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Chemical Structure| 1256781-61-9 Chemical Structure| 1256781-61-9

Structure of 1256781-61-9

Chemical Structure| 1256781-61-9

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Product Details of [ 1256781-61-9 ]

CAS No. :1256781-61-9
Formula : C12H15BBr2O3
M.W : 377.87
SMILES Code : CC1(C)OB(OC1(C)C)C1=C(Br)C=CC(O)=C1Br
MDL No. :MFCD17215824

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Application In Synthesis of [ 1256781-61-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1256781-61-9 ]

[ 1256781-61-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 365564-07-4 ]
  • [ 1256781-61-9 ]
  • pinacol 2,6-dibromo-3,5-dimethoxypnehylboronate [ No CAS ]
YieldReaction ConditionsOperation in experiment
90% With N-Bromosuccinimide; In N,N-dimethyl-formamide; at 20℃; for 14h; General procedure: To a solution of 3-anisyl pinacol borane (50mg, 0.21mmol) in DMF (1mL) was added N-bromosuccinimide (82mg, 0.46mmol). After stirring at room temperature for 14h, resultant solution was treated with 10% Na2S2O3 aq (10 ml) and was extracted with Et2O (10ml×3). The combined organic phase was washed with H2O (10ml×2) and brine (10ml×1) and dried over MgSO4. After removal of solvent under reduced pressure, the residue was chromatographed on silica gel with Hexane to afford 2-bromo-5-methoxyphenyl pinacol borate (57.3mg, 87% yield) as colorless oil
 

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