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Chemical Structure| 1345202-03-0 Chemical Structure| 1345202-03-0

Structure of 1345202-03-0

Chemical Structure| 1345202-03-0

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Product Details of [ 1345202-03-0 ]

CAS No. :1345202-03-0
Formula : C30H20N2
M.W : 408.49
SMILES Code : C1(NC2=C3C=CC=C2)=C3C=CC(C4=CC5=C(C=C4)N(C6=CC=CC=C6)C7=C5C=CC=C7)=C1
MDL No. :MFCD32012082
InChI Key :JNIGFUXIZVCEED-UHFFFAOYSA-N
Pubchem ID :67952954

Safety of [ 1345202-03-0 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H315-H319
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313

Application In Synthesis of [ 1345202-03-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1345202-03-0 ]

[ 1345202-03-0 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 57774-35-3 ]
  • [ 1345202-03-0 ]
  • C43H27N3 [ No CAS ]
YieldReaction ConditionsOperation in experiment
54% With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate; In 5,5-dimethyl-1,3-cyclohexadiene; for 8h;Reflux; Inert atmosphere; Under argon flow, Intermediate 3 (3.3 g, 8.1 mmol) was added sequentially, <strong>[57774-35-3]4-bromo-4'-cyanobiphenyl</strong> (2.5 g, 9.7 mmol) (Dibenzylideneacetone) dipalladium (0.297, 0.324 mmol) Tri-t-butylphosphonium tetrafluoroborate (0.234 g, 0.805 mmol) Sodium t-butoxide (1.5 g, 16.2 mmol) Anhydrous xylene (40 mL), And heated to reflux for 8 hours. After the reaction solution was allowed to cool to room temperature, Separating the organic layer, The organic solvent was distilled off under reduced pressure. The resulting residue was purified by silica gel column chromatography, 2.6 g (yield 54%) of a white solid (H-1) was obtained.
 

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