronic applications. This paper reports a method for the chemical bonding of vertically aligned CNTs onto metal substrates that avoids the need for high temperatures and can be performed at temperatures as low as 80 °C. Open-ended CNTs were directly bonded onto Cu and Pt substrates that had been functionalized using diazonium radical reactive species, thus allowing bond formation with the open-ended CNTs. Careful control during grafting of the organic species onto the metal substrates resulted in functional group uniformity, as demonstrated by FT-IR analysis. Scanning electron microscopy images confirmed the formation of direct connections between the vertically aligned CNTs and the metal substrates. Furthermore, electrochemical characterization and application as a sensor revealed the nature of the bonding between the CNTs and the metal substrates.

Keywords: carbon nanotubes ; metal–carbon interface ; bond formation

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Product Details of Trifluoromethanesulfonate lithium

CAS No. :33454-82-9
Formula : CF3LiO3S
M.W : 156.01
SMILES Code : O=S(C(F)(F)F)([O-])=O.[Li+]
Synonyms :
Triflate lithium; Trifluoromethylsulfonate lithium; Trifluoromethanesulphonic acid lithium
MDL No. :MFCD00013227
InChI Key :MCVFFRWZNYZUIJ-UHFFFAOYSA-M
Pubchem ID :3664839

Safety of Trifluoromethanesulfonate lithium

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302
Precautionary Statements:P280-P305+P351+P338

Application In Synthesis of Trifluoromethanesulfonate lithium

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Upstream synthesis route of [ 33454-82-9 ]
  • Downstream synthetic route of [ 33454-82-9 ]

[ 33454-82-9 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 108-75-8 ]
  • [ 33454-82-9 ]
  • [ 107264-00-6 ]
References: [1] Tetrahedron, 1993, vol. 49, # 11, p. 2151 - 2158.
 

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