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Chemical Structure| 1318253-36-9 Chemical Structure| 1318253-36-9

Structure of 1318253-36-9

Chemical Structure| 1318253-36-9

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Product Details of [ 1318253-36-9 ]

CAS No. :1318253-36-9
Formula : C18H14N2
M.W : 258.32
SMILES Code : NC1=CC2=C(C=C1)N(C3=CC=CC=C3)C4=C2C=CC=C4
MDL No. :MFCD31384991

Safety of [ 1318253-36-9 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 1318253-36-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1318253-36-9 ]

[ 1318253-36-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 26608-06-0 ]
  • [ 1318253-36-9 ]
  • C30H20N2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
82% With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; potassium tert-butylate; In toluene; at 85℃; for 4h; Synthesis of Intermediate C-7 7.75 g (30 mmol) of 9-phenyl-9H-carbazol-3-amine, 4.94 g (20.0 mmol) of <strong>[26608-06-0]3-bromodibenzo[b,d]furan</strong>, 0.37 g (0.4 mmol) of Pd2(dba)3, 0.08 g (0.4 mmol) of P(tBu)3, and 5.76 g (60 mmol) of KOtBu were dissolved in 200 mL of toluene, and then, the resulting mixed solution was stirred at a temperature of 85 C. for 4 hours. After the obtained reaction solution was cooled to room temperature, an extraction process was performed thereon using 50 mL of water and 50 mL of diethylether. An organic layer obtained from the resulting solution was dried using magnesium sulfate, and a solvent was removed therefrom by evaporation. The residue obtained therefrom was separation-purified by silica gel column chromatography, thereby completing the preparation of 6.96 g (yield: 82%) of Intermediate C-7. The prepared compound was identified by LC-MS. (C30H20N2O: M+ 424.50)
 

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