[ CAS No. 1250980-04-1 ] {[proInfo.proName]}

Name: 1250980-04-1|5'-(4-Carboxyphenyl)-[1,1':3',1''-terphenyl]-3,4'',5-tricarboxylic acid|98%
Brand: Ambeed
SKU: A1271723
Price: 41.0 USD
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Quality Control of [ 1250980-04-1 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 1250980-04-1 ]

Product Details of [ 1250980-04-1 ]

CAS No. :	1250980-04-1	MDL No. :
Formula :	C₂₈H₁₈O₈	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	SFQRRWVFWPTCJU-UHFFFAOYSA-N
M.W :	482.44	Pubchem ID :	102518112
Synonyms :

Safety of [ 1250980-04-1 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1250980-04-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1250980-04-1 ]

[ 1250980-04-1 ] Synthesis Path-Downstream 1~8

1
trimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1':3',1''-terphenyl]-3,4'',5-tricarboxylate [ No CAS ]
[ 1250980-04-1 ]

Yield	Reaction Conditions	Operation in experiment
0.54 g	With lithium hydroxide monohydrate; potassium hydroxide In 1,4-dioxane for 18h; Reflux;
	With lithium hydroxide monohydrate; potassium hydroxide

Reference： [1]Schnobrich, Jennifer K.; Lebel, Olivier; Cychosz, Katie A.; Dailly, Anne; Wong-Foy, Antek G.; Matzger, Adam J. [Journal of the American Chemical Society, 2010, vol. 132, # 39, p. 13941 - 13948]
[2]Ahmed, Alauddin; Matzger, Adam J.; Nath, Karabi; Siegel, Donald J. [Angewandte Chemie - International Edition, 2022, vol. 61, # 25][Angew. Chem., 2022, vol. 134, # 25]

2
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 1250980-04-1 ]
(Cu₂(C₂₄H₁₄(COO)4)(H₂O)1.5), trigonal, R₃M [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%	With HCl In 1,4-dioxane; water; N,N-dimethyl-formamide Sonication; Cu(NO3)2*2.5H2O and acid in 0.005 M soln. HCl in DMF-dioxane-H2) (4:1:1)were sonicated until dissolved and heated at 85°C for 12 h; mother liquor was decanted and replaced with fresh DMF-dioxane-H2O (4:1:1), crystals were washed twice with DMF and five times with acetone, dried in vacuo at room temp. for 4 h and at 100°C for 18 h; elem. anal.;

3
copper nitrate hemi(pentahydrate) [ No CAS ]
[ 1250980-04-1 ]
(Cu₂(C₂₄H₁₄(COO)4)(H₂O)1.5), orthorhombic, FDDD [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
55%	In 1,4-dioxane; water; N,N-dimethyl-formamide Sonication; Cu(NO3)2*2.5H2O and acid in DMF-dioxane-H2) (4:1:1) were sonicated untildissolved and heated at 85°C for 24 h; mother liquor was decanted and replaced with fresh DMF-dioxane-H2O (4:1:1), crystals were washed twice with DMF and five times with acetone, dried in vacuo at room temp. for 4 h and at 100°C for 18 h; elem. anal.;

4
C₃₄H₃₀O₈ [ No CAS ]
[ 1250980-04-1 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide In tetrahydrofuran; methanol at 85℃; for 12h;

5
yttrium(lll) nitrate hexahydrate [ No CAS ]
[ 1250980-04-1 ]
[ 7732-18-5 ]
[ 33513-42-7 ]
[ 445-29-4 ]
[dimethylammonium]₂[Y₆(μ₃-OH)₈(5′-(4-carboxyphenyl)-[1,1′:3′,1″-terphenyl]-3,4″,5-tricarboxylic acid)₂(2-fluorobenzoic acid)₃(formate)(N,N-dimethylformamide)₄] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
40%	at 115℃; for 24h; High pressure;

6
[ 626-39-1 ]
[ 1250980-04-1 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: anhydrous sodium carbonate; tetrakis-(triphenylphosphine)-palladium / tetrahydrofuran / 48 h / 85 °C / Inert atmosphere 2: anhydrous sodium carbonate; tetrakis-(triphenylphosphine)-palladium / tetrahydrofuran / 85 h / 24 °C / Inert atmosphere 3: sodium hydroxide / tetrahydrofuran; methanol / 12 h / 85 °C
	Multi-step reaction with 3 steps 1: tripotassium phosphate tribasic; tetrakis-(triphenylphosphine)-palladium 2: tripotassium phosphate tribasic; tetrakis-(triphenylphosphine)-palladium 3: potassium hydroxide; lithium hydroxide monohydrate

Reference： [1]Angeli, Giasemi K.; Bosveli, Artemis; Froudakis, George; Kouvidis, Konstantinos; Loukopoulos, Edward; Trikalitis, Pantelis N.; Tsangarakis, Constantinos; Tylianakis, Emmanuel [Journal of the American Chemical Society, 2021, vol. 143, # 27, p. 10250 - 10260]
[2]Ahmed, Alauddin; Matzger, Adam J.; Nath, Karabi; Siegel, Donald J. [Angewandte Chemie - International Edition, 2022, vol. 61, # 25][Angew. Chem., 2022, vol. 134, # 25]

7
[ 99768-12-4 ]
[ 1250980-04-1 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: anhydrous sodium carbonate; tetrakis-(triphenylphosphine)-palladium / tetrahydrofuran / 48 h / 85 °C / Inert atmosphere 2: anhydrous sodium carbonate; tetrakis-(triphenylphosphine)-palladium / tetrahydrofuran / 85 h / 24 °C / Inert atmosphere 3: sodium hydroxide / tetrahydrofuran; methanol / 12 h / 85 °C
	Multi-step reaction with 3 steps 1: tripotassium phosphate tribasic; tetrakis-(triphenylphosphine)-palladium 2: tripotassium phosphate tribasic; tetrakis-(triphenylphosphine)-palladium 3: potassium hydroxide; lithium hydroxide monohydrate

8
dimethyl 5'-bromo-[1,1':3',1''-terphenyl]-4,4''-dicarboxylate [ No CAS ]
[ 1250980-04-1 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: tripotassium phosphate tribasic; tetrakis-(triphenylphosphine)-palladium 2: potassium hydroxide; lithium hydroxide monohydrate

Reference： [1]Ahmed, Alauddin; Matzger, Adam J.; Nath, Karabi; Siegel, Donald J. [Angewandte Chemie - International Edition, 2022, vol. 61, # 25][Angew. Chem., 2022, vol. 134, # 25]

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[ CAS No. 1250980-04-1 ] {[proInfo.proName]}

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Application In Synthesis of [ 1250980-04-1 ]

[ 1250980-04-1 ] Synthesis Path-Downstream 1~8

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