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Chemical Structure| 12154-84-6 Chemical Structure| 12154-84-6

Structure of 12154-84-6

Chemical Structure| 12154-84-6

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Product Details of [ 12154-84-6 ]

CAS No. :12154-84-6
Formula : C13H19IrO2
M.W : 399.51
SMILES Code : CC1=O[Ir+]234(O=C(C)[CH-]1)C5=C2CCC3=C4CC5
MDL No. :MFCD08273779

Safety of [ 12154-84-6 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319-H335
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340+P312-P305+P351+P338-P332+P313-P337+P313-P403+P233-P405-P501

Application In Synthesis of [ 12154-84-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 12154-84-6 ]

[ 12154-84-6 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 64-18-6 ]
  • [ 12154-84-6 ]
  • [ 739-58-2 ]
  • [ 1379605-13-6 ]
  • [ 1379605-13-6 ]
YieldReaction ConditionsOperation in experiment
[0144] Under argon atmosphere, (4-dimethylaminophenyl)diphenylphosphine (e) (122.1 mg, 0.4 mmol) and acetylacetonato iridium(1,5-cyclooctadiene) (80.0 mg, 0.2 mmol) were placed in a Schlenk flask. Four milliliters of a degassed 1,2-dimethoxyethane was added thereto with a syringe, and the flask was tightly sealed, followed by stirring the resulting mixture at 15° C. for 12 hours. Thereafter, 1,2-dimethoxyethane was removed under reduced pressure, and 2.5 mL of a degassed aqueous formic acid solution (98 vol percent) was added thereto with a syringe. The flask was tightly sealed, and the mixture was stirred at 60° C. for 1 hour. Thereafter, the aqueous formic acid solution was removed under reduced pressure, and ethanol was added thereto, followed by stirring the resulting mixture overnight and then washing. As a result, the iridium hydride complex E was obtained as white powder (115.9 mg, 0.14 mmol). Spectroscopic Data of the Iridium Hydride Complex E: [0145] 1H NMR (CD2Cl2), delta: 7.17-7.68 (m, 24H), 6.51-6.53 (m, 4H), 2.99 (s, 12H), [mer: ?10.08 (td, JH-P=16.8 Hz, JH-H=4.8 HZ, 2H), ?10.48 (tt, JH-P=18.8 Hz, JH-H=5.2 Hz, 1H)], [fac: ?10.18 (t, JH-P=18.4 Hz, 1H), ?11.64 (ddd, JH-P=103.5, 19.2 Hz, JH-H=2.4 Hz, 2H)] [0146] 31P[1H] NMR (CD2Cl2), delta: [mer: 13.9 (s)], [fac: 5.62 (s)]
  • 2
  • [ 12154-84-6 ]
  • [ 739-58-2 ]
  • Ir(acac)(P(4-dmaPh)Ph<SUB>2</SUB>)<SUB>2</SUB> [ No CAS ]
YieldReaction ConditionsOperation in experiment
In 1,2-dimethoxyethane; at 80℃; for 12h;Inert atmosphere; Schlenk technique; Sealed tube; [0165] Under argon atmosphere, acetylacetonato iridium (1,5-cyclooctadiene) (20 mg, 0.05 mmol) and (4-dimethylaminophenyl)diphenylphosphine (b) (30.5 mg, 0.10 mmol) were placed in a Schlenk flask. After addition of a degassed 1,2-dimethoxyethane (1 mL) thereto with a syringe, the flask was tightly sealed, and the mixture was stirred at room temperature for 12 hours. Thereafter, precipitated pale yellow solids were collected as the iridium complex B. Spectroscopic Data of the Iridium Complex B: [0166] 1H NMR (C6D6), delta: 7.94-8.03 (m, 12H), 7.00-7.20 (m, 12H), 6.37-6.39 (m, 4H), 5.40 (s, 1H), 2.43 (s, 12H), 1.38 (s, 6H) [0167] 31P[1H] NMR (C6D6), delta: 16.3 (s)
 

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