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Chemical Structure| 1025719-26-9 Chemical Structure| 1025719-26-9

Structure of 1025719-26-9

Chemical Structure| 1025719-26-9

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Product Details of [ 1025719-26-9 ]

CAS No. :1025719-26-9
Formula : C18H29BO2
M.W : 288.24
SMILES Code : CC1(C(C)(OB(O1)C2=CC(C(C)C)=CC(C(C)C)=C2)C)C
MDL No. :MFCD12405517

Safety of [ 1025719-26-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 1025719-26-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1025719-26-9 ]

[ 1025719-26-9 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 23058-81-3 ]
  • [ 73183-34-3 ]
  • [ 1025719-26-9 ]
YieldReaction ConditionsOperation in experiment
86% With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate; In 1,4-dioxane; at 85℃; for 12h;Inert atmosphere; A mixture <strong>[23058-81-3]1-bromo-3,5-bis(propan-2-yl)benzene</strong> (2.41 g, 9.99 mmol, 1.00 equiv), 4,4,5,5-tetramethyl-2-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,2-dioxaborolane (3.05 g, 12.01 mmol, 1.20 equiv), potassium acetate (2.94 g, 30.00 mmol, 3.00 equiv) and PdCl2(dppf).CH2Cl2 (408 mg, 0.50 mmol, 0.05 equiv) in 1,4-dioxane (20 mL) was stirred under nitrogen for 12 h at 85 C. The resulting mixture was cooled to room temperature and concentrated under vacuum. The residue was purified on a silica gel column eluted with ethyl acetate/petroleum ether (1:15) to afford 2.48 g (86%) of 2-(3,5-diisopropylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane as a white solid. 1H NMR (400 MHz, DMSO-d6): δ 7.34 (s, 2H), 7.23 (s, 2H), 2.92-2.83 (m, 2H), 1.29 (s, 12H), 1.13 (d, J=6.9 Hz, 12H) ppm.
  • 2
  • [ 80058-84-0 ]
  • [ 1025719-26-9 ]
 

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