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Chemical Structure| 13471-35-7 Chemical Structure| 13471-35-7

Structure of 13471-35-7

Chemical Structure| 13471-35-7

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Product Details of [ 13471-35-7 ]

CAS No. :13471-35-7
Formula : C8H11BO2
M.W : 149.98
SMILES Code : COB(C1=CC=CC=C1)OC
MDL No. :MFCD24857381
InChI Key :MJMJJGCCNUPJBI-UHFFFAOYSA-N
Pubchem ID :139471

Safety of [ 13471-35-7 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H312-H332
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501

Application In Synthesis of [ 13471-35-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 13471-35-7 ]

[ 13471-35-7 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 852138-89-7 ]
  • [ 13471-35-7 ]
  • C18H11BBr2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
43% 4,4'-dibromo-2,2'-diiodobiphenyl (2.24 g,3.92mmol) dissolved in 50mL anhydrous tetrahydrofuran solution, adding 2.5M n-butyl lithium n-hexane solution at -78 C(6.5 mL, 16 mmol), the reaction solution was kept at this temperature for 2 hours.Rapid addition of phenyldichlorophosphine(0.66g,4.4mmol). The incubation was continued for 1 hour, and the reaction was slowly warmed to room temperature overnight. After the reaction is over, quench with waterThe reaction, the organic phase was washed with brine, dried and purified by column chromatography to afford a powder solid (0.67 g, 43%).
 

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