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Chemical Structure| 134029-92-8 Chemical Structure| 134029-92-8

Structure of 134029-92-8

Chemical Structure| 134029-92-8

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Product Citations

Product Citations

Zheng, Xin ; Bolotin, Igor L ; Tanriover, Beria ; Rathnayake, Kumuditha ; Askins, Erik J ; Cabana, Jordi , et al.

Abstract: This study investigated the reactivity of two carbon electrodes (glassy carbon-GC and carbon powder-CP), with iodine monochloride for surface chlorination and subsequent covalent attachment of thiol-terminated molecules, (6-mercaptohexyl)ferrocene and benzene-1,2,4,5-tetrathiol. X-ray photoelectron spectroscopy analysis revealed that the iodine monochloride treatment resulted in chlorination and iodination of both carbon electrodes, with post-reaction GC exhibiting significant Cl:C ratios. However, chlorination of either carbon electrode did not enhance reactivity with thiol-terminated molecules. For GC, inherent or anodized surface oxide groups were found to be equally effective for covalent attachment of thiol-terminated molecules through Michael addition as chlorine-termination through nucleophilic aromatic substitution. In contrast, CP, despite its lower surface reactivity, could directly tether (6-mercaptohexyl)ferrocene without pretreatment or chlorination. Furthermore, a tetrathiolate bridge was successfully employed to covalently attach a molybdenum complex to anodized GC.

Keywords: Carbon electrode modifications ; glassy carbon ; carbon black powder ; chlorination ; alkanethiols ; aromatic thiols

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Product Details of [ 134029-92-8 ]

CAS No. :134029-92-8
Formula : C16H22FeS
M.W : 302.26
SMILES Code : SCCCCCC[C-]12[Fe+2]3456789([CH-]%10[CH]6=[CH]7[CH]8=[CH]9%10)[CH]1=[CH]3[CH]4=[CH]25
MDL No. :MFCD09265168

Safety of [ 134029-92-8 ]

GHS Pictogram:
Signal Word:Danger
Hazard Statements:H315-H319-H413-H372
Precautionary Statements:P501-P273-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Class:9
UN#:3334
Packing Group:
 

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