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Chemical Structure| 1311408-02-2 Chemical Structure| 1311408-02-2

Structure of 1311408-02-2

Chemical Structure| 1311408-02-2

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Product Details of [ 1311408-02-2 ]

CAS No. :1311408-02-2
Formula : C30H28BNO2
M.W : 445.36
SMILES Code : CC1(C)C(C)(C)OB(C2=CC=C(C3=CC=C(N4C5=C(C6=C4C=CC=C6)C=CC=C5)C=C3)C=C2)O1

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Application In Synthesis of [ 1311408-02-2 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1311408-02-2 ]

[ 1311408-02-2 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 10016-52-1 ]
  • [ 1311408-02-2 ]
  • 9-(4'-(8-bromodibenzo[b,d]furan-2-yl)-[1,1'-biphenyl]-4-yl)-9H-carbazole [ No CAS ]
YieldReaction ConditionsOperation in experiment
44% With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In 1,4-dioxane; water; at 80℃; for 16.5h;Inert atmosphere; Example 1.11.15 9-(4'-(8-bromodibenzo[b,d]furan-2-yl)-[1,1'-biphenyl]-4-yl)-9H-carbazole (Compound 15) A mixture of 9-(4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-4-yl)-9H-carbazole (1.75 g, 4.42 mmol), <strong>[10016-52-1]2,8-dibromodibenzo[b,d]furan</strong> (2.52 g, 7.74 mmol), tetrakis(triphenylphosphine) palladium(0) (0.25 g, 0.22 mmol), potassium carbonate (1.83 g, 13.26 mmol), 1,4-dioxane (40.00 mL), and water (8.00 mL) was degassed with bubbling argon for 30 minutes. The reaction mixture was then heated to 80° C. and was stirred overnight (16.5 hours), maintaining an argon atmosphere. Consumption of the starting material was confirmed by thin-layer chromatography and the reaction was cooled to room temperature. The product was extracted with dichloromethane, dried, and purified by silica gel column chromatography with dichloromethane in hexanes as the eluent. The product fractions were then dried and the product was collected to yield Compound 15 (1.09 g, 44percent).
 

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