Home Cart Sign in  
Chemical Structure| 102336-07-2 Chemical Structure| 102336-07-2

Structure of 102336-07-2

Chemical Structure| 102336-07-2

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 102336-07-2 ]

CAS No. :102336-07-2
Formula : C9H11NO3
M.W : 181.19
SMILES Code : O=C(O)CCC1=CC(OC)=NC=C1
MDL No. :MFCD10698168

Safety of [ 102336-07-2 ]

Application In Synthesis of [ 102336-07-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 102336-07-2 ]

[ 102336-07-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 102336-07-2 ]
  • [ 1401462-03-0 ]
YieldReaction ConditionsOperation in experiment
50% Step 3 2-(2-Methoxypyridin-4-yl)ethanamine hydrochloride Procedure: 3-(2-Methoxypyridin-4-yl)propanoic acid (2.5 g, 18.3 mmol) was added to concentrated H2SO4 (10 ml) and stirred at 70 C. When the solution became clear, sodium azide (1.8 g, 27.6 mmol) was slowly added over a period of 2 hours. The mixture was stirred for 2 hours at 70 C. and then for 16 hours at room temperature, and then poured onto ice. The solution was basified with sat. NaHCO3 and extracted with DCM (3*100 mL). The combined organic layers were dried over anhydrous Na2SO4, and evaporated under reduced pressure. The oily residue was dissolved in anhydrous EtOH and HCl in dioxane was added to the solution. The solvent was evaporated under reduce pressure to give 2-(2-methoxypyridin-4-yl)ethanamine hydrochloride (1.3 g, 50%) as a yellow solid. LC-MS: 153 [M+H]+, tR=0.36 min.
 

Historical Records

Technical Information

Categories