Products Cited in Publications Worldwide Cobalt-driven selective hydrogermylation of terminal and internal alkynes

Cobalt-driven selective hydrogermylation of terminal and internal alkynes

Broniarz, Konstancja; Lewandowski, Dariusz; Hreczycho, Grzegorz

DOI:

Abstract

A highly selective cobalt-catalyzed hydrogermylation of alkynes has been developed using complexes with inexpensive and readily accessible triazine-based PNP ligands. This method enables the selective synthesis of (E)-β-vinylgermanes from terminal alkynes, which is compatible with both alkyl- and aryl-substituted acetylenes and the selective synthesis of (Z)-α-isomers from internal alkynes. The process is characterized by exceptional selectivity, resulting in high yields.

Keywords

Alkynes ; Hydrogermylation ; Cobalt ; Hydrogermanes

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