Alternatived Products of [ 1283676-82-3 ]
Product Details of [ 1283676-82-3 ]
CAS No. : | 1283676-82-3 |
MDL No. : | |
Formula : |
C24H26N2O7
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | XKYMEDSRZSGBCL-IBGZPJMESA-N |
M.W : |
454.47
|
Pubchem ID : | 101907290 |
Synonyms : |
|
Safety of [ 1283676-82-3 ]
Application In Synthesis of [ 1283676-82-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1283676-82-3 ]
- 1
-
dimethyl 2-amino-[1,1’-biphenyl]-4,4’-dicarboxylate
[ No CAS ]
-
[ 1283676-82-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1.1: dmap; diisopropyl-carbodiimide / dichloromethane / 0.5 h / Cooling with ice
1.2: 40 h / 40 °C
2.1: water; potassium hydroxide / tetrahydrofuran / 16 h / 50 °C |
|
- 2
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[ 67-56-1 ]
-
[ 1283676-82-3 ]
-
[ 1283676-80-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
With sulfuric acid Reflux; optical yield given as %ee; |
|
- 3
-
[ 67-56-1 ]
-
[ 1283676-82-3 ]
-
C21H22N2O5
[ No CAS ]
-
C21H22N2O5
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
Stage #1: C24H26N2O7 With zinc(II) nitrate; N-formyldiethylamine
Stage #2: Heating;
Stage #3: methanol With sulfuric acid for 16h; Reflux; |
|
- 4
-
[ 1007568-39-9 ]
-
[ 1283676-82-3 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 3 steps
1.1: palladium 10% on activated carbon; hydrogen / methanol; dichloromethane / 18 h / 2327.23 Torr
2.1: dmap; diisopropyl-carbodiimide / dichloromethane / 0.5 h / Cooling with ice
2.2: 40 h / 40 °C
3.1: water; potassium hydroxide / tetrahydrofuran / 16 h / 50 °C |
|
|
Multi-step reaction with 3 steps
1.1: acetic acid; iron / 12 h / 50 °C
2.1: benzotriazol-1-ol; dicyclohexyl-carbodiimide / dichloromethane / 96 h / 0 °C / Inert atmosphere
3.1: potassium hydroxide / tetrahydrofuran; water / 19 h / 50 °C
3.2: pH 4 |
|
Reference:
[1]Lun, David J.; Waterhouse, Geoffrey I. N.; Telfer, Shane G.
[Journal of the American Chemical Society, 2011, vol. 133, # 15, p. 5806 - 5809]
[2]Kutzscher, Christel; Hoffmann, Herbert C.; Krause, Simon; Stoeck, Ulrich; Senkovska, Irena; Brunner, Eike; Kaskel, Stefan
[Inorganic Chemistry, 2015, vol. 54, # 3, p. 1003 - 1009]
- 5
-
[ 1283676-80-1 ]
-
[ 1283676-82-3 ]
Yield | Reaction Conditions | Operation in experiment |
88% |
Stage #1: dimethyl 2-(1-(tert-butoxycarbonyl)pyrrolidine-2-carboxamido)biphenyl-4,4'-dicarboxylate With potassium hydroxide In tetrahydrofuran; water at 50℃; for 19h;
Stage #2: With hydrogenchloride In water |
|
393 mg |
With water; potassium hydroxide In tetrahydrofuran at 50℃; for 16h; optical yield given as %ee; |
|
Reference:
[1]Kutzscher, Christel; Hoffmann, Herbert C.; Krause, Simon; Stoeck, Ulrich; Senkovska, Irena; Brunner, Eike; Kaskel, Stefan
[Inorganic Chemistry, 2015, vol. 54, # 3, p. 1003 - 1009]
[2]Lun, David J.; Waterhouse, Geoffrey I. N.; Telfer, Shane G.
