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[ CAS No. 1373432-11-1 ] {[proInfo.proName]}

(2S,3S)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole/ Sold under license from Zejun for research purposes ,{[proInfo.pro_purity]}
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Chemical Structure| 1373432-11-1
Chemical Structure| 1373432-11-1
Structure of 1373432-11-1 * Storage: {[proInfo.prStorage]}
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Product Details of [ 1373432-11-1 ]

CAS No. :1373432-11-1 MDL No. :MFCD31707596
Formula : C20H25O3P Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 344.38 Pubchem ID :-
Synonyms :

Safety of [ 1373432-11-1 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1373432-11-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1373432-11-1 ]

[ 1373432-11-1 ] Synthesis Path-Downstream   1~5

  • 1
  • [ 1246888-86-7 ]
  • [ 1373432-11-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: lithium diisopropyl amide / tetrahydrofuran; n-heptane; chlorobenzene / 1 h / -78 °C / Inert atmosphere 1.2: -78 - 20 °C / Inert atmosphere 2.1: titanium(IV) isopropylate / tetrahydrofuran / 12 h / Inert atmosphere; Reflux
  • 2
  • [ 1373432-36-0 ]
  • [ 1373432-11-1 ]
YieldReaction ConditionsOperation in experiment
95% With titanium(IV) isopropylate In tetrahydrofuran at 70℃; for 16h; Inert atmosphere; stereospecific reaction;
90% With titanium(IV) isopropylate In tetrahydrofuran for 12h; Inert atmosphere; Reflux;
With titanium(IV) isopropylate In tetrahydrofuran Inert atmosphere; stereospecific reaction;
With titanium(IV) isopropylate In tetrahydrofuran at 65℃; for 14h; Inert atmosphere; Schlenk technique;
With trichlorosilane; triethylamine

  • 3
  • [ 1202032-99-2 ]
  • [ 1373432-11-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: tris-(dibenzylideneacetone)dipalladium(0); potassium fluoride / 1,4-dioxane / Inert atmosphere 2: lithium diisopropyl amide / Inert atmosphere 3: titanium(IV) isopropylate / tetrahydrofuran / Inert atmosphere
  • 5
  • [ 23112-96-1 ]
  • [ 1373432-11-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: tris-(dibenzylideneacetone)dipalladium(0); potassium fluoride / 1,4-dioxane / Inert atmosphere 2: lithium diisopropyl amide / Inert atmosphere 3: titanium(IV) isopropylate / tetrahydrofuran / Inert atmosphere
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[ 1373432-11-1 ]

Chemical Structure| 1477517-18-2

A1005935[ 1477517-18-2 ]

(2R,3R)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole

Reason: Optical isomers