Home Cart Sign in  
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

Type HazMat fee for 500 gram (Estimated)
Excepted Quantity USD 0.00
Limited Quantity USD 15-60
Inaccessible (Haz class 6.1), Domestic USD 80+
Inaccessible (Haz class 6.1), International USD 150+
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 100+
Accessible (Haz class 3, 4, 5 or 8), International USD 200+
Chemical Structure| 1118567-11-5 Chemical Structure| 1118567-11-5

Structure of 1118567-11-5

Chemical Structure| 1118567-11-5

*Storage: {[sel_prStorage]}

*Shipping: {[sel_prShipping]}

,{[proInfo.pro_purity]}

4.5 *For Research Use Only !

{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]} Purity: {[proInfo.pro_purity]}

Change View

Size Price VIP Price

US Stock

Global Stock

In Stock
{[ item.pr_size ]} Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price, item.vip_usd) ]}

US Stock: ship in 0-1 business day
Global Stock: ship in 5-7 days

  • {[ item.pr_size ]}

In Stock

- +

Please Login or Create an Account to: See VIP prices and availability

US Stock: ship in 0-1 business day
Global Stock: ship in 2 weeks

  • 1-2 Day Shipping
  • High Quality
  • Technical Support
Product Citations

Alternative Products

Product Details of [ 1118567-11-5 ]

CAS No. :1118567-11-5
Formula : C11H15FO4S
M.W : 262.30
SMILES Code : O=S(C1=CC=C(C)C=C1)(OCCOCCF)=O
MDL No. :MFCD30290198

Safety of [ 1118567-11-5 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H302-H312-H332-H335-H317-H314
Precautionary Statements:P260-P264-P270-P271-P272-P280-P301+P330+P331-P302+P352-P303+P361+P353-P304+P340-P305+P351+P338-P310-P333+P313-P363-P403+P233-P405-P501
Class:8
UN#:1760
Packing Group:

Application In Synthesis of [ 1118567-11-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1118567-11-5 ]

[ 1118567-11-5 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 1118567-11-5 ]
  • [ 13406-29-6 ]
  • (2-(2-fluoroethoxy)ethyl)tris(4-(trifluoromethyl)phenyl)phosphonium salt [ No CAS ]
YieldReaction ConditionsOperation in experiment
In toluene;Heating; Finally, 1.0 g of 2-(2-fluoroethoxy)ethyl 4-methylbenzenesulfonate was added to 5 ml of toluene in which 1.2 g of tris (4-(trifluoromethyl)phenyl)phosphine was dissolved, And then heated again with a hot air blower. The synthesized (2-(2-fluoroethoxy)ethyl) tripyridin-4-ylphosphonium salt was cooled at room temperature and then separated and purified using a quasi-purification column.
  • 2
  • [ 118591-58-5 ]
  • [ 1118567-11-5 ]
YieldReaction ConditionsOperation in experiment
44% With diethylamino-sulfur trifluoride; In dichloromethane; at 0 - 25℃; for 2h;Inert atmosphere; To a solution of 2-(2-hydroxyethoxy)ethyl 4-methylbenzenesulfonate (7.64 g, 29.3 mmol) in DCM (115 ml) under Ar was added at 0-5 C diethylaminosulfur trifluoride (14.2 g, 11.6 ml, 88 mmol). The light yellow solution was warmed to 20-25 C and was stirred for 1 h. The reaction mixture was cooled again to 5-10 C and quenched with 1M NaHCCh (200 ml) and solid NaHCCh (11 g) was added to reach pH 7-8. The organic layer was concentrated under vacuum. Due to bad conversion, the crude was dissolved again in DCM (115 ml) under Ar and diethylaminosulfur trifluoride (7.1 g, 5.82 ml, 44 mmol) was added at 0-5 C. The light yellow solution was warmed to 20-25C and stirred for 1 h. The reaction mix was cooled again to 5-lOC and quenched with 1M NaHCCh (200 ml), and solid NaHCCh (3 g) was added to reach pH 7-8. The organic layer was concentrated under vacuum to obtain the crude product as a yellow oil which was purified by MPLC over silica (eluent: heptane/ethyl acetate) to obtain the desired product (3.4 g, 44%) as a light yellow oil. 1 H NMR (400 MHz, CHLOROFORM-d) d ppm 1.56 (s, 1 H) 1.90 (t, J=6.l8 Hz, 1 H) 2.45 (s, 3 H) 3.50 - 3.57 (m, 2 H) 3.63 - 3.74 (m, 4 H) 4.16 - 4.25 (m, 2 H) 7.31 - 7.41 (m, 2 H) 7.76 - 7.85 (m, 2 H). LC- MS: m/z = 261.2 [M-H] .
 

Historical Records