[Journal of the American Chemical Society, 2011, vol. 133, # 15, p. 5806 - 5809]
- 6
-
[ 1283676-82-3 ]
-
[ 1283676-84-5 ]
Yield | Reaction Conditions | Operation in experiment |
90% |
With trifluoroacetic acid In dichloromethane for 0.166667h; Cooling with ice; |
|
- 7
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[ 792-74-5 ]
-
[ 1283676-82-3 ]
- 8
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4,4′,4″-(benzene-1,3,5-tricarbonyltris(azanediyl)) tribenzoic acid
[ No CAS ]
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zinc nitrate tetrahydrate
[ No CAS ]
-
[ 1283676-82-3 ]
-
4Zn(2+)*O(2-)*C24H24N2O7(2-)*1.33C30H18N3O9(3-)*5H2O
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
78% |
at 100℃; for 48h; |
|
Reference:
[1]Kutzscher, Christel; Hoffmann, Herbert C.; Krause, Simon; Stoeck, Ulrich; Senkovska, Irena; Brunner, Eike; Kaskel, Stefan
[Inorganic Chemistry, 2015, vol. 54, # 3, p. 1003 - 1009]
- 9
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zinc nitrate tetrahydrate
[ No CAS ]
-
[ 100-21-0 ]
-
[ 1283676-82-3 ]
-
[ 1453220-01-3 ]
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[Zn4O(1,4-benzenedicarboxylate)1/2(bpdc-ProBoc)1/2(5,5',10,10',15,15'-hexamethyltruxene-2,7,12-tricarboxylato)4/3]
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In water at 85℃; for 17h; |
|
- 10
-
zinc nitrate tetrahydrate
[ No CAS ]
-
[ 605-70-9 ]
-
[ 1283676-82-3 ]
-
[ 1453220-01-3 ]
-
[Zn4O(ndc)1/2(bpdc-ProBoc)1/2(5,5',10,10',15,15'-hexamethyltruxene-2,7,12-tricarboxylato)4/3]
[ No CAS ]
- 11
-
zinc nitrate tetrahydrate
[ No CAS ]
-
[ 100-21-0 ]
-
[ 1137578-95-0 ]
-
[ 1283676-82-3 ]
-
[Zn4O(1,4-benzenedicarboxylate)1/2(bpdc-ProBoc)1/2(hett)4/3]
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In water at 85℃; for 17h; |
|
- 12
-
zinc nitrate tetrahydrate
[ No CAS ]
-
[ 100-21-0 ]
-
[ 1283676-82-3 ]
-
5,5',10,10',15,15'-hexabutyltruxene-2,7,12-tricarboxylic acid
[ No CAS ]
-
[Zn4O(1,4-benzenedicarboxylate)1/2(bpdc-ProBoc)1/2(hbtt)4/3]
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
Stage #1: zinc nitrate tetrahydrate; terephthalic acid; C24H26N2O7; 5,5',10,10',15,15'-hexabutyltruxene-2,7,12-tricarboxylic acid In water at 85℃; for 17h;
Stage #2: for 20h; |
|
- 13
-
zinc nitrate tetrahydrate
[ No CAS ]
-
[ 100-21-0 ]
-
[ 1283676-82-3 ]
-
5,5',10,10',15,15'-hexaoctyltruxene-2,7,12-tricarboxylic acid
[ No CAS ]
-
[Zn4O(1,4-benzenedicarboxylate)1/2(bpdc-ProBoc)1/2(hott)4/3]
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In water at 85℃; for 24h; |
|
- 14
-
zinc nitrate tetrahydrate
[ No CAS ]
-
[ 605-70-9 ]
-
[ 1283676-82-3 ]
-
5,5',10,10',15,15'-hexabutyltruxene-2,7,12-tricarboxylic acid
[ No CAS ]
-
[Zn4O(ndc)1/2(bpdc-ProBoc)1/2(hbtt)4/3]
[ No CAS ]
- 15
-
zinc nitrate tetrahydrate
[ No CAS ]
-
[ 605-70-9 ]
-
[ 1283676-82-3 ]
-
5,5',10,10',15,15'-hexaoctyltruxene-2,7,12-tricarboxylic acid
[ No CAS ]
-
[Zn4O(ndc)1/2(bpdc-ProBoc)1/2(hott)4/3]
[ No CAS ]