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Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
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Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 10534-88-0 Chemical Structure| 10534-88-0

Structure of 10534-88-0

Chemical Structure| 10534-88-0

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Little, Joshua M ; Li, Shuo ; Li, Yang ; Wu, Lianping ; Huseynli, Asmat ; Srivastava, Satyam , et al.

Abstract: Two-dimensional materials (2DMs) exhibit distinctive electronic, electrochemical, and barrier properties, yet scalable production methods for conformal, thick, and uniform coatings across diverse and complex substrates remain limited. We introduce a Metal Ion Release Assembly (MIRA) strategy that uses a gelatin hydrogel preloaded with metal ions (Mn+) as a controlled ion-release platform. Upon immersion in a 2DM dispersion, Mn+ is released from the hydrogel, screening the surface charges of nanosheets and inducing electrostatic assembly at the gelatin hydrogel surface. This MIRA process enables the formation of Mn+–2DM multilayer coatings without the need for additives. The applicability of MIRA is demonstrated using graphene oxide, Ti3C2Tx MXene, and montmorillonite nanosheets via spin coating, dip coating, and doctor blading. Coating thicknesses from ∼1 μm to >20 μm are systematically tuned by adjusting immersion time, Mn+ concentration, and 2DM dispersion concentration. Interference reflection microscopy confirms rapid nanosheet attachment and assembly driven by burst Mn+ release. A diffusion-limited analytical model based on Fick’s second law with time-dependent diffusion coefficients accurately predicts coating thickness evolution. Mn+ can be removed through mild acid rinsing. Scalability and substrate adaptability in MIRA are demonstrated by fabricating large-area (∼400 cm2) and conformal coatings on curved and cylindrical surfaces. Electrochemical tests show the MXene electrodes fabricated using MIRA and acid rinsing processes perform comparably to pristine MXene electrodes, with similar resistances, specific capacitance, and cycling stability. MIRA provides a tunable and scalable platform for thick 2DM coatings, with applications in sensing, electromagnetic shielding, and corrosion protection.

Keywords: metal ions ; electrostatic assembly ; 2D materials ; scalable coating ; controllable release kinetics

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Little, Joshua Michael ;

Abstract: This dissertation introduces novel strategies for the synthesis and assembly of 2D materials (2DMs) into functional heterostructures, leveraging metal ion interactions and nanoconfinement effects. It details the creation of noble metal ion (NMI)-crosslinked 2DM hydrogels and the development of NMI-complexed 2DM inks. A key contribution is the introduction of the Metal Ion Release Assembly (MIRA) process, a versatile and scalable method for depositing thick and uniform 2DM coatings on complex surfaces using metal ion-loaded hydrogels. This technique allows for tunable coating thickness by controlling parameters such as metal ion concentration and 2DM dispersion concentration. Furthermore, the dissertation presents a novel electrostatic assembly process guided by vacuum filtration for the synthesis of catalytic metal nanocrystals, specifically platinum (Pt), within the interlayer confined spacings of 2DMs like graphene oxide (GO) and MXene. This method enables controllable Pt loadings and influences the size, distribution, and morphology of the resulting Pt nanocrystals by manipulating the concentration of the tetraammineplatinum(II) nitrate (TPtN) precursor and water removal techniques such as air-drying and freeze-drying. The synthesized Pt-2DM heterostructures demonstrate substrate-dependent catalytic activities in reactions like 3-nitrostyrene and phenylacetylene hydrogenation. Beyond catalysis, the dissertation showcases the broader applications of 2DM assemblies, including anti-counterfeiting technologies utilizing unclonable MXene topographies and the use of machine learning to accelerate the design of sustainable biobased packaging, ultrastretchable electronics, and nerve-on-a-chip platforms. This comprehensive work enhances the fundamental understanding of metal-2DM interactions and establishes new, scalable fabrication strategies for high-performance materials relevant to energy, environmental solutions, and advanced manufacturing.

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Alternative Products

Product Details of [ 10534-88-0 ]

CAS No. :10534-88-0
Formula : Cl2H18N6Ni
M.W : 231.78
SMILES Code : [NH3][Ni+2]([NH3])([NH3])([NH3])([NH3])[NH3].[Cl-].[Cl-]
MDL No. :MFCD00011505

Safety of [ 10534-88-0 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H312-H317-H332-H334-H350
Precautionary Statements:P264-P301+P312-P280-P302+P352-P312-P261-P333+P313-P304+P340-P285-P342+P311-P308+P313-P405-P501
Class:6.1
UN#:2811
Packing Group:
 

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