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Chemical Structure| 1093862-55-5 Chemical Structure| 1093862-55-5

Structure of 1093862-55-5

Chemical Structure| 1093862-55-5

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Product Details of [ 1093862-55-5 ]

CAS No. :1093862-55-5
Formula : C14H7BrN2S3
M.W : 379.32
SMILES Code : BrC1=CC=C(C2=CC=C(C3=CC=CS3)C4=NSN=C42)S1
MDL No. :N/A

Safety of [ 1093862-55-5 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319
Precautionary Statements:P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330

Application In Synthesis of [ 1093862-55-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1093862-55-5 ]

[ 1093862-55-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 1093862-55-5 ]
  • [ 121554-09-4 ]
  • 4-(5-(4-octyloxyphenyl)-2-thienyl)-7-(2-thienyl)-2,1,3-benzothiadiazole [ No CAS ]
YieldReaction ConditionsOperation in experiment
59% With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In ethanol; water; toluene; at 90℃;Inert atmosphere; 4-Octyloxyphenylboronic acid (0.69 g, 2.77 mmol), compound 13 (0.70 g, 1.85 mmol), K2CO3 (1.27 g, 9.23 mmol), toluene (40 ml), ethanol (5 ml) and water (20 ml) were all added to a 3- neck round bottomed flask and the system was evacuated, with the aid of a vacuum pump, and filled with nitrogen 3 times. Subsequently, Pd(PP i3)4 (0.10 g, 0.09 mmol) was added and the reaction mixture was heated to 90 C overnight. The reaction mixture was poured into a separating funnel, in which water (10 ml) and more toluene (10 ml) was added. The organic layer was concentrated under reduced pressure with subsequent azeotropic drying The crude product was purified by flash column chromatography (silica gel) using 30% CH2CI2 in hexanes as the eluent to yield 14 as a red powder (0.55 g, 59%). 1 H NMR (400 MHz, CDCb): δ (ppm) 0.92 (t, 3H), 1.28-1.40 (m, 8H), 1.48 (quint, 2H), 1.83 (quint., 2H), 4.03 (t, 2H), 6.97 (d, 2H), 7.24 (dd, 1 H), 7.33 (d, 1 H), 7.48 (dd, 1 H), 7.65 (d, 2H), 7.90 (d, 2H), 8.12 (d, 1 H), 8.15 (dd, 1 H).
 

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