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[ CAS No. 103-59-3 ] {[proInfo.proName]}

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3d Animation Molecule Structure of 103-59-3
Chemical Structure| 103-59-3
Chemical Structure| 103-59-3
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Product Details of [ 103-59-3 ]

CAS No. :103-59-3 MDL No. :MFCD00048316
Formula : C13H16O2 Boiling Point : -
Linear Structure Formula :- InChI Key :KLKQSZIWHVEARN-RMKNXTFCSA-N
M.W : 204.26 Pubchem ID :5355851
Synonyms :

Safety of [ 103-59-3 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 103-59-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 103-59-3 ]

[ 103-59-3 ] Synthesis Path-Downstream   1~8

  • 1
  • [ 103-59-3 ]
  • [ 60533-01-9 ]
YieldReaction ConditionsOperation in experiment
17% Stage #1: cinnamyl isobutyrate With triethylamine at -60℃; for 0.0833333h; Inert atmosphere; Stage #2: With trimethylsilyl trifluoromethanesulfonate at -60 - 20℃; for 24h; Inert atmosphere; Typical procedure for Ireland-Claisen rearrangement with Et3N as a base General procedure: Ester 1 (2.34 mmol) was added into solution of Et3N (1.6 mL, 11.51 mmol) in dry CH2Cl2 (2.2 mL) under a nitrogen atmosphere. The reaction mixture was cooled to -60 °C. Then, trialkyl silyl triflate (3.7 mmol) was added dropwise. Next, an organocatalyst (10 mol %) was added in one portion. The reaction temperature was allowed to reach ambient temperature and the reaction mixture was stirred at this temperature for 24 h. After the reaction, the solvent was evaporated under reduced pressure. Diethyl ether (5 mL) and 1.3 M NaOH (7 mL) were added to the distillation residue. The aqueous layer was washed with CH2Cl2 (3x8 mL) and after that it was acidified with concentrated HCl. The products were extracted with CH2Cl2 (3x8 mL). The organic phase was washed with water (3x12 mL), dried with anhydrous MgSO4 and the solvent was evaporated under reduced pressure.
With sodium hydride In toluene
With hydrogenchloride; nitrobenzene; lithium diisopropyl amide Yield given. Multistep reaction;
  • 2
  • [ 103-59-3 ]
  • [ 60532-99-2 ]
YieldReaction ConditionsOperation in experiment
With sodium hydride In toluene
  • 3
  • [ 104-54-1 ]
  • [ 79-30-1 ]
  • [ 103-59-3 ]
YieldReaction ConditionsOperation in experiment
With pyridine In benzene
  • 4
  • [ 60533-00-8 ]
  • C26H30O4 [ No CAS ]
  • [ 103-59-3 ]
YieldReaction ConditionsOperation in experiment
1: 26% 2: 7% With indium(III) chloride; indium In acetonitrile Inert atmosphere; Sonication;
  • 5
  • [ 104-54-1 ]
  • C26H30O4 [ No CAS ]
  • [ 103-59-3 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: pyridine; dmap / dichloromethane / 1.5 h / 0 °C / Inert atmosphere 2: indium(III) chloride; indium / acetonitrile / Inert atmosphere; Sonication
  • 6
  • [ 103-59-3 ]
  • [ 100-46-9 ]
  • C20H25NO2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
12% With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)diiridium(I) dichloride; caesium carbonate In tetrahydrofuran at 90℃; for 24h; Inert atmosphere; Sealed tube;
  • 7
  • [ 104-54-1 ]
  • [ 97-62-1 ]
  • [ 103-59-3 ]
YieldReaction ConditionsOperation in experiment
With recombinant acyltransferase from Mycobacterium smegmatis In aq. phosphate buffer at 25℃; for 24h; Green chemistry; Enzymatic reaction;
  • 8
  • [ 103-59-3 ]
  • 3-phenyloxiran-2-yl methyl isobutyrate [ No CAS ]
YieldReaction ConditionsOperation in experiment
88% With 3,5,5-trimethyl hexanal; aluminium oxide nanoparticles; oxygen In acetonitrile at 60℃; for 24h; Schlenk technique; B. General procedure for the preparation of epoxides 2 General procedure: To a 25 mL dried Schlenk tube was added the mixture of nano-Al2O3 (10.2 mg), alkene1 (1.0 mmol), 3, 5, 5-trimethylhexanal (3.0 mmol) in dry MeCN (5 mL) successively.The resulting mixture was stirred at 60 °C for 24 h under 1 atm of O2. After the reactionwas completed, the reaction mixture was cooled to room temperature, diluted withEtOAc (25 mL) and filtered. After removing the solvent under vacuum, the crudeproduct was separated by column chromatography on silica gel using PE-EtOAc aseluent to give the desired product 2.
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