Alternatived Products of [ 13400-02-7 ]
Product Details of [ 13400-02-7 ]
| CAS No. : | 13400-02-7 |
MDL No. : | |
| Formula : |
C11H14O3
|
Boiling Point : |
- |
| Linear Structure Formula : | - |
InChI Key : | - |
| M.W : |
194.23
|
Pubchem ID : | - |
| Synonyms : |
|
Safety of [ 13400-02-7 ]
| Signal Word: | |
Class: | |
| Precautionary Statements: | |
UN#: | |
| Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 13400-02-7 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 13400-02-7 ]
- 1
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[ 13400-02-7 ]
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[ 37785-48-1 ]
- 2
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[ 13400-02-7 ]
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(R)-1-(3',4',5'-trimethoxyphenyl)ethanol
[ No CAS ]
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[ 37785-48-1 ]
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(S)-1-(3',4',5'-trimethoxyphenyl)ethanol
[ No CAS ]
- 3
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[ 696-62-8 ]
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[ 13400-02-7 ]
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[ 134029-62-2 ]
| Yield | Reaction Conditions | Operation in experiment |
| 50% |
With zirconia-supported palladium; potassium carbonate In N,N-dimethyl-formamide at 140℃; for 4h; Inert atmosphere; |
|
- 4
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[ 13400-02-7 ]
-
[ 1885-35-4 ]
| Yield | Reaction Conditions | Operation in experiment |
| 54% |
With N-Bromosuccinimide; potassium phosphate tribasic heptahydrate; trimethylsilylazide; copper diacetate In acetonitrile at 80℃; for 25h; Schlenk technique; |
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- 5
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[ 54230-88-5 ]
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[ 13400-02-7 ]
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(E)-8-(3,4,5-trimethoxystyryl)tetrazolo[1,5-a]pyridine
[ No CAS ]
| Yield | Reaction Conditions | Operation in experiment |
| 82% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In N,N-dimethyl-formamide at 130℃; for 12h; Inert atmosphere; |
|
| 82% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In N,N-dimethyl-formamide at 130℃; for 12h; Inert atmosphere; |
|
Reference：
[1]Das, Sandip Kumar; Roy, Satyajit; Khatua, Hillol; Chattopadhyay, Buddhadeb
[Journal of the American Chemical Society, 2018, vol. 140, # 27, p. 8429 - 8433]
[2]Das, Sandip Kumar; Roy, Satyajit; Khatua, Hillol; Chattopadhyay, Buddhadeb
[Journal of the American Chemical Society, 2020, vol. 142, # 38, p. 16211 - 16217]
- 6
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[ 201230-82-2 ]
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[ 13400-02-7 ]
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[ 29540-83-8 ]
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[ 73183-34-3 ]
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(E)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(3,4,5-trimethoxyphenyl)prop-1-en-1-yl 4-methylbenzoate
[ No CAS ]
- 7
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[ 13400-02-7 ]
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[ 1576-37-0 ]
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4-Methyl-N-(1-phenyl-3-(3,4,5-trimethoxyphenyl)propyl)benzenesulfonamide
[ No CAS ]
| Yield | Reaction Conditions | Operation in experiment |
| 58% |
With bis(1,5-cyclooctadiene)nickel (0); potassium <i>tert</i>-butylate; tris-(o-tolyl)phosphine; phenylboronic acid In toluene at 120℃; for 20h; Inert atmosphere; |
28 Preparation of 4-Methyl-N-(1-phenyl-3-(3,4,5-trimethoxyphenyl)propyl)benzenesulfonamide
In a nitrogen atmosphere, add raw material 1a (0.2mmol, 52.2mg), raw material 2e (0.4mmol, 77.6mg), KOtBu (0.1mmol, 11.2mg), PhB(OH)2 (0.2mmol, 24.4 mg), Ni(cod)2(0.01mmol, 2.8mg), and P(4-OMePh)3(0.02mmol, 7.0mg), finally add Toluene (0.3mL), stir at 120 for 20 hours, and cool to It was concentrated at room temperature and directly separated by column chromatography to obtain the target product 4e with a yield of 58% and 52.4 mg. |
- 8
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[ 13400-02-7 ]
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[ 3086-62-2 ]
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[ 1885-35-4 ]
| Yield | Reaction Conditions | Operation in experiment |
| 90% |
With ammonium bicarbonate; copper(II) nitrate In dimethyl sulfoxide at 140℃; for 30h; Autoclave; |
Representative Procedure for Conversion of Various Arylethenesto Aromatic Nitriles
General procedure: To a stainless steel autoclave lined with Teflon, 0.5 mmol substrate,0.075 mmol Cu(NO3)2, 1 mmol (NH4)2CO3, and 2 mLDMSO were added. Then the reactor was filled with 2 MPaoxygen and was heated under magnetic stirring at 140 °C for 30h or 40 h (Caution: the use of the high-pressure oxygen ispotentially hazardous. Thus, experiments using the high-pressureoxygen must only be carried out under rigorous safety precautions,and it is required to use the appropriate high-pressurereactor to avoid the potential leakage or explosion of the gas).Once the reaction time was reached, the mixture was cooled toroom temperature, diluted with 30 mL diethyl ether, and filteredvia a Celite pad. The organic mixture was washed withwater (3 × 5 mL), dried with anhydrous sodium sulfate, and concentratedin vacuum. GC analysis provided the GC yields of theproduct with an internal standard. In addition, the combinedcrude product from another 1-5 parallel experiments was purifiedby column chromatography and identified by 1H NMR and13C NMR spectroscopy. All the products are the known compounds,and the analytical data of several typical compoundsare as follows: |
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