Alternatived Products of [ 1143576-84-4 ]
Product Details of [ 1143576-84-4 ]
CAS No. : | 1143576-84-4 |
MDL No. : | MFCD28975121 |
Formula : |
C32H29BO2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
456.38
|
Pubchem ID : | - |
Synonyms : |
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Safety of [ 1143576-84-4 ]
Application In Synthesis of [ 1143576-84-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1143576-84-4 ]
- 1
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[ 1229012-68-3 ]
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[ 1143576-84-4 ]
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2-chloro-4,7-diphenyl-9-(4-(10-phenylanthracen 9-yl)phenyl)-1,10-phenanthroline
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
50.8% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate; In ethanol; toluene; at 100℃; for 12.0h;Inert atmosphere; |
Synthesis of 2-chloro-4,7-diphenyl-9-(4-(10-phenylanthracen 9-yl)phenyl)-1,10-phenanthroline A mixture of 6.8 g (16.9 mmol) of <strong>[1229012-68-3]2,9-dichloro-4,7-diphenyl-1,10-phenanthroline</strong>, 7.7 g (16.9 mmol) of 4,4,5,5-tetramethyl-2-(4-(10-phenylanthracen-9-yl)phenyl)-1,3,2-dioxaborolane, 196 mg (0.17 mmol) of Pd(PPh3)4, 17 ml of 2M Na2CO3, 50 ml of EtOH and 150 ml toluene was degassed and placed under nitrogen, and then heated at 100 C. for 12 h. After finishing the reaction, the mixture was allowed to cool to room temperature. The organic layer was extracted with ethyl acetate and water, dried with anhydrous magnesium sulfate, the solvent was removed and the residue was purified by column chromatography on silica to give product (6 g, 8.6 mmol, 50.8%) as a yellow solid. |