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Chemical Structure| 12184-22-4 Chemical Structure| 12184-22-4

Structure of 12184-22-4

Chemical Structure| 12184-22-4

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Product Details of [ 12184-22-4 ]

CAS No. :12184-22-4
Formula : C10Cl2Mo
M.W : 286.95
SMILES Code : [Cl-][Mo+4]12345678(C9=C1[C-]2C3=C49)(C%10=C5[C-]6C7=C8%10)[Cl-]
MDL No. :MFCD00009948

Safety of [ 12184-22-4 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H314
Precautionary Statements:P271-P280-P264-P301+P330+P331-P303+P361+P353-P310-P304+P340-P305+P351+P338-P363-P403+P233-P501
Class:8
UN#:3261
Packing Group:

Application In Synthesis of [ 12184-22-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 12184-22-4 ]

[ 12184-22-4 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 12184-22-4 ]
  • [ 137-66-6 ]
  • Cp<SUB>2</SUB>Mo(6-O-palmitoyl-L-ascorbato) [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% With sodium hydroxide; In water; at 20℃;pH 10.0;Inert atmosphere; General procedure: 6-O-Palmitoyl l-ascorbic acid (82.3 mg (0.20 mmol) was charged in a three neck round bottom flask of 100 mL, in 10 mL of deionized, degassed water and sonicated for 2 h to induce dissolution. In a separate a three neck round bottom flask of 100 mL, 58.9 mg (0.20 mmol) of Cp2MoCl2 in 6 mL of deionized, degassed water was also sonicated for 2 h. To this solution, the 6-O-palmitoyl-l-ascorbic acid was added and the pH adjusted to 10 with 0.1 M NaOH. The reaction mixture was stirred overnight at room temperature under a nitrogen atmosphere, forming a dark-yellow precipitate. The precipitate was filtered and washed with small amounts of water. The product was purified by column chromatography, using LH20 (lipophilic sephadex 20-100 mum) as solid phase and methanol as solvent. The product was dried under vacuum for 24 h. IR (KBr, cm- 1): 3116, 2960, 2915, 2850, 1734, 1614, 1470, 1261, 717. 1H NMR (D2O): 5.70 (s, 5H, Cp), 5.68 (s, 5H, Cp?), 5.25 (d, 1OH5, J = 6.8 Hz), 4.30 (d, 1H4, J = 4.2 Hz), 4.09 (dd, 2H6, J = 4.4 Hz, J = 11.4 Hz), 3.86 (pseudo dd, 1H5, J = 11.7 Hz, J = 7.9 Hz), 2.29 (t, 2H7, J = 7.4 Hz), 1.51(quintet, 2H8, J = 6.3 Hz), 1.24 (bs, 12H9-20), 0,86 (t, 3H21, J = 6.6 Hz). 13C NMR (DMSO-d6): delta (ppm): 177.5 (CO), 172.9 (CO), 139.82 (C2), 129.88 (C3), 102.71 (Cp), 102.48 (Cp?), 73.8, 68.3, 64.8, 33.5, 31.3, 29.1, 29.0, 28.9, 28.8, 28.5, 24.5, 22.1, 14.0. Anal. Calc. for Mo(C32H46O7): C, 60.18; H, 7.26. Found:C, 59.95; H, 7.15
 

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