Alternatived Products of [ 112170-33-9 ]
Product Details of [ 112170-33-9 ]
CAS No. : | 112170-33-9 |
MDL No. : | |
Formula : |
C13H10N2
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
194.23
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 112170-33-9 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 112170-33-9 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 112170-33-9 ]
- 1
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[ 91983-26-5 ]
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[ 19524-06-2 ]
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[ 112170-33-9 ]
- 2
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[ 112170-33-9 ]
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[ 99163-12-9 ]
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[ 950520-47-5 ]
- 3
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[ 112170-33-9 ]
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[ 99163-12-9 ]
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(Z)-2,3-bis(4-(pyridin-4-yl)phenyl)acrylonitrile
[ No CAS ]
- 4
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[ 133878-94-1 ]
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[ 112170-33-9 ]
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[ 2407762-42-7 ]
Yield | Reaction Conditions | Operation in experiment |
83% |
With sodium ethanolate In ethanol at 20℃; for 24h; Inert atmosphere; Cooling with ice; |
1
In an ice bath, under the protection of argon, to a solution of compound 3a (1eq.) And compound 4 (1eq.) In anhydrous ethanol was added sodium ethoxide (the amount of sodium ethoxide relative to the molar ratio of compound 3). It is 1: 1), and the condensation reaction is performed at room temperature for 24 hours. The precipitated solid was filtered, washed with ethanol, and dried under vacuum to obtain compound 5a.Compound 5a (540mg, 83% yield) was prepared from compound 3a (400mg, 1.43mmol) as a red solid. |
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With sodium ethanolate In ethanol at 20℃; for 24h; |
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Reference:
[1]Current Patent Assignee: NANKAI UNIVERSITY - CN110642852, 2020, A
Location in patent: Paragraph 0053; 0063; 0066-0068
[2]Chen, Chao; Ni, Xiang; Jia, Shaorui; Liang, Yong; Wu, Xiaoli; Kong, Deling; Ding, Dan
[Advanced Materials, 2019, vol. 31, # 52]
- 5
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[ 53566-95-3 ]
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[ 112170-33-9 ]
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[ 2816169-81-8 ]
Yield | Reaction Conditions | Operation in experiment |
78.4% |
With potassium hydroxide In ethanol at 20℃; for 5h; Inert atmosphere; Sealed tube; |
2 2) Preparation of (2Z,2'Z)-3,3'- ((benzozaalkynyl)bis(4,1-phenyl)bis(2-(4-(4-(pyridine-4-J)phenyl)acrylonitrile):
0.52mmol 2-(4-pyridine-4-phenyl)acetonitrile and 0.22mmol 4,4-dicarbonyltriphenylamine, 0.52mmol potassium hydroxide and 20mL ethanol were added to the flask with a stirrer, the rubber stopper was sealed, nitrogen protected, and the reaction was carried out for 5 hours at room temperature; The reactants were dried dry, extracted with dichloromethane and water, and then recrystallized and purified with petroleum ether, dichloromethane, ethyl acetate system (petroleum ether: dichloromethane: ethyl acetate = 50:5:1, v:v:v), and after concentrated drying, the yield was 78.4%. |
78.4% |
With potassium hydroxide In ethanol at 20℃; Inert atmosphere; |
|
Reference:
[1]Current Patent Assignee: SOUTHERN MEDICAL UNIVERSITY CHINA - CN114853665, 2022, A
Location in patent: Paragraph 0099-0100; 0103-0104
[2]Yang, Hui; Shang, Zhanhao; Shi, Qiankun; Gao, Jucai; Wang, Xiaorui; Hu, Fang
[Chemistry - An Asian Journal, 2023, vol. 18, # 10